Materials Data on Tl3SbS3 by Materials Project
Tl3SbS3 crystallizes in the trigonal R3m space group. The structure is three-dimensional. Tl1+ is bonded in a 5-coordinate geometry to five equivalent S2- atoms. There are a spread of Tl–S bond distances ranging from 3.05–3.66 Å. Sb3+ is bonded in a distorted trigonal non-coplanar geometry to three equivalent S2- atoms. All Sb–S bond lengths are 2.47 Å. S2- is bonded in a 6-coordinate geometry to five equivalent Tl1+ and one Sb3+ atom.
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