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Materials Data on Tl3In by Materials Project

Tl3In is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tl is bonded to eight equivalent Tl and four equivalent In atoms to form TlTl8In4 cuboctahedra that share corners with twelve equivalent TlTl8In4 cuboctahedra, edges with eight equivalent InTl12 cuboctahedra, edges with sixteen equivalent TlTl8In4 cuboctahedra, faces with four equivalent InTl12 cuboctahedra, and faces with fourteen equivalent TlTl8In4 cuboctahedra. All Tl–Tl bond lengths are 3.49 Å. All Tl–In bond lengths are 3.49 Å. In is bonded to twelve equivalent Tl atoms to form InTl12 cuboctahedra that share corners with twelve equivalent InTl12 cuboctahedra, edges with twenty-four equivalent TlTl8In4 cuboctahedra, faces with six equivalent InTl12 cuboctahedra, and faces with twelve equivalent TlTl8In4 cuboctahedra.

36 MATERIALS SCIENCE↗

Materials Data on Tl3In by Materials Project

Tl3In crystallizes in the orthorhombic Cmmm space group. The structure is three-dimensional. there are two inequivalent Tl sites. In the first Tl site, Tl is bonded in a distorted body-centered cubic geometry to six Tl and two equivalent In atoms. There are four shorter (3.45 Å) and two longer (3.50 Å) Tl–Tl bond lengths. Both Tl–In bond lengths are 3.25 Å. In the second Tl site, Tl is bonded in a body-centered cubic geometry to eight Tl atoms. All Tl–Tl bond lengths are 3.45 Å. In is bonded in a distorted body-centered cubic geometry to four equivalent Tl atoms.

36 MATERIALS SCIENCE↗