Materials Data on Tl2GeF6 by Materials Project
Tl2GeF6 crystallizes in the trigonal P-3m1 space group. The structure is three-dimensional. Tl1+ is bonded in a 12-coordinate geometry to twelve equivalent F1- atoms. There are a spread of Tl–F bond distances ranging from 3.04–3.26 Å. Ge4+ is bonded in an octahedral geometry to six equivalent F1- atoms. All Ge–F bond lengths are 1.84 Å. F1- is bonded in a single-bond geometry to four equivalent Tl1+ and one Ge4+ atom.
36 MATERIALS SCIENCE↗