Materials Data on Tl2F3 by Materials Project
TlTlF3 is alpha Rhenium trioxide-like structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one thallium molecule and one TlF3 framework. In the TlF3 framework, Tl is bonded to six equivalent F atoms to form corner-sharing TlF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Tl–F bond lengths are 2.36 Å. F is bonded in a linear geometry to two equivalent Tl atoms.
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