Results for “Tl(ZnSb)2”

Materials Data on Tl(ZnSb)2 by Materials Project

Tl(ZnSb)2 crystallizes in the tetragonal I4cm space group. The structure is three-dimensional and consists of two Tl ribbons oriented in the (0, 0, 1) direction and one ZnSb framework. In each Tl ribbon, Tl1+ is bonded in a 2-coordinate geometry to two equivalent Tl1+ atoms. Both Tl–Tl bond lengths are 3.74 Å. In the ZnSb framework, Zn2+ is bonded to four equivalent Sb+2.50- atoms to form a mixture of corner and edge-sharing ZnSb4 tetrahedra. There are a spread of Zn–Sb bond distances ranging from 2.67–2.74 Å. Sb+2.50- is bonded to four equivalent Zn2+ atoms to form a mixture of corner and edge-sharing SbZn4 tetrahedra.