Materials Data on TiS2N by Materials Project
STiNS is trigonal omega-derived structured and crystallizes in the trigonal R3m space group. The structure is two-dimensional and consists of three ammonia molecules and three TiS2 sheets oriented in the (0, 0, 1) direction. In each TiS2 sheet, Ti3+ is bonded to six equivalent S2- atoms to form edge-sharing TiS6 octahedra. All Ti–S bond lengths are 2.43 Å. S2- is bonded in a distorted T-shaped geometry to three equivalent Ti3+ atoms.
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