SEARCH · Engineering Papers

Results for “TiH”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

10 records

All sources NASA NTRS DOE OSTI

NASA NTRS1999

TiCl, TiH and TiH+ Bond Energies, a Test of a Correlation Consistent Ti Basis Set

Correlation consistent basis sets are developed for Ti atom. The polarization functions are optimized for the average of the 3F and 5F states. One series of correlation consistent basis sets is for 3d and 4s correlation, while the second series includes 3s and 3p correlation as well as 3d and 4s correlation. These basis sets are tested using the Ti 3F-5F separation and the dissociation energies of TiCl X4Phi, TiH X4Phi, and TiH(+) X3Phi. The CCSD(T) complete basis set limit values are determined by extrapolation. The Douglas Kroll approach is used to compute the scalar relativistic effect. Spin-orbit effects are taken from experiment and/or computed at the CASSCF level. The Ti 3F-5F separation is in excellent agreement with experiment, while the TiCl, TiH, and TiH(+) bond energies are in good agreement with experiment. Extrapolation with the valence basis set is consistent with other atoms, while including 3s and 3p correlation appears to make extrapolation.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1988

Full configuration interaction benchmark calculations for TiH

Full configuration interaction (FCI) results for the 3F and 5F states of Ti and the 4Phi and 2Delta states of TiH are presented. While the coupled pair functional (CPF) or modified CPF approaches are found to work well for the 4Phi state of TiH, they do not perform as well for the 2Delta state. Although for mu, the CASSCF/MRCI methods do well for the 2Delta state, when the active space is expanded outside the normal valence definition, the dipole moment is only brought into agreement with the FCI results by natural orbital iterations.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1983

CASSCF/CI calculations for first row transition metal hydrides - The TiH(4-phi), VH(5-delta), CrH(6-sigma-plus), MnH(7-sigma-plus), FeH(4,6-delta) and NiH(2-delta) states

Calculations are performed for the predicted ground states of TiH(4-phi), VH(5-delta), CrH(6-sigma-plus), MnH(7-sigma-plus), Fett(4,6-delta) and NiH(2-delta). For FeH both the 6-delta and 4-delta states are studied, since both are likely candidates for the ground state. The ground state symmetries are predicted based on a combination of atomic coupling arguments and coupling of 4s(2)3d(n) and 4s(1)3d(n+1) terms in the molecular system. Electron correlation is included by a CASSCF/CI (SD) treatment. The CASSCF includes near-degeneracy effects, while correlation of the 3d electrons in included at the CI level.

Walch, S. P.↗

NASA NTRS1988

Muon motion in titanium hydride

Motional narrowing of the transverse-field muon spin rotation signal was observed in gamma-TiH(x) for x = 1.83, 1.97, and 1.99. An analysis of the data for TiH1.99 near room temperature indicates that the mechanism responsible for the motion of the muon out of the octahedral site is thermally activated diffusion with an attempt frequency comparable to the optical vibrations of the lattice. Monte Carlo calculations to simulate the effect of muon and proton motion upon the muon field-correlation time were used to interpret the motional narrowing in TiH1.97 near 500 K. The interpretation is dependent upon whether the Bloembergen, Purcell, and Pound (BPP) theory or an independent spin-pair relaxation model is used to obtain the vacancy jump rate from proton NMR T1 measurements. Use of BPP theory shows that the field-correction time can be obtained if the rate of motion of the muon with respect to the rate of the motion for the protons is decreased. An independent spin-pair relaxation model indicates that the field-correlation time can be obtained if the rate of motion for the nearest-neighbor protons is decreased.

Kempton, J. R.↗

NASA NTRS1991

Evaluation of a hydrogen resistant titanium aluminide alloy

The Ti-24Al-11Nb (Ti-24-11) alloy heat treated to the fine basketweave microstructure was shown previously to be hydrogen tolerant. In order to assess its limit of hydrogen tolerance, the tensile, creep, fracture toughness, and sustained load crack growth behaviors of this alloy were studied as a function of hydrogen content. All test specimens were thermally charged with internal hydrogen and tested at 25 and 600 C. Coupon specimens were used for developing the hydrogen charging procedures and for studying compatibility of the alloy with high temperature, high pressure gaseous hydrogen. The mechanical test results indicated that the fine basketweave microstructure was tolerant to hydride embrittlement for hydrogen contents up to approximately 1500 wt. ppm, providing that the hydride formed was of the TiH2 type. On the other hand, hydrogen charging experiments indicated that the Ti-24-11 alloy was severely cracked and pulverized under zero load when the hydrogen content exceeded 3000 wt. ppm. X-ray diffraction results revealed that the dichotomous behaviors might be due to the formation of TiH(1.924) type hydrides at higher hydrogen contents. Thus, hydrogen embrittlement in the Ti-24-11 alloy with the fine basketweave microstructure depends on hydrogen content and the nature of the hydrides formed.

Chan, K. S.↗

NASA NTRS2007

A Burst Chasing X-ray Polarimeter

Tihs is a viewgraph presentation of a discussion of the X-ray Polarimeter. Gamma-ray bursts are one of the most powerful explosions in the universe and have been detected out to distances of almost 13 billion light years. The exact origin of these energetic explosions is still unknown but the resulting huge release of energy is thought to create a highly relativistic jet of material and a power-law distribution of electrons. There are several theories describing the origin of the prompt GRB emission that currently cannot be distinguished. Measurements of the linear polarization would provide unique and important constraints on the mechanisms thought to drive these powerful explosions. We present the design of a sensitive, and extremely versatile gamma-ray burst polarimeter. The instrument is a photoelectric polarimeter based on a time-projection chamber. The photoelectric time-projection technique combines high sensitivity with broad band-pass and is potentially the most powerful method between 2 and 100 keV where the photoelectric effect is the dominant interaction process We present measurements of polarized and unpolarized X-rays obtained with a prototype detector and describe the two mission concepts, the Gamma-Ray Burst Polarimeter (GRBP) for thc U S Naval Academy satellite MidSTAR-2, and thc Low Energy Polarimeter (LEP) onboard POET, a broadband polarimetry concept for a small explorer mission.

Hill, Joanne↗

NASA NTRSDate not supplied

Prism Assembly for Roman Space Telescope Wide Field Instrument Slit-less Spectroscopy

The Roman Space Telescope (RST) is a three mirror anastigmat design with a 2.4 m primary mirror. RST will be based in L2 orbit, from where it will provide science information on exoplanets and dark energy using the Coronagraph Instrument (CGI) and Wide Field Instrument (WFI). The WFI features a 300 megapixel near-infrared detector array which provides a field of view 100 times larger than that of Hubble Space Telescope. The Prism Assembly is a small add-on instrument to the Roman Space Telescope’s Wide Field Instrument (WFI), installed in a slot in WFI’s element wheel. The Prism assembly has a passband from 0.75 µm to 1.8 µm, enabling a survey of redshifts in the range 0.2 to 1.7 µm. It provides low resolution slit-less spectroscopy with a spectral resolution R > 70 for all wavelengths, and R < 170 for λ > 0.8 µm across the full field. The Prism Assembly has the potential to provide more supernova spectra than ground-based spectroscopy during the mission lifetime. Being a late add-on to the RST mission, the Prism Assembly has had restrictions on size, weight and geometry, and a challenging schedule, which has dictated much of the implementation. Despite these challenges, the Prism Assembly is a pocket-sized high-performance spectrographic element, implemented as a refractive, all-spherical optical design using only two elements, one S-TIH-1 glass and one CaF2. This presentation will give an overview of the Prism Assembly, from design and implementation, through alignment, test and calibration. (100 words): The Roman Space Telescope is a three mirror anastigmat design with a 2.4 m primary mirror, which will provide science information on dark energy and exoplanets. The Prism Assembly is a small add-on instrument to the telescope’s Wide Field Instrument, enabling low resolution slit-less spectroscopy with a spectral resolution 70 < R < 170 across the full field from λ= 0.75 µm to 1.8 µm. The Prism Assembly is a refractive, all-spherical optical design using a glass and a CaF2 element. This presentation will give an overview of the Prism Assembly, from design and implementation, through alignment, test and calibration.

Space Instrumentation↗

NASA NTRSDate not supplied

NASA Exploration Toilet Hardware Status and Crew Feedback from ISS Artemis-2 Demonstration

The Universal Waste Management System (UWMS), ISS operational nomenclature “Toilet”, was initially installed on the International Space Station (ISS) in 2020 with final installation completed in 2021. Technical progress continues to be made with each on-orbit operation and will ultimately culminate with nominal US crew use of the hardware on ISS. During 2023, the Artemis-2 Demonstration was started, and this paper discusses issues encountered, on-orbit troubleshooting, subsequent ground failure investigation and proposed repairs as well as near-term plans to resume the Artemis-2 demo. Also discussed is an update to the commercial-off-the-shelf (COTS) Conductivity Monitor which is planned to be flown for the resumption of the demo along with additional UWMS hardware and Toilet Integration Hardware (TIH). An updated design of the commode seat and fecal bag for Artemis-2 UWMS will be demonstrated on ISS and a summary of the hardware is included in the paper. Use of the hardware during the first days of the aborted demonstration by crewmembers and feedback received is summarized as well as hardware updates resulting from that feedback. The paper will also provide an overview of the demo results to date that inform the Orion-installed UWMS unit and future manifesting of consumables for both Orion and ISS.

Toilet↗

NASA NTRSDate not supplied

NASA Exploration Toilet Hardware Status and Crew Feedback from ISS Artemis-2 Demonstration

The Universal Waste Management System (UWMS), ISS operational nomenclature “Toilet”, was initially installed on the International Space Station (ISS) in 2020 with final installation completed in 2021. Technical progress continues to be made with each on-orbit operation and will ultimately culminate with nominal US crew use of the hardware on ISS. During 2023, the Artemis-2 Demonstration was started, and this paper discusses issues encountered, on-orbit troubleshooting, subsequent ground failure investigation and proposed repairs as well as near-term plans to resume the Artemis-2 demo. Also discussed is an update to the commercial-off-the-shelf (COTS) Conductivity Monitor (CCM) which is planned to be flown for the resumption of the demo along with additional UWMS hardware and Toilet Integration Hardware (TIH). An updated design of the commode seat and fecal bag for Artemis-2 UWMS will be demonstrated on ISS and a summary of the hardware is included in the paper. Use of the hardware during the first days of the aborted demonstration by crewmembers and feedback received is summarized as well as hardware updates resulting from that feedback. The paper will also provide an overview of the demo results to date that inform the Orion-installed UWMS unit and future manifesting of consumables for both Orion and ISS.

Toilet↗

NASA NTRSDate not supplied

NASA Exploration Hardware Status and Crew Feedback from Artemis-2 Demonstration

Toilet↗