Materials Data on Ti4V by Materials Project
Ti4V crystallizes in the orthorhombic Fmmm space group. The structure is three-dimensional. there are two inequivalent Ti sites. In the first Ti site, Ti is bonded in a 8-coordinate geometry to two equivalent Ti and two equivalent V atoms. Both Ti–Ti bond lengths are 2.93 Å. Both Ti–V bond lengths are 2.61 Å. In the second Ti site, Ti is bonded in a distorted body-centered cubic geometry to eight Ti atoms. There are four shorter (2.77 Å) and two longer (2.80 Å) Ti–Ti bond lengths. V is bonded in a 12-coordinate geometry to four equivalent Ti atoms.
36 MATERIALS SCIENCE↗