Materials Data on Ti3S2 by Materials Project
Ti3S2 is Ilmenite-derived structured and crystallizes in the trigonal R32 space group. The structure is three-dimensional. Ti is bonded in a 4-coordinate geometry to four equivalent S atoms. There are two shorter (2.42 Å) and two longer (2.44 Å) Ti–S bond lengths. S is bonded to six equivalent Ti atoms to form a mixture of distorted edge, face, and corner-sharing STi6 pentagonal pyramids.
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