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NASA NTRS1988

Crystallization of BaF2-ZnF2-YbF3-ThF4 glass

The phases and the rates of crystallization in a Ba-Zn-Yb-Th fluoride glass were studied using differential scanning calorimetry, XRD, and observational and chemical SEM analyses. The crystallizing phases that were identified included a BaYbTh fluoride, ZnF2, and YbF3. The BaYbTh fluoride crystallized first at about 450 C, and ZnF2, which was excluded from this phase, crystallized at its surfaces. At higher temperatures, the BaYbTh fluoride phase decomposed partially to BaThF6 and YbF3 phases.

Garcia, Roberto↗

NASA NTRS1976

UF6 breeder reactor power plants for electric power generation

The reactor concept analyzed is a U-233F6 core surrounded by a molten salt (Li(7)F, BeF2, ThF4) blanket. Nuclear survey calculations were carried out for both spherical and cylindrical geometries. Thermodynamic cycle calculations were performed for a variety of Rankine cycles. A conceptual design is presented along with a system layout for a 1000 MW stationary power plant. Advantages of the gas core breeder reactor (GCBR) are as follows: (1) high efficiency; (2) simplified on-line reprocessing; (3) inherent safety considerations; (4) high breeding ratio; (5) possibility of burning all or most of the long-lived nuclear waste actinides; and (6) possibility of extrapolating the technology to higher temperatures and MHD direct conversion.

Rust, J. H.↗

NASA NTRS1991

Vacuum deposited optical coatings experiment (AO 138-4)

The aim of this experiment was to test the optical behavior of 20 components and coatings subjected to space exposure. Most of them are commonly used for their reflective or transmittive properties in spaceborne optics. They consist in several kind of metallic and dielectric mirrors designed for the 0.12 to 10 microns spectrum, UV, and NIR bandpass filters, visible, and IR antireflecting coatings, visible/IR dichroic beam splitters, and visible beam splitter. The coatings were deposited on various substrates such as glasses, germanium, magnesium fluoride, quartz, zinc selenide, and kanigened aluminum. Several coating materials were used such as Al, Ag, Au, MgF2, LaF3, ThF3, ThF4, SiO2, TiO2, ZrO2, Al2O3, MgO, Ge, and ZnSe. Five samples of each component were manufactured. Two flight samples were mounted in such a way that one was directly exposed to space and the other looking backwards. The same arrangement was used for the spare samples stored on ground in a box identical to the flight one and they were kept under vacuum during the LDEF mission. Finally, one set of reference components was stocked in a sealed box under a dry nitrogen atmosphere. By comparing the preflight and postflight optical performances of the five samples of each component, it is possible to detect the degradations due to the space exposure.

Charlier, Jean↗