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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Enabling fast charging – A battery technology gap assessment

The battery technology literature is reviewed, with an emphasis on key elements that limit extreme fast charging. Key gaps in existing elements of the technology are presented as well as developmental needs. Among these needs are advanced models and methods to detect and prevent lithium plating; new positive-electrode materials which are less prone to stress-induced failure; better electrode designs to accommodate very rapid diffusion in and out of the electrode; measure temperature distributions during fast charge to enable/validate models; and develop thermal management and pack designs to accommodate the higher operating voltage.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2018

Direct Supercritical CO 2 Power Cycle Technology Research and Development: Technology Gaps and Research Needs

This research and development (R&D) plan aims to identify technology gaps and research needs to help enable the commercialization of the direct supercritical carbon dioxide (sCO 2 ) power cycle technology by 2025. The goal of the plan is to help reduce technical risks to commercialization of the technology by providing guidance to United States (U.S.) national laboratories for closing the technology gaps.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2014

Assessment of Regulatory Technology Gaps for Advanced Small Modular Sodium Fast Reactors

As part of an ongoing Regulatory Technology Development Plan (RTDP) for advanced small modular reactors, a review of the Sandia National Laboratories (SNL) report Sodium Fast Reactor Safety and Licensing Research Plan was conducted to identify technology-related barriers that would impact the licensing of a small sodium fast reactor (SFR), which could be resolved with technology development performed in conjunction with key additional regulatory interactions. While the general conclusions of the SNL report are still valid for small SFRs, a subsequent evaluation of the report recognized several areas that would benefit from regulatory clarification of requirements, as described in the following table.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2014

Contaminant Stabilization Technology Gap Report

After an intentional radiological release or nuclear power plant (NPP) accidental release, there may be a large area that is contaminated. Re-suspension and tracking of contamination may create issues with containing the contaminated area and create additional exposure to responders. There is a need for technologies/methodologies to reduce resuspension and tracking. Current radiological particle containment relies on securing the area, setting up a single egress and ingress route, and minimizing the amount of contaminated equipment and vehicles leaving the contaminated zone. The re-suspension and tracking of contamination greatly hampers the ability to conduct first response activities in that zone therefore technologies that can reduce these spreading mechanisms are needed. In the NPP decommissioning industry, coatings are employed to reduce the spread of contamination. These coatings may not be readily available in the quantities needed for early response. Responders need containment methodologies that can be employed with existing equipment and materials on site using techniques such as fire hosing, street sweepers, and painting. A review by Parra et al. (2009) provided a good overview of fixative/stabilization materials, which formed the basis (in addition to a literature search) for a list of potential technologies presented to stakeholders in the initial stages of this work. Advantages and disadvantages were identified for each of the technologies, which were grouped into tiers based on the time-frame they would be available following a radiological release. Stakeholders then ranked containment technologies in terms of their preference and interest in use and availability. The final part of this task is to gather more information on the stakeholder-selected technologies and identify technical gaps that need to be filled with experimental research before technical procedures can be developed for containment technology use in the field.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Enabling Fast Charging: A Technology Gap Assessment

Decreasing energy consumption across the U.S. transportation sector, especially in commercial light-duty vehicles, is essential for the United States to gain energy independence. Recently, powertrain electrification with plug-in electric vehicles (PEVs) have gained traction as an alternative due to their inherent efficiency advantages compared to the traditional internal combustion engine vehicle (ICEV). Even though there are many different classes of PEVs, the intent of this study is to focus on non-hybrid powertrains, or battery electric vehicles (BEVs).

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2017

Enabling Fast Charging: A Technology Gap Assessment

The transportation sector accounts for the largest percentage of energy use in the United States. Decreasing energy consumption across this sector, especially in commercial light duty transportation, is essential for the U.S. to gain energy independence. Recently, powertrain electrification with plug-in electric vehicles (PEVs) have gained traction as an alternative due to their inherent efficiency advantages compared to the traditional internal combustion engine vehicle (ICEV). Accounting for 500,000 vehicle on the road today, these PEVs will reduce oil imported into the U.S. by five billion gallons and save two billion dollars in fuel costs to consumers over their useful life. Though there are many different classes of PEV, the intent of this study is to focus on non-hybrid powertrains, or battery electric vehicles (BEVs). Despite rapid drops in cost within the BEV powertrain of over 4x in the last 10 years, the PEV market still only accounts for approximately 1% of new light duty vehicle sales annually. Though BEV powertrain costs are not quite at parity with the ICEV, another gap to wider adoption of BEVs that have been identified is the ability to refuel quickly, or to fast charge. Though the majority of recharging BEVs is done at home, having access to fast charge stations has a big impact on BEV utility from a consumer perspective. To address the fast charge barrier, charging at 350 kW, or extreme fast charging (XFC), has been proposed and will serve as the basis for discussion in this report. Studies have shown that in areas where drivers have access to 50 kW or 120 kW fast charge stations, annual electric vehicle miles traveled (eVMT) increased by over 25%, even in cases where fast charging was used for 1-5% of total charging events [1, 2]. Having access to these fast charge stations can help alleviate the “range anxiety” that is cited as a common reason for consumers to hesitate to buy a BEV. Though, to be truly competitive to the ICEV refueling experience, even higher power stations are necessary. These extreme fast charge stations (XFC) should be able to recharge a BEV in less than 10 minutes and provide approximately 175 additional miles of driving. However, this introduces a host of new challenges that need to be addressed. As a result, it is expected that packs designed to meet XFC will be significantly more expensive initially than BEVs optimized for range that can reach 140kW with current technology. From the battery cell to the power grid to which these 350 kW chargers are connected, this study will discuss the issues that need to be addressed at each level in order to implement a 350 kW charging network. Although this report is U.S.-focused, the findings should be applicable to other countries with mature automotive infrastructures.

25 ENERGY STORAGE↗
DOE OSTI2016

FY-16 Technology Gap Study Technical Report: Analysis of Undissolved Anode Materials of Mark-IV Electrorefiner

The Experimental Breeder Reactor II (EBR-II) is a sodium cooled fast reactor developed at Argonne National Laboratory (ANL). The used fuels from the EBR-II are currently being treated in the Fuel Conditioning Facility (FCF) at the Idaho National Laboratory (INL). The Mark IV (Mk-IV) electrorefiner (ER) is a unit process in the FCF, which is primarily assigned to treating the used driver fuels. The stainless steel anode baskets hold the chopped spent driver fuel segments. During electrorefining, the anode baskets are immersed into the electrolyte and the used fuel is dissolved electrochemically. Perforated sides and bottoms allow the flow of the electrolyte into and out of the anode baskets. The steel cathode is also immersed into the electrolyte and collects the reduced products. The active metal contents in the used fuel (e.g., Cs, Sr, lanthanides, Pu, etc.) reacts with uranium cations in the electrolyte and progressively reports to the electrolyte. Noble metals are mostly retained in the cladding hulls. Varying quantities of zirconium are retained in the cladding hulls depending on the operational conditions of the Mk-IV ER. The undissolved anode materials are removed from the anode baskets and stored for subsequent metal waste form processing. These undissolved materials typically include undissolved fuels, stainless steel cladding, and adhering electrolyte. A couple of hulls are retrieved for chemical analysis and used for estimating the composition of the entire undissolved anode materials. The mass balance attempt based on this practice of estimating the undissolved anode materials has been a challenge due to inherently high sampling errors associated with heterogeneous undissolved material compositions. Responding to the prescribed challenge, this report investigates chemical analysis data as a whole and finds noticeable trends in the compositions of undissolved anode material samples with respect to the mass of the whole undissolved anode materials. Based upon this discovery, an empirical model is proposed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

SiC/SiC Composites Technology Gap Analysis for Molten Salt Reactors

The purpose of this report is to identify the research and development (R&D) gaps for potential applications of silicon carbide/silicon carbide matrix (SiC/SiC) composite components for Generation IV Molten Salt Reactors (MSRs).

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2014

Research gaps and technology needs in development of PHM for passive AdvSMR components

Advanced small modular reactors (AdvSMRs), which are based on modularization of advanced reactor concepts, may provide a longer-term alternative to traditional light-water reactors and near-term small modular reactors (SMRs), which are based on integral pressurized water reactor (iPWR) concepts. SMRs are challenged economically because of losses in economy of scale; thus, there is increased motivation to reduce the controllable operations and maintenance costs through automation technologies including prognostics health management (PHM) systems. In this regard, PHM systems have the potential to play a vital role in supporting the deployment of AdvSMRs and face several unique challenges with respect to implementation for passive AdvSMR components. This paper presents a summary of a research gaps and technical needs assessment performed for implementation of PHM for passive AdvSMR components.

42 ENGINEERING↗
DOE OSTI2023

The research challenges in security and safeguards for nuclear fission batteries

This paper discusses the nuclear security and safeguards research challenges presented by the development and deployment of nuclear fission batteries. These are defined as easily transportable and deployable nuclear systems which are designed to operate either unattended or autonomously. We start by defining the current landscape of domestic and international safeguards and security and discuss how it can be affected by the introduction these new nuclear systems. We then specifically discuss the technology gaps and technologies to be developed to facilitate their practical deployment. We find that, as expected, we can leverage conclusions from existing security and safeguards studies for small modular rectors and develop bespoke target set analyses to inform security postures based on probabilistic risk assessment. We find also that specific fission battery security economic analysis tools are needed and security by design must be applied early. However, the most important finding is that these new systems will require a new comprehensive set of cyber tools covering transportation, installation, operation, maintenance security of the fission battery systems. Altogether, we find that the development of the necessary security and safeguards requirements at the design phase of such a technology will be of great benefit in the smooth deployment of this modern nuclear energy system.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2014

Novel Supercritical Carbon Dioxide Power Cycle Utilizing Pressured Oxy-combustion in Conjunction with Cryogenic Compression

The team of Southwest Research Institute ® (SwRI) and Thar Energy LLC (Thar) applied technology engineering and economic analysis to evaluate two advanced oxy-combustion power cycles, the Cryogenic Pressurized Oxy-combustion Cycle (CPOC), and the Supercritical Oxy-combustion Cycle. This assessment evaluated the performance and economic cost of the two proposed cycles with carbon capture and included a technology gap analysis of the proposed technologies to determine the technology readiness level of the cycle and the cycle components. The results of the engineering and economic analysis and the technology gap analysis were used to identify the next steps along the technology development roadmap for the selected cycle. The project objectives, as outlined in the FOA, were 90% CO 2 removal at no more than a 35% increase in cost of electricity (COE) as compared to a Supercritical Pulverized Coal Plant without CO 2 capture. The supercritical oxy-combustion power cycle with 99% carbon capture achieves a COE of $\$$121/MWe. This revised COE represents a 21% reduction in cost as compared to supercritical steam with 90% carbon capture ($\$$137/MWe). However, this represents a 49% increase in the COE over supercritical steam without carbon capture ($\$$80.95/MWe), exceeding the 35% target. The supercritical oxy-combustion cycle with 99% carbon capture achieved a 37.9% HHV plant efficiency (39.3% LHV plant efficiency), when coupling a supercritical oxy-combustion thermal loop to an indirect supercritical CO 2 (sCO 2 ) power block. In this configuration, the power block achieved 48% thermal efficiency for turbine inlet conditions of 650°C and 290 atm. Power block efficiencies near 60% are feasible with higher turbine inlet temperatures, however a design tradeoff to limit firing temperature to 650°C was made in order to use austenitic stainless steels for the high temperature pressure vessels and piping and to minimize the need for advanced turbomachinery features such as blade cooling. The overall technical readiness of the supercritical oxy-combustion cycle is TRL 2, Technology Concept, due to the maturity level of the supercritical oxy-combustor for solid fuels, and several critical supporting components, as identified in the Technical Gap Analysis. The supercritical oxycombustor for solid fuels operating at pressures near 100 atm is a unique component of the supercritical oxy-combustion cycle. In addition to the low TRL supercritical oxy-combustor, secondary systems were identified that would require adaptation for use with the supercritical oxycombustion cycle. These secondary systems include the high pressure pulverized coal feed, high temperature cyclone, removal of post-combustion particulates from the high pressure cyclone underflow stream, and micro-channel heat exchangers tolerant of particulate loading. Bench scale testing was utilized to measure coal combustion properties at elevated pressures in a CO 2 environment. This testing included coal slurry preparation, visualization of coal injection into a high pressure fluid, and modification of existing test equipment to facilitate the combustion properties testing. Additional bench scale testing evaluated the effectiveness of a rotary atomizer for injecting a coal-water slurry into a fluid with similar densities, as opposed to the typical application where the high density fluid is injected into a low density fluid. The swirl type supercritical oxy-combustor was developed from initial concept to an advanced design stage through numerical simulation using FLUENT and Chemkin to model the flow through the combustor and provide initial assessment of the coal combustion reactions in the flow path. This effort enabled the initial combustor mechanical layout, initial pressure vessel design, and the conceptual layout of a pilot scale test loop. A pilot scale demonstration of the supercritical oxy-combustion cycle is proposed as the next step in the technology development. This demonstration would advance the supercritical oxy-combustion cycle and the supercritical oxy-combustor from a current TRL of 2, Technology Concept, to TRL 6, Pilot Scale System Demonstrated in a Relevant Environment, and enable the evaluation and continued refinement of the supercritical oxy-combustor and critical secondary systems.

42 ENGINEERING↗
DOE OSTI2014

Assessment of the Cast Stone Low-Temperature Waste Form Technology Coupled with Technetium Removal - 14379

The U.S. Department of Energy Office of Environmental Management (EM) is engaging the national laboratories to provide the scientific and technological rigor to support EM program and project planning, technology development and deployment, project execution, and assessment of program outcomes. As an early demonstration of this new responsibility, Pacific Northwest National Laboratory (PNNL) and Savannah River National Laboratory (SRNL) were chartered to implement a science and technology program addressing low-temperature waste forms for immobilization of DOE aqueous waste streams, including technetium removal as an implementing technology. As a first step, the laboratories examined the technical risks and uncertainties associated with the Cast Stone waste immobilization and technetium removal projects at Hanford. Science and technology gaps were identified for work associated with 1) conducting performance assessments and risk assessments of waste form and disposal system performance, and 2) technetium chemistry in tank wastes and separation of technetium from waste processing streams. Technical approaches to address the science and technology gaps were identified and an initial sequencing priority was suggested. A subset of research was initiated in 2013 to begin addressing the most significant science and technology gaps. The purpose of this paper is to report progress made towards closing these gaps and provide notable highlights of results achieved to date.

Cast Stone Low-Temperature Waste Form Technology C↗
DOE OSTI2019

250 kWth Pilot Testing in Support of a 10 MWe Coal-Direct Chemical Looping Demonstration Feasibility Study

The Coal-Direct Chemical Looping (CDCL) process is emerging as a promising technology capable of high efficiency for producing electricity with low cost for carbon capture. In the CDCL process, coal is fully combusted to form carbon dioxide (CO2) and water via reaction with Fe2O3-based oxygen-carrier particles in a moving-bed reducer reactor. During reaction with coal, the Fe2O3 is reduced to form a mixture of Fe and FeO. The reduced particles are then transported to the combustor reactor where they are re-oxidized with air. The oxidation of the Fe and FeO mixture generates heat that can be used to produce steam for power generation. Once the particles are fully regenerated, they are pneumatically recycled to the reducer reactor where another reduction-oxidation (Redox) cycle begins. The Babcock & Wilcox Company (B&W) and The Ohio State University (OSU) have been developing the CDCL technology based on iron-based metal oxide particles circulating in a moving-bed reducer coupled with an entrained-flow combustor. As part of a Phase I effort of a DOE-sponsored project, B&W identified scale-up technology gaps for the coal-direct chemical looping reactor process, most of which fall under the moving-bed reactor design and operation. However, after the Phase I research, B&W concluded that the CDCL technology has the potential of generating electricity while meeting the DOE goals of greater than 90% CO2 capture and less than 35% increase in levelized cost of electricity (LCOE). B&W then moved to a Phase II project to design, build and demonstrate the CDCL technology at a 250 kWth capacity. B&W finished the construction and commissioning of the pilot test facility in 2017. The approach used to design a 250 kWth pilot-scale CDCL facility to investigate the technology gaps is presented. Important lessons from the commissioning activities that would transfer to commercial plant start-up are also shared. The findings from the test program are being incorporated into a Pre-FEED study for a 10 MWe large pilot demonstration. Under a separately-funded heat integration project, B&W and OSU are developing a multiphase computational fluid dynamic model (MFIX) of the combustor to quantify heat transfer to embedded steam generation surface, utilizing pinch analysis (ASPEN Energy Analyzer) to identify potential improvements of the heat integration scheme, and developing an integrated dynamic model (ProTRAX) of the steam turbine coupled with the chemical looping process to identify potential start-up and transient operation issues. Under an advanced control system for optimizing operation, B&W is supporting OSU to install a rules-based optimizer (B&W’s FocalPoint) on their 25 kWt bench-scale facility on the OSU West Campus. Finally, B&W and OSU were recently selected to perform a Phase I Feasibility study to evaluate installation of the 10 MWe pilot at the Dover Power & Light Municipal Power Plant in Dover, Ohio. The feasibility study includes compiling an Environmental Information Volume and generating a cost estimate for the design, construction and commissioning of the plant as well as lining up commitments from potential project participants and funding contributors. Updates on each project will be presented. The status of the technology development will be discussed. We focus on the progress made to date towards closing the technology gaps under each project.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2018

Update on Design of 10 MWe Iron-Based Coal Direct Chemical Looping Demonstration Plant

The Coal-Direct Chemical Looping (CDCL) process is emerging as a promising technology capable of high efficiency for producing electricity with low cost for carbon capture. In the CDCL process, coal is fully combusted to form carbon dioxide (CO2) and water via reaction with Fe2O3-based oxygen-carrier particles in a moving-bed reducer reactor. During reaction with coal, the Fe2O3 is reduced to form a mixture of Fe and FeO. The reduced particles are then transported to the combustor reactor where they are re-oxidized with air. The oxidation of the Fe and FeO mixture generates heat that can be used to produce steam for power generation. Once the particles are fully regenerated, they are pneumatically recycled to the reducer reactor where another reduction-oxidation (Redox) cycle begins. The Babcock & Wilcox Company (B&W) and The Ohio State University (OSU) have been developing the CDCL technology based on iron-based metal oxide particles circulating in a moving-bed reducer coupled with an entrained-flow combustor. As part of a Phase I effort of a DOE-sponsored project, B&W identified scale-up technology gaps for the coal-direct chemical looping reactor process, most of which fall under the moving-bed reactor design and operation. However, after the Phase I research, B&W concluded that the CDCL technology has the potential of generating electricity while meeting the DOE goals of greater than 90% CO2 capture and less than 35% increase in levelized cost of electricity (LCOE). B&W then moved to a Phase II project to design, build and demonstrate the CDCL technology at a 250 kWth capacity. B&W finished the construction and commissioning of the pilot test facility in 2017. The approach used to design a 250 kWth pilot-scale CDCL facility to investigate the technology gaps is presented. Important lessons from the commissioning activities that would transfer to commercial plant start-up are also shared. The findings from the test program are being incorporated into a Pre-FEED study for a 10 MWe large pilot demonstration. Under a separately-funded heat integration project, B&W and OSU are developing a multiphase computational fluid dynamic model (MFIX) of the combustor to quantify heat transfer to embedded steam generation surface, utilizing pinch analysis (ASPEN Energy Analyzer) to identify potential improvements of the heat integration scheme, and developing an integrated dynamic model (ProTRAX) of the steam turbine coupled with the chemical looping process to identify potential start-up and transient operation issues. Under an advanced control system for optimizing operation, B&W is supporting OSU to install a rules-based optimizer (B&W’s FocalPoint) on their 25 kWt bench-scale facility on the OSU West Campus. Finally, B&W and OSU were recently selected to perform a Phase I Feasibility study to evaluate installation of the 10 MWe pilot at the Dover Power & Light Municipal Power Plant in Dover, Ohio. The feasibility study includes compiling an Environmental Information Volume and generating a cost estimate for the design, construction and commissioning of the plant as well as lining up commitments from potential project participants and funding contributors. Updates on each project will be presented. The status of the technology development will be discussed. We focus on the progress made to date towards closing the technology gaps under each project.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2024

Consortium to Assess Northern Appalachian Resource Yield (CANARY) of CORE-CM for Advanced Materials

The Consortium to Assess Northern Appalachian Resource Yield (CANARY) of CORE-CM for Advanced Materials is conducted by Penn State and its partners. The objectives of the project are to 1) assess and catalog Northern Appalachian (NA) basin CORE-CM resources and waste streams, 2) develop strategies to recover CORE-CM from these streams, 3) assess the infrastructure, industries, and businesses in the NA basin to determine CORE-CM supply chain gaps, 4) review technology gaps related to CORE-CM production, 5) formulate plans to establish Technology Innovation Centers, and 6) develop stakeholder outreach and engagement in educational activities. This final report documents the work conducted throughout the project.

99 GENERAL AND MISCELLANEOUS↗