Materials Data on TeCF3 by Materials Project
CTeF3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight trifluoromethanetellurol molecules. C4+ is bonded in a distorted trigonal non-coplanar geometry to one Te1- and three F1- atoms. The C–Te bond length is 2.22 Å. All C–F bond lengths are 1.36 Å. Te1- is bonded in a distorted single-bond geometry to one C4+ atom. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one C4+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one C4+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one C4+ atom.
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