Materials Data on TcNO2 by Materials Project
TcNO2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional and consists of two TcNO2 frameworks. Tc7+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent O2- atoms. All Tc–O bond lengths are 2.02 Å. N3- is bonded in a distorted linear geometry to two equivalent O2- atoms. Both N–O bond lengths are 1.69 Å. O2- is bonded in a 3-coordinate geometry to two equivalent Tc7+ and one N3- atom.
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