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DOE OSTI2020

Materials Data on TbVO2 by Materials Project

TbVO2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Tb is bonded to six equivalent O atoms to form edge-sharing TbO6 octahedra. There are four shorter (2.34 Å) and two longer (2.36 Å) Tb–O bond lengths. V is bonded in a square co-planar geometry to four equivalent O atoms. All V–O bond lengths are 2.20 Å. O is bonded to three equivalent Tb and two equivalent V atoms to form a mixture of distorted corner and edge-sharing OTb3V2 trigonal bipyramids.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on TbVO2 by Materials Project

TbVO2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Tb is bonded in a distorted hexagonal planar geometry to six equivalent O atoms. There are two shorter (2.27 Å) and four longer (2.46 Å) Tb–O bond lengths. V is bonded in a linear geometry to two equivalent O atoms. Both V–O bond lengths are 1.88 Å. O is bonded to three equivalent Tb and one V atom to form a mixture of distorted corner and edge-sharing OTb3V tetrahedra.

36 MATERIALS SCIENCE↗