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TbPd is alpha-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Tb is bonded in a 7-coordinate geometry to seven equivalent Pd atoms. There are a spread of Tb–Pd bond distances ranging from 2.94–3.02 Å. Pd is bonded in a 7-coordinate geometry to seven equivalent Tb atoms.
TbPd is alpha-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Tb is bonded in a 7-coordinate geometry to seven equivalent Pd atoms. There are a spread of Tb–Pd bond distances ranging from 2.88–3.05 Å. Pd is bonded in a 7-coordinate geometry to seven equivalent Tb atoms.