Materials Data on Tb(GeRh)2 by Materials Project
TbRh2Ge2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Tb is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Ge atoms. All Tb–Rh bond lengths are 3.33 Å. All Tb–Ge bond lengths are 3.19 Å. Rh is bonded to four equivalent Tb and four equivalent Ge atoms to form a mixture of distorted edge, face, and corner-sharing RhTb4Ge4 tetrahedra. All Rh–Ge bond lengths are 2.47 Å. Ge is bonded in a 9-coordinate geometry to four equivalent Tb, four equivalent Rh, and one Ge atom. The Ge–Ge bond length is 2.53 Å.