Materials Data on TaNCl6 by Materials Project
(TaCl6)2N2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonia molecules and four TaCl6 clusters. In each TaCl6 cluster, Ta5+ is bonded in an octahedral geometry to six equivalent Cl1- atoms. All Ta–Cl bond lengths are 2.36 Å. Cl1- is bonded in a single-bond geometry to one Ta5+ atom.
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