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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Field Testing of Compartmentalization Methods for Multifamily Construction

The 2012 International Energy Conservation Code (IECC) has an airtightness requirement of 3 air changes per hour at 50 Pascals test pressure (3 ACH50) for single-family and multifamily construction (in climate zones 3–8). The Leadership in Energy & Environmental Design certification program and ASHRAE Standard 189 have comparable compartmentalization requirements. ASHRAE Standard 62.2 will soon be responsible for all multifamily ventilation requirements (low rise and high rise); it has an exceptionally stringent compartmentalization requirement. These code and program requirements are driving the need for easier and more effective methods of compartmentalization in multifamily buildings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

'Smart' Irrigation Systems

The article discusses the ASHRAE Standard 189, with mandatory and optional provisions related to water use efficiency, then focuses on the use of water efficient irrigation systems and the use of recycled water such as air conditioner condensate for landscaping irrigation. Benefits of such practices include both water and energy savings.

Air Conditioner Condensate↗

DOAS, Radiant Cooling Revisited

The article discusses dedicated outdoor air systems (DOAS) and radiant cooling technologies. Both of these topics were covered in previous ASHRAE Journal columns. This article reviews the technologies and their increasing acceptance. The two steps that ASHRAE is taking to disseminate DOAS information to the design community, available energy savings and the market potential of radiant cooling systems are addressed as well.

Air Conditioner Condensate↗

Equatorial UBVRI photoelectric sequences

From 1335 BVRI observations of 189 stars in selected areas 92-115, Landolt's (1973) network of faint UBV standards has been extended to R I. Of these stars, 173 have four or more observations. The (U-B) values of Landolt are adopted, and a well-observed equatorial faint-star network is presented on the Johnson UBVRI photometric system.

Moffett, T. J.↗

The response of thermally and optically stimulated luminescence from Al2O3:C to high-energy heavy charged particles

The thermoluminescence (TL) and optically stimulated luminescence (OSL) response of Al2O3 dosimeters to high-energy heavy charged particles (HCP) has been studied using the heavy ion medical accelerator at Chiba, Japan. The samples were Al2O3 single-crystal chips, of the type usually known as TLD-500, and Luxel(TM) dosimeters (Al2O3:C powder in plastic) from Landauer Inc. The samples were exposed to 4He (150 MeV/u), 12C (400 MeV/u), 28Si (490 MeV/us) and 56Fe (500 MeV/u) ions, with linear energy transfer values covering the range from 2.26 to 189 keV/micrometers in water and doses from 1 to 100 mGy (to water). A 90Sr/90Y beta source, calibrated against a 60Co secondary standard, was used for calibration purposes. For OSL, we used both continuous-wave OSL measurements (CW-OSL, using green light stimulation at 525 nm) and pulsed OSL measurements (POSL, using 532 nm stimulation from a Nd:YAG Q-switched laser). The efficiencies (eta HCP, gamma) of the different HCPs at producing OSL or TL were observed to depend not only upon the linear energy transfer (LET) of the HCP, but also upon the sample type (single crystal chip or Luxel(TM)) and the luminescence method used to define the signal--i.e. TL, CW-OSL initial intensity, CW-OSL total area, or POSL. Observed changes in shape of the decay curve lead to potential methods for extracting LET information of unknown radiation fields. A discussion of the results is given, including the potential use of OSL from Al2O3 in the areas of space radiation dosimetry and radiation oncology. c2004 Elsevier Ltd. All rights reserved.

Heavy Ions↗

First Measurement of R ( X τ / ℓ ) as an Inclusive Test of the b → c τ ν Anomaly

We measure the tau-to-light-lepton ratio of inclusive B -meson branching fractions R ( X τ / ℓ ) ≡ B ( B → X τ ν ) / B ( B → X ℓ ν ) , where ℓ indicates an electron or muon, and thereby test the universality of charged-current weak interactions. We select events that have one fully reconstructed B meson and a charged lepton candidate from 189 fb − 1 of electron-positron collision data collected with the Belle II detector. We find R ( X τ / ℓ ) = 0.228 ± 0.016 ( stat ) ± 0.036 ( syst ) , in agreement with standard-model expectations. This is the first direct measurement of R ( X τ / ℓ ) . Published by the American Physical Society 2024

Physics↗

Long-Term Creep Behavior of a CoCrFeNi Medium-Entropy Alloy

We report that current research shows that high-entropy alloys (HEAs) can offer superior oxidation resistance compared to more traditional austenitic stainless steels with equivalent tensile mechanical performance. While many reports have been published on creep of CoCrFeNiMn, few focus on the CoCrFeNi family of low to medium entropy alloys. In this manuscript, uniaxial tensile creep test results for more than 46,000 accumulated hours are presented on the equiatomic CoCrFeNi alloy. The alloy was manufactured at NETL using a vacuum induction melt solidification approach with a computationally designed homogenization cycle. After completing the homogenization cycle, the ingot was first hot forged and then hot rolled into 10 mm thick plate, a product form that is relevant to many industries. Creep tests were performed in the temperature range of 600-650 °C using applied stresses from 120 to 189 MPa. This study builds upon previous results on the CoCrFeNiMn family of high-entropy alloys and offers a modicum of clarification about performance compared to small button melts by using ASTM standard test procedures and mechanical test specimens. The apparent creep activation energy and creep stress exponent were similar to those for CoCrFe medium-entropy and CoCrFeNiMn high-entropy alloys. The post-test creep microstructure showed some Cr segregation, which has also been noted for other CoCrFe alloys. The CoCrFeNi alloy also presents a double minimum or two minimum creep rate phenomena.

36 MATERIALS SCIENCE↗

Solidification of spent ion exchange resins into the SIAL matrix at the Dukovany NPP, Czech Republic

Based on the decision of the State Office for Nuclear Safety, the Dukovany NPP has been obliged to secure the efficient capacities for the disposal of spent ion exchange resins. Therefore, in September 2010, based on the contract with supplier company AMEC Nuclear Slovakia s.r.o. has begun with pumping and treatment of ion exchange resins from the storage tank 0TW30B02, situated in the auxiliary building. The SIAL{sup R} technology, developed in AMEC Nuclear Slovakia, has been used for the solidification purposes. This technology allows an on-site treatment of various special radioactive waste streams (resins, sludge, sludge/resins and borates) at the room temperature. The SIAL{sup R} matrix and technology were licensed by the Czech State Office for Nuclear Safety in 2007. On-site treatment and solidification of spent ion exchange resins at Dukovany NPP involves process of resin removal from tank using remotely operated manipulator, resin transportation, resin separation from free water, resin filling into 200 dm{sup 3} drums and solidification into SIAL{sup R} matrix in 200 dm{sup 3} drums using the FIZA S 200 facility. The final product is observed for compressive strength, leachability, radionuclide composition, dose rate, solids and total weight. After meeting the requirements for final disposal and consolidation, the drums are being transported for the final disposal to the Repository at Dukovany site. During the 3 month's trial operation in 2010, and the normal operation in 2011 and 2012, 189 tons of dewatered resins have been treated into 1960 drums, with total activity higher than 920 GBq. At the end of trial run (2010), 22 tons of dewatered resins were treated into 235 drums. During standard operation approximately 91 tons in 960 drums (2011) and 76 tons in 765 drums (2012) were treated. The weights of resins in the drum ware in the range from 89 - 106 kg and compressive strength limit (10 MPa) has already been achieved 24 hours after fixation. The final measured strength values ranged from 19.0 - 34.7 MPa and real leachability values ranged from 0.03 - 0.65%, far below the 4% limit value. Collective effective dose of all workers in 2012 was 7.7 mSv (12.6 mSv in 2011, 6.2 mSv in 2010). Average individual effective dose in 2012 was 0.55 mSv (14 workers), and maximal individual effective dose was 2.25 mSv. This approach allows fast, safe and cost effective immobilization and transformation of dangerous radioactive waste such as sludge and resins into the solid form, which is suitable for long term storage or disposal. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Search for Dark Matter Induced Deexcitation of 180 Ta m

Weak-scale dark matter particles, in collisions with nuclei, can mediate transitions between different nuclear energy levels. In particular, owing to sizeable momentum exchange, dark matter particles can enable de-excitation of nuclear isomers that are extremely long lived with respect to regular radioactive decays. In this paper, we utilize data from a past experiment with 180 Ta m to search for γ-lines that would accompany dark matter induced de-excitation of this isomer. Non-observation of such transitions above background yields the first direct constraint on the lifetime of 180 Ta m against DM-initiated transitions: T 1/2 > 1.3 × 10 14 a at 90% C.I. Using this result, we derive novel constraints on dark matter models with strongly interacting relics, and on models with inelastic dark matter particles. Existing constraints are strengthened by this independent new method. As a result, the obtained limits are also valid for the Standard Model γ-decay of 180 Ta m .

150 ≤ A ≤ 189↗

Benzyl trichloroacetimidates as derivatizing agents for phosphonic acids related to nerve agents by EI-GC-MS during OPCW proficiency test scenarios

Abstract The use of benzyl trichloroacetimidates for the benzylation of phosphonic acid nerve agent markers under neutral, basic, and slightly acidic conditions is presented. The benzyl-derived phosphonic acids were detected and analyzed by Electron Ionization Gas Chromatography–Mass Spectrometry (EI-GC–MS). The phosphonic acids used in this work included ethyl-, cyclohexyl- and pinacolyl methylphosphonic acid, first pass hydrolysis products from the nerve agents ethyl N -2-diisopropylaminoethyl methylphosphonothiolate (VX), cyclosarin (GF) and soman (GD) respectively. Optimization of reaction parameters for the benzylation included reaction time and solvent, temperature and the effect of the absence or presence of catalytic acid. The optimized conditions for the derivatization of the phosphonic acids specifically for their benzylation, included neutral as well as catalytic acid (< 5 mol%) and benzyl 2,2,2-trichloroacetimidate in excess coupled to heating the mixture to 60 °C in acetonitrile for 4 h. While the neutral conditions for the method proved to be efficient for the preparation of the p -methoxybenzyl esters of the phosphonic acids, the acid-catalyzed process appeared to provide much lower yields of the products relative to its benzyl counterpart. The method’s efficiency was tested in the successful derivatization and identification of pinacolyl methylphosphonic acid (PMPA) as its benzyl ester when present at a concentration of ~ 5 μg/g in a soil matrix featured in the Organisation for the Prohibition of Chemical Weapons (OPCW) 44th proficiency test (PT). Additionally, the protocol was used in the detection and identification of PMPA when spiked at ~ 10 μg/mL concentration in a fatty acid-rich liquid matrix featured during the 38 th OPCW-PT. The benzyl derivative of PMPA was partially corroborated with the instrument's internal NIST spectral library and the OPCW central analytical database (OCAD v.21_2019) but unambiguously identified through comparison with a synthesized authentic standard. The method’s MDL (LOD) values for the benzyl and the p -methoxybenzyl pinacolyl methylphosphonic acids were determined to be 35 and 63 ng/mL respectively, while the method’s Limit of Quantitation (LOQ) was determined to be 104 and 189 ng/mL respectively in the OPCW-PT soil matrix evaluated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Improved ligand geometries in crystallographic refinement using AFITT in PHENIX

Modern crystal structure refinement programs rely on geometry restraints to overcome the challenge of a low data-to-parameter ratio. While the classical Engh and Huber restraints work well for standard amino-acid residues, the chemical complexity of small-molecule ligands presents a particular challenge. Most current approaches either limit ligand restraints to those that can be readily described in the Crystallographic Information File (CIF) format, thus sacrificing chemical flexibility and energetic accuracy, or they employ protocols that substantially lengthen the refinement time, potentially hindering rapid automated refinement workflows. PHENIX – AFITT refinement uses a full molecular-mechanics force field for user-selected small-molecule ligands during refinement, eliminating the potentially difficult problem of finding or generating high-quality geometry restraints. It is fully integrated with a standard refinement protocol and requires practically no additional steps from the user, making it ideal for high-throughput workflows. PHENIX – AFITT refinements also handle multiple ligands in a single model, alternate conformations and covalently bound ligands. Here, the results of combining AFITT and the PHENIX software suite on a data set of 189 protein–ligand PDB structures are presented. Refinements using PHENIX – AFITT significantly reduce ligand conformational energy and lead to improved geometries without detriment to the fit to the experimental data. Finally, for the data presented, PHENIX – AFITT refinements result in more chemically accurate models for small-molecule ligands.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Uncertainty-quantified phenomenological optical potentials for single-nucleon scattering

Optical-model potentials (OMPs) continue to play a key role in nuclear reaction calculations. However, the uncertainty of phenomenological OMPs in widespread use—inherent to any parametric model trained on data—has not been fully characterized, and its impact on downstream users of OMPs remains unclear. Here we assign well-calibrated uncertainties for two representative global OMPs, those of Koning-Delaroche and Chapel Hill '89, using Markov-chain Monte Carlo for parameter inference. By comparing the canonical versions of these OMPs against the experimental data originally used to constrain them, we show how a lack of outlier rejection and a systematic underestimation of experimental uncertainties contributes to bias of, and overconfidence in, best-fit parameter values. Our updated, uncertainty-quantified versions of these OMPs address these issues and yield complete covariance information for potential parameters. Scattering predictions generated from our ensembles show improved performance both against the original training corpora of experimental data and against a new “test” corpus comprising many of the experimental single-nucleon scattering data collected over the last twenty years. Finally, we apply our uncertainty-quantified OMPs to two case studies of application-relevant cross sections. We conclude that, for many common applications of OMPs, including OMP uncertainty should become standard practice. Furthermore, to facilitate their immediate use, digital versions of our updated OMPs and related tools for forward uncertainty propagation are included as Supplemental Material.

150 ≤ A ≤ 189↗

Test of Light-Lepton Universality in the Rates of Inclusive Semileptonic B-Meson Decays at Belle II

We present the first measurement of the ratio of branching fractions of inclusive semileptonic B -meson decays, R ( X e / μ ) = B ( B → X e ν ) / B ( B → X μ ν ) , a precision test of electron-muon universality, using data corresponding to 189 fb - 1 from electron-positron collisions collected with the Belle II detector. In events where the partner B meson is fully reconstructed, we use fits to the lepton momentum spectra above 1.3 GeV / c to obtain R ( X e / μ ) = 1.007 ± 0.009 ( stat ) ± 0.019 ( syst ) , which is the most precise lepton-universality test of its kind and agrees with the standard-model expectation.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Using A Guided Interview to Create an Individual Exposure Profile for The Lifetime Surveillance of Astronaut Health (LSAH)

BACKGROUND To support NASA’s Lifetime Surveillance of Astronaut Health (LSAH) project, Individual Exposure Profiles (IEPs) were developed to record an astronaut’s pre-, in-, and post-NASA exposures. NASA astronauts were invited to participate in a one-time guided interview to review known hazard exposures and medical history documented in NASA records and to add new information not otherwise reported. The purpose of the IEP project was to determine if any significant information was gained from these interviews and identify potential trends in long-term health. METHODOLOGY The pre-filled exposure profile data was extracted from several sources including medical records, biographies, and LSAH records. The information that was pre-filled before the interview included occupational exposures prior to selection to the Astronaut Corps, during active astronaut career (e.g., EVA and ground-based training, on-orbit exposures), and after active career. The IEPs also contained relevant medical history (e.g., audiometry, illnesses, injuries) and significant non-occupational exposures. 189 interviews were conducted from 2012-2014. A Microsoft Access database was created to store the information collected in the IEPs before and after the interviews. The database houses the information from the IEPs to track the updates made to the original data. By analyzing which astronauts supplied additional information and which kinds of data were consistently added, potential gaps and trends in missing data may be identified. In designing the database, an efficient structure was implemented for ease of inputting data and to create variables that would generate quantifiable data. Creating standardized variables within the structure helped ease the process of inputting, organizing data, and analyzing data. Additional updates/data were denoted and were categorized by type of update. The categories identified were “Confirmed”, “Confirmed & Supplemented”, “Supplemented”, “Denied”, “Denied & Supplemented”, and “Other”. STATISTICAL ANALYSIS AND RESULTS To assess frequency of exposure updates, descriptive statistics will be generated and stratified by relevant factors such as astronaut selection decade, age at selection, and program/era. Hypothesis testing will be performed to understand the associations between updates to exposure information and population characteristics.

Astronaut health↗

Test of lepton flavor universality with a measurement of R ( D * ) using hadronic B tagging at the Belle II experiment

The ratio of branching fractions R ( D * ) = B ( B ¯ → D * τ − ν ¯ τ ) / B ( B ¯ → D * ℓ − ν ¯ ℓ ) , where ℓ is an electron or muon, is measured using a Belle II data sample with an integrated luminosity of 189 fb − 1 at the SuperKEKB asymmetric-energy e + e − collider. Data is collected at the ϒ ( 4 S ) resonance, and one B meson in the ϒ ( 4 S ) → B B ¯ decay is fully reconstructed in hadronic decay modes. The accompanying signal B meson is reconstructed as B ¯ → D * τ − ν ¯ τ using leptonic τ decays. The normalization decay, B ¯ → D * ℓ − ν ¯ ℓ , produces the same observable final-state particles. The ratio of branching fractions is extracted in a simultaneous fit to two signal-discriminating variables in both channels and yields R ( D * ) = 0.262 − 0.039 + 0.041 ( stat ) − 0.032 + 0.035 ( syst ) . This result is consistent with the current world average and with Standard Model predictions. Published by the American Physical Society 2024

Adachi, I. (ORCID:0000000322870173)↗

Measurement of the 175 Hf half-life

Hafnium-175 is a useful radioisotope for numerous applications; however, its evaluated half-life (70 ± 2 days) has a large uncertainty. To enable a new measurement of the half-life, 175 Hf was produced via proton irradiation of natural lutetium and chemically purified. The 175 Hf sample was counted approximately once a month with three high-purity germanium detectors for 13 months (~5.5 half-lives). A 133 Ba standard was counted in an identical manner to quantify systematic uncertainties over the measurement period. In conclusion, the measured 175 Hf half-life is 69.90 ± 0.07 days, in agreement with the evaluated value, but with significantly reduced uncertainty.

150 ≤ A ≤ 189↗

Wastewater Treatment at the Fernald Preserve-Past, Present, and Future - 19555

Industrial wastewater treatment at the Fernald Preserve, Ohio, Site has been ongoing since a uranium metals refinery was constructed there at the beginning of the Cold War in 1951. Initially, the primary purpose of treatment was to recover uranium for reuse. Later, when cleanup of the site was progressing in the 1990's, wastewater treatment efforts greatly expanded. Large treatment facilities were constructed to handle contaminated surface water, groundwater, remediation wastewater, and leachate from the on-site disposal facility. These new facilities were designed to reduce uranium concentration to meet the US Environmental Protection Agency (EPA) drinking water standard and not generate large quantities of contaminated waste. Anion-exchange resin was chosen as the treatment media. The centerpiece of these facilities was the Advanced Wastewater Treatment facility, which had a treatment capacity of 10,978 liters per minute (lpm) (2900 gallons per minute [gpm]). Forecasts estimated that with the exception of groundwater the site's remediation would be completed in 2006. In 2003, the US Department of Energy (DOE) Office of Environmental Management began negotiations with the EPA and Ohio Environmental Protection Agency to reduce wastewater treatment capacity at the Fernald Environmental Management Project. These negotiations resulted in the site's treatment capacity being reduced to 6814 lpm (1800 gpm) via the Converted Advanced Wastewater Treatment facility (CAWWT). By 2010, the uranium concentration in the groundwater being pumped had been reduced to the degree that only intermittent treatment for uranium removal was needed. As a result, the CAWWT was considerably oversized. Increased maintenance on the aging CAWWT equipment led the DOE Office of Legacy Management (LM) to commission an assessment of the facility, which was completed in early 2015. The condition assessment identified numerous components at or near the end of their design life. Based on the assessment's findings and the fact that the current facility's treatment capacity was substantially greater than needed, LM began looking at options for an appropriately sized treatment system to handle the site's needs until the groundwater remediation was completed (currently projected for 2039). Options were evaluated in the spring of 2015, and LM presented the recommended changes to regulators and stakeholders. Approvals for a new, smaller system with a 189 lpm (50 gpm) capacity were obtained through a series of meetings in the summer of 2015. After more detailed planning in the fall of 2015, LM initiated the project in 2016. The project comprises the following four phases: (1) Removal and disposal of used media, piping, and tanks to make room for the new system in the existing building (completed in January 2017); (2) design of the new system (completed in April 2017); (3) construction, installation, and startup of the new system (completed in May 2018); and (4) backwash basin refurbishment (yet to be completed). In the late 2030's, when groundwater remediation is projected to be completed at the site, it is anticipated that the only remaining wastewater treatment need will be for small quantities of leachate from the on-site disposal facility. Results of leachate treatment testing in 2003 indicate it may be feasible to utilize a small passive treatment system for this leachate. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗