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Materials Data on SrU by Materials Project

SrU crystallizes in the trigonal R3m space group. The structure is two-dimensional and consists of three SrU sheets oriented in the (0, 0, 1) direction. Sr is bonded in a 9-coordinate geometry to six equivalent Sr and three equivalent U atoms. All Sr–Sr bond lengths are 3.44 Å. All Sr–U bond lengths are 3.69 Å. U is bonded in a 9-coordinate geometry to three equivalent Sr and six equivalent U atoms. All U–U bond lengths are 3.44 Å.

36 MATERIALS SCIENCE↗

Materials Data on SrU(SeO5)2 by Materials Project

SrU(SeO5)2 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Sr2+ is bonded in a 5-coordinate geometry to eight O2- atoms. There are a spread of Sr–O bond distances ranging from 2.41–3.17 Å. U6+ is bonded in a 7-coordinate geometry to seven O2- atoms. There are a spread of U–O bond distances ranging from 1.82–2.62 Å. There are two inequivalent Se6+ sites. In the first Se6+ site, Se6+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Se–O bond distances ranging from 1.72–1.75 Å. In the second Se6+ site, Se6+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There are a spread of Se–O bond distances ranging from 1.68–1.79 Å. There are ten inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to one Sr2+ and one U6+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one U6+ atom. In the third O2- site, O2- is bonded in a bent 120 degrees geometry to one U6+ and one Se6+ atom. In the fourth O2- site, O2- is bonded in a 3-coordinate geometry to one Sr2+, one U6+, and one Se6+ atom. In the fifth O2- site, O2- is bonded in a 3-coordinate geometry to two equivalent U6+ and one Se6+ atom. In the sixth O2- site, O2- is bonded in a bent 120 degrees geometry to one Sr2+ and one Se6+ atom. In the seventh O2- site, O2- is bonded in a bent 150 degrees geometry to one U6+ and one Se6+ atom. In the eighth O2- site, O2- is bonded in a distorted trigonal planar geometry to two equivalent Sr2+ and one Se6+ atom. In the ninth O2- site, O2- is bonded in a 1-coordinate geometry to one Sr2+ and one O2- atom. The O–O bond length is 1.23 Å. In the tenth O2- site, O2- is bonded in a 1-coordinate geometry to two equivalent Sr2+ and one O2- atom. The O–O bond length is 1.25 Å.

36 MATERIALS SCIENCE↗

Materials Data on SrU(PS4)2 by Materials Project

SrU(PS4)2 is Zircon-derived structured and crystallizes in the tetragonal P4_2/mbc space group. The structure is three-dimensional. Sr2+ is bonded in a distorted body-centered cubic geometry to eight S2- atoms. There are four shorter (3.11 Å) and four longer (3.24 Å) Sr–S bond lengths. U4+ is bonded in a 8-coordinate geometry to eight S2- atoms. There are four shorter (2.77 Å) and four longer (2.97 Å) U–S bond lengths. P5+ is bonded in a tetrahedral geometry to four S2- atoms. There are a spread of P–S bond distances ranging from 2.02–2.08 Å. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a 1-coordinate geometry to two equivalent U4+ and one P5+ atom. In the second S2- site, S2- is bonded in a 3-coordinate geometry to two equivalent Sr2+ and one P5+ atom. In the third S2- site, S2- is bonded in a 3-coordinate geometry to one Sr2+, one U4+, and one P5+ atom.

36 MATERIALS SCIENCE↗

Materials Data on SrU(MoO4)4 by Materials Project

SrUMo4O16 crystallizes in the monoclinic P2/c space group. The structure is three-dimensional. Sr2+ is bonded to seven O2- atoms to form SrO7 pentagonal bipyramids that share corners with two equivalent UO7 pentagonal bipyramids. There are a spread of Sr–O bond distances ranging from 2.48–2.58 Å. U6+ is bonded to seven O2- atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent SrO7 pentagonal bipyramids. There are a spread of U–O bond distances ranging from 1.82–2.47 Å. There are two inequivalent Mo6+ sites. In the first Mo6+ site, Mo6+ is bonded in a 5-coordinate geometry to six O2- atoms. There are a spread of Mo–O bond distances ranging from 1.74–2.59 Å. In the second Mo6+ site, Mo6+ is bonded in a 6-coordinate geometry to six O2- atoms. There are a spread of Mo–O bond distances ranging from 1.73–2.58 Å. There are nine inequivalent O2- sites. In the first O2- site, O2- is bonded in a bent 150 degrees geometry to one Sr2+ and one Mo6+ atom. In the second O2- site, O2- is bonded in a linear geometry to one Sr2+ and one U6+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to two Mo6+ atoms. In the fourth O2- site, O2- is bonded in a 3-coordinate geometry to one U6+ and two Mo6+ atoms. In the fifth O2- site, O2- is bonded in a 3-coordinate geometry to one U6+ and two equivalent Mo6+ atoms. In the sixth O2- site, O2- is bonded in a 3-coordinate geometry to one Sr2+ and two equivalent Mo6+ atoms. In the seventh O2- site, O2- is bonded in a single-bond geometry to two Mo6+ atoms. In the eighth O2- site, O2- is bonded in a 3-coordinate geometry to one Sr2+ and two Mo6+ atoms. In the ninth O2- site, O2- is bonded in a distorted bent 150 degrees geometry to one U6+ and one Mo6+ atom.

36 MATERIALS SCIENCE↗

Inter-well connectivity detection in CO 2 WAG projects using statistical recurrent unit models

Routine well-wise injection and production measurements contain significant information on subsurface structure and properties. Data-driven technology that interprets surface data into subsurface structure or properties can assist operators in making informed decisions by providing a better understanding of field assets. Our machine-learning framework is built on the statistical recurrent unit (SRU) model and interprets well-based injection/production data into inter-well connectivity without relying on a geologic model. We test it on synthetic and field-scale CO 2 EOR projects utilizing the water-alternating-gas (WAG) process. SRU is a special type of recurrent neural network (RNN) that allows for better characterization of temporal trends, by learning various statistics of the input at different time scales. In our application, the complete states (injection rate, pressure and cumulative injection) at injectors and pressure states at producers are fed to SRU as the input and the phase rates at producers are treated as the output. Once the SRU is trained and validated, it is then used to assess the connectivity of each injector to any producer using permutation variable importance method, wherein inputs corresponding to an injector are shuffled and the increase in prediction error at a given producer is recorded as the importance (connectivity metric) of the injector to the producer. This method is tested in both synthetic and field-scale cases. The validation of the proposed data-driven inter-well connectivity assessment is performed using synthetic data from simulation models where inter-well connectivity can be easily measured using the streamline-based flux allocation. The SRU model is shown to offer excellent prediction performance on the synthetic case. Despite significant measurement noise and frequent well shut-ins imposed in the field-scale case, the SRU model offers good prediction accuracy, the overall relative error of the phase production rates at most producers ranges from 10% to 30%. It is shown that the dominant connections identified by the data-driven method and streamline method are in close agreement. This significantly improves confidence in our data-driven procedure. The novelty of this work is that it is purely data-driven method and can directly interpret routine surface measurements to intuitive subsurface knowledge. Furthermore, the streamline-based validation procedure provides physics-based backing to the results obtained from data analytics. This study results in a reliable and efficient data analytics framework that is well-suited for large field applications.

42 ENGINEERING↗

Cassini Star Tracking and Identification Algorithms, Scene Simulation, and Testing

The Cassini mission will use autonomous star identification for initial attitude determination and a star tracking function for maintaining attitude. Because of the complexity of the StarID software, special software simulation tools were created to simulate the Stellar Reference Unit (SRU) output as a function of commands, spacecraft attitude, and star scene, and to allow the introduction of fault conditions. This paper gives the overview of the algorithm design and SRU simulation and a description of the simulation test results and a comparison with field test results obtained using the engineering model SRU.

Cassini↗

Robust Carbon Dioxide Plume Imaging Using Joint Tomographic Inversion of Seismic Onset Time and Distributed Pressure and Temperature Measurements (Final Report)

We develop and demonstrate rapid and cost-effective methodologies for spatiotemporal tracking of CO2 plumes during geologic sequestration using joint inversion of seismic data and distributed pressure and temperature measurements. Key elements of our methodology are: (a) a computationally efficient approach to pressure and temperature propagation, (b) analysis of time lapse seismic data using a novel ‘seismic onset time’ approach to detect fluid front propagation, and (c) data assimilation and uncertainty assessment via joint inversion of pressure, temperature and time lapse seismic data, and (d) validating the numerical tomographic inversion using a CO2 injection demonstration projects, specifically data collected from the from the Petra Nova Parish Holdings CCUS project in the West Ranch Field, Texas and the Chester-16 reef CO2 injection site in Northern Michigan which is part of the DOE Midwestern Carbon Sequestration Project. The research team is led by Texas A&M University and includes Battelle as a subcontractor with support from Shell, Anadarko, Chevron and JX Nippon. A carbon dioxide (CO2) water-alternating-gas (WAG) pilot was conducted to gain insights into tertiary oil recovery potential via CO2 flood in the West Ranch Field as part of the Petra Nova project, the world’s largest post-combustion CO2 capture and utilization initiative. With a fluvial formation geology and large contrasts in permeability, this is a challenging and novel application of CO2 enhanced oil recovery (EOR). We build a predictive dynamic model of the subsurface that incorporates the multiphase and compositional data acquired during the pilot operation. The calibrated model is used for the carbon dioxide plume imaging. The study began with an initialization of the pilot sector model extracted from a calibrated full-field model. The pilot model calibration follows a two-step hierarchical workflow. First, we performed a large-scale update of the permeability distribution by integrating available bottomhole pressure and multiphase production data. In the second step, local permeability field is fine-tuned using a streamline-based method to match CO2 breakthrough times at the producers. The predictive capability of the calibrated model was verified through two blind validation tests: (1) the model showed good agreement with saturation logs acquired at two observation wells; and (2) the model reproduced the CO2 recovery as a fraction of the injected CO2. The use of seismic onset times has shown great promise for integrating near-continuous seismic surveys for updating geologic models. In this study, we analyze the impact of seismic survey frequency on the onset time approach aiming to extend the application of onset time to infrequent seismic surveys. In addition, we quantitatively examine the nonlinearity of the onset time method and compare it to the commonly used amplitude inversion method. We carry out a sensitivity analysis of seismic survey frequency based on the complete seismic survey data (over 175 surveys) of steam injection in a heavy oil reservoir (Peace River Unit) in Canada. Our results show that an adequate onset time map can be obtained from the infrequent seismic surveys by interpolation between seismic surveys as long as there is no change in the dominant underlying physics between the successive surveys. The study also shows that nonlinearity of the onset time method can be -smaller than that of the amplitude inversion method by several orders of magnitude. Application to the Brugge benchmark case shows that the onset time method obtains comparable permeability update as the traditional seismic amplitude inversion method with faster computation and improved convergence characteristics. We extend the streamline-based data integration approach to incorporate distributed temperature sensor (DTS) data using the concept of thermal tracer travel time. Then, a hierarchical workflow composed of evolutionary and streamline methods is employed to jointly history match the DTS and pressure data. Finally, CO2 saturation and streamline maps are used to visualize the CO2 plume movement during the sequestration process. The hierarchical workflow is applied to a carbon sequestration project in a carbonate reef reservoir within the Northern Niagaran Pinnacle Reef Trend in Michigan, USA. The monitoring data set consists of distributed temperature sensing (DTS) data acquired at the injection well and a monitoring well, flowing bottom-hole pressure data at the injection well, and time-lapse pressure measurements at several locations along the monitoring well. The history matching results indicate that the CO2 movement is mostly restricted to the intended zones of injection which is consistent with an independent warm-back analysis of the temperature data. In addition to employing simulation models and inverse methods for CO2 plume imaging, we also initialized a data-driven technology for detecting inter-well connectivity based on production and pressure data. Our machine-learning framework is built on the statistical recurrent unit (SRU) model and interprets well-based injection/production data into inter-well connectivity without relying on a geologic model. We test it on synthetic and field-scale CO2 EOR projects utilizing the water-alternating-gas (WAG) process. The validation of the proposed data-driven inter-well connectivity assessment is performed using synthetic data from simulation models where inter-well connectivity can be easily measured using the streamline-based flux allocation. The SRU model is shown to offer excellent prediction performance on the synthetic case. Despite significant measurement noise and frequent well shut-ins imposed in the field-scale case, the SRU model offers good prediction accuracy, the overall relative error of the phase production rates at most producers ranges from 10% to 30%. It is shown that the dominant connections identified by the data-driven method and streamline method are in close agreement. Texas A&M University, the lead organization in the project, was primarily responsible for the development of tomographic approaches for CO2 plume mapping in conjunction with distributed pressure, temperature and seismic onset time data. Battelle, as a subcontractor, was primarily responsible for the development of analytical and empirical methods for analyzing transient injection rate and pressure data from point/line sources such as injection and monitoring wells. An additional area of emphasis for Battelle was the use of machine learning for such tasks as inferring reservoir connectivity information from injection-production data, and identifying variable importance for machine learning-based proxy models developed from full-physics simulations. The two organizations also collaborated on the application of the tomographic inversion methodology for a field data set.

02 PETROLEUM↗

Description of the attitude control, guidance and navigation space replaceable units for automated space servicing of selected NASA missions

Control elements such as sensors, momentum exchange devices, and thrusters are described which can be used to define space replaceable units (SRU), in accordance with attitude control, guidance, and navigation performance requirements selected for NASA space serviceable mission spacecraft. A number of SRU's are developed, and their reliability block diagrams are presented. An SRU assignment is given in order to define a set of feasible space serviceable spacecraft for the missions of interest.

Chobotov, V. A.↗

Cassini Stellar Reference Unit: Performance Test Approach and Results

The Cassini Stellar Reference Unit (SRU) is the prime attitude determination sensor on the Cassini spacecraft...To ensure that the SRU will operate within specification for the entire mission, an extensive test program has been undertaken to characterize the SRU performance prior to launch and to quantify any expected performance degradation. Results from several eomplimentary test programs are presented and compared with pre-test performance predictions.

star↗

A real-time multiphysics model of a pressurized solid oxide electrolysis cell (SOEC) for cyber-physical simulation

Solid oxide electrolysis cells (SOEC) can play important roles in integrated energy systems (IES) as the hydrogen production hub and the resilience energy hub. When tied to a microgrid with high renewable penetration, the SOEC is subjected to rapid load transitions in response to the intermittent renewable generations that occur not only in diurnal cycles but also in short timeframes (e.g., sub-minute). The cyber-physical simulation approach can derisk operability research but requires a real-time dynamic SOEC model. In the present work, a real-time multiphysics model for pressurized SOEC is developed and validated in the pressure range from 1.4 to 8bar. Further, the accuracy of the single repeating unit (SRU) assumption in SOEC stack simulation is quantified. A guidance of more than 45 cells in one SOEC stack is recommended to safely apply the SRU assumption. Modeling results suggest that at a given current density, more power is consumed by SOEC at elevated operating pressures. The anode air and cathode stream have major impacts on thermal management, highlighting the potential benefit of integrating SOEC with other thermal processes in IES. To achieve high hydrogen production efficiency, the SOEC could operate at the maximum endothermic point to maximize the use of thermal energy. The real-time execution of the developed SOEC model is also demonstrated, which only takes 0.1% of the fixed time step of 5ms. The developed model establishes the basis for cyber-physical simulation of SOEC hybrid systems.

25 ENERGY STORAGE↗

WIPP Safety Significant Confinement Ventilation System (SSCVS) HEPA Filtration System - 20165

Construction and major equipment fabrication are underway for a new ventilation exhaust system at the Waste Isolation Pilot Plant (WIPP). The new system will provide continuous High Efficiency Particulate Air (HEPA) filtration of the exhaust from the WIPP underground while meeting the ventilation demands for expanded waste emplacement and mining operations over the next 40 years. The integrated system design provides for reducing the salt, clay and diesel particulates from the exhaust airflow from the mine, prior to full filtration using Nuclear Safety Significant HEPA filters. The SSCVS design and equipment provides for continuous HEPA filtration over a wide range of operating and environmental conditions. The new exhaust system connects to the existing underground exhaust shaft, and the exhaust air flows from the underground through Salt Reduction Units (SRUs) to protect the final filter banks from excessive moisture and rapid salt/dust buildup. Each of the six (6) SRUs consists of a demister to remove entrained moisture, a dry salt remover unit to filter approximately 90% of the entrained salt/dust, and an automated water treatment system to periodically clean the demisters and to remove salt from the SRU filters. At the maximum expected exhaust flowrate of 540,000 Cubic Feet per Minute (CFM) / 255 Cubic Meters per Second (m{sup 3}/s), five (5) salt removal units will be in operation with one unit in standby or maintenance. An in-line variable frequency drive booster fan will offset pressure losses through each SRU and reduce the relative humidity of the air exiting the SRUs. In the event of a high radiation alarm from the underground Continuous Air Monitors (CAMs), the SRUs will be automatically bypassed, which places the SRS and building outside of the Safety Significant confinement boundary. From the SRUs, the exhaust is directed to the HEPA filter banks located in the New Filter Building. The exhaust system is designed to provide continuous HEPA filtration prior to release to the exhaust stack. There are 22 HEPA filter banks rated at 27,000 CFM / 12.75 m{sup 3}/s each. Each filter bank has two stages of pre-filters and two stages of HEPA filters. The filtered air from each of the 22 filter banks discharges into a common concrete plenum, which is maintained under a negative pressure by the main exhaust fans. Six 1,000 HP variable frequency drive exhaust fans are provided on the south side of the plenum. At the maximum expected exhaust flow of 540,000 CFM, four exhaust fans and twenty filter banks will be in operation. The fans discharge vertically to a separate concrete exhaust plenum. The filtered exhaust is routed from the exhaust plenum to a 125-foot-tall exhaust stack via a 13-foot diameter duct. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NASA Shuttle Logistics Depot (NSLD) - The application of ATE

The concept of the NASA Shuttle Logistics Depot (NSLD) developed for the Space Shuttle Orbiter Program is described. The function of the NSLD at Cape Canaveral is to perform the acceptance and diagnostic testing of the Shuttle's space-rated line-replaceable units and shop-replaceable units (SRUs). The NSLD includes a comprehensive electronic automatic test station, program development stations, and assorted manufacturing support equipment (including thermal and vibration test equipment, special test equipment, and a card SRU test system). The depot activities also include the establishment of the functions for manufacturing of mechanical parts, soldering, welding, painting, clean room operation, procurement, and subcontract management.

Simpkins, Lorenz G.↗

System Modeling of a Lunar Molten Regolith Electrolysis Plant

In-Situ Resource Utilization (ISRU) is the process of extracting local resources to produce commodities for propulsion, life support systems, and off-planet construction rather than transporting consumables from Earth. Molten Regolith Electrolysis (MRE) is a novel ISRU method of extracting oxygen gas and metal alloy from lunar regolith. The MRE process involves placing lunar regolith between two electrodes, through which current is passed, to melt the regolith and reduce the metal oxide constituents by direct electrolysis (e.g. FeO, SiO 2 , MgO, Al 2 O 3 ) into oxygen gas and metal alloys. The oxygen is liquefied and used as propellant for landers, while the metals (e.g. Ferro-alloys) are further processed and used in structural building materials and parts manufacturing. A system model was developed that accounted for the major processes of an MRE plant (from excavation of raw materials to storage of products) to assess the feasibility of a lunar MRE plant. The S ystem Engineering and Integration ( S E&I) I SRU M odeling and A nalysis (SIMA) team utilized its previously documented system sizing model, the Mission Analysis and Integration Tool (MAIT) as framework of the system model. MAIT uses MATLAB/Simulink to integrate subsystem models into a complete system model of the MRE plant. Total mass, volume, and power requirements were computed for numerous iterations of a MRE plant.

In-Situ Resource Utilization↗

An IRU for Cassini

The JPL Inertial Reference Unit (IRU) is the single most sophisticated assembly on the Cassini Spacecraft. At the core of the IRU is the state-of-the-art, Litton (formerly Delco) Hemispherical Resonator Gyroscope (HRG). Launched in October 1997, Cassini's trajectory utilizes gravity assist manuevers around Venus (twice), Earth, and Jupiter over a seven year period, arriving at Saturn in June 2004.

Cassini IRU Inertial Reference Unit attitude stabi↗

Cassini Tracking and Identification Architecture

The Cassini spacecraft will perform a detailed examination of the Saturnian system, including the release of a probe to study Saturn's largest satellite, Titan. The star tracker for the Cassini mission must provide accurate data during the entire flight including four years of measurement in a harsh radiation environment.

CCD base star camera Cassini star tracker Stellar ↗