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At least 19 records

Toward Predictive RANS and SRS Computations of Turbulent External Flows of Practical Interest

In this work, we investigate the main challenges to prediction of turbulent external flows of practical interest with Reynolds-Averaged Navier–Stokes equations (RANS) and Scale-Resolving Simulation (SRS) models. This represents a crucial step toward further developing and establishing these formulations so they can be confidently utilized in engineering problems without reference data. The study initiates by identifying the major challenges to prediction. A literature review is performed to illustrate their effects in RANS and SRS computations. Afterward, we evaluate the impact of the challenges to prediction by analyzing representative statistically steady and unsteady flows with prominent RANS and SRS methods. These include multiple turbulent viscosity and second-moment RANS closures, and hybrid and bridging SRS models. The results demonstrate the potential of the selected SRS models to predict engineering flows. Yet, they also show the importance of considering the challenges to prediction during the setup and conduction of numerical experiments. These can suppress the advantages of using SRS formulations. The data also indicate that only SRS models can confidently predict statistically unsteady flows. In contrast, the results demonstrate that mean-flow quantities of statistically steady flows can be efficiently calculated with RANS closures, especially second-moment closures. Among the selected SRS methods, bridging models reveal better suited for prediction due to their ability to prevent commutation errors and enable the robust evaluation of numerical and modeling errors. This last property allows the use of a new validation technique that does not require reference data.

42 ENGINEERING↗

Model Validation for the FY2021 SRS Composite Analysis Monitoring Plan

Using a projected end-state date of 2065 (SRNS 2015b), the Savannah River Site (SRS) Composite Analysis (CA) modeling for each facility and waste site began on the inventory year assigned to it so that source depletion and radionuclide transport out of the system could be appropriately captured. Some SRS waste sites that have already achieved their end states (i.e., end-state inventories and end-state configuration) are currently contributing to the potential off-site public dose through source release, groundwater transport, discharge to on-site surface streams, and stream transport to the CA point of assessments (POAs). The inventory year assigned to these waste sites is 2002 or before. This means that SRS CA results from 2002 and beyond are a reasonable representation for these waste sites that have already achieved their end states and are currently contributing to the potential off-site public dose. The SRS Annual Environmental Report (AER) monitoring can differentiate and separate liquid pathway data allowing the data representing only waste sites at their end state to be produced. Because the SRS CA has projected reasonable end-state impacts from 2002 and beyond, and the AER monitoring can differentiate and separate operating and end-state contributions to annual liquid pathway release, an opportunity exists to use the AER monitoring data to validate the SRS CA model.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Squeezed Light Stimulated Raman Scattering (SRS) Microscopy for Bioenergy Applications

Stimulated Raman scattering (SRS) microscopy using picosecond near-IR pulses have provided a great penetration depth with reduced fluorescence interference when imaging biological samples for bioenergy applications. These tools have provided insight into 1) tracking the degradation of chemical composites in biomass feedstocks to investigate the recalcitrant factors during the deconstruction processes, 2) monitoring the production of chemicals in photosynthetic plants and wood-digesting microorganisms, and 3) probing plant-bacteria interactions. However, the above processes are usually slow and require continuous imaging for an extended period. This is challenging for classic SRS because the laser power needed to achieve enough sensitivity causes photodamage in the samples during such long experiments. Quantum-squeezed light with reduced noise in the intensity quadrature can improve the sensitivity of classic SRS microscopy beyond the shot noise limit. The successful squeezing of one of the picosecond pulses in the above SRS will improve sensitivity and reduce photodamage, greatly expanding the range of studies available to SRS microscopy.

BIOMASS FUELS↗

SRS Computer Animation and Drive Train System

The spinning rocket simulator (SRS) is an ongoing project at Oral Roberts University. The goal of the SRS is to gather crucial data concerning a spinning rocket under thrust for the purpose of analysis and correction of the coning motion experienced by this type of spacecraft maneuver. The computer animation simulates a virtual, scale model of the component of the SRS that represents the spacecraft itself. This component is known as the (VSM), or virtual spacecraft model. During actual physical simulation, this component of the SRS will experience a coning. The goal of the animation is to cone the VSM within that range to accurately represent the motion of the actual simulator. The drive system of the SRS is the apparatus that turns the actual simulator. It consists of a drive motor, motor mount and chain to power the simulator into motion. The motor mount is adjustable and rigid for high torque application. A digital stepper motor controller actuates the main drive motor for linear acceleration. The chain transfers power from the motor to the simulator via sprockets on both ends.

Arthun, Daniel↗

Bioremediation of copper in sediments from a constructed wetland ex situ with the novel bacterium Cupriavidus basilensis SRS

The H-02 constructed wetland was designed to remove metals (primarily copper and zinc) to treat building process water and storm water runoff from multiple sources associated with the Tritium Facility at the DOE-Savannah River Site, Aiken, SC. The concentration of Cu and Zn in the sediments has increased over the lifetime of the wetland and is a concern. A bioremediation option was investigated at the laboratory scale utilizing a newly isolated bacterium of the copper metabolizing genus Cupriavidus isolated from Tim’s Branch Creek, a second-order stream that eventually serves as a tributary to the Savannah River, contaminated with uranium and other metals including copper, nickel, and mercury. Cupriavidus basilensis SRS is a rod-shaped, gram-negative bacterium which has been shown to have predatory tendencies. The isolate displayed resistance to the antibiotics ofloxacin, tetracycline, ciprofloxacin, select fungi, as well as Cu 2+ and Zn 2+ . Subsequent ribosomal sequencing demonstrated a 100% confidence for placement in the genus Cupriavidus and a 99.014% match to the C. basilensis type strain. When H-02 wetland samples were inoculated with Cupriavidus basilensis SRS samples showed significant (p < 0.05) decrease in Cu 2+ concentrations and variability in Zn 2+ concentrations. Over the 72-h incubation there were no significant changes in the inoculate densities (10 6 –10 8 cells/ML) indicating Cupriavidus basilensis SRS resiliency in this environment. This research expands our understanding of the Cupriavidus genus and demonstrates the potential for Cupriavidus basilensis SRS to bioremediate sites impacted with heavy metals, most notably copper.

54 ENVIRONMENTAL SCIENCES↗

A Comparison of Adverse Meteorology Inputs for Emergency Management and Safety Basis Dispersion Modeling Applications at SRS

The MELCOR Accident Consequence Calculation System (MACCS), used for safety basis accident analyses at SRS, implements adjustment factors to consider the increased vertical turbulence associated with local surface roughness and the increased lateral turbulence associated with time-based plume meander. The two models used for SRS emergency planning radiological consequence assessment, i.e., Hotspot and Puff/Plume, currently do not have an option to input or apply diffusion adjustments for meander or surface roughness. Adverse meteorology conditions at SRS have been determined as E stability class and 1.3 meters per second wind speed for ground level releases. This is the input used for emergency planning models. Contrastingly safety basis analyses use a different input, representing adverse meteorology values as F stability class and wind speeds of 1.3 meters per second (for a ground level release). This results in an apparent discrepancy between the two approaches. In this report we document the differing modeling assumptions, discuss the logic behind each modeling approach used to represent local roughness and plume meander conditions, and numerically compare dispersion coefficients and concentration estimates obtained from each set of model inputs.

54 ENVIRONMENTAL SCIENCES↗

Spontaneous Raman Scattering (SRS) System for Calibrating High-Pressure Flames Became Operational

A high-performance spontaneous Raman scattering (SRS) system for measuring quantitative species concentration and temperature in high-pressure flames is now operational. The system is located in Glenn s Engine Research Building. Raman scattering is perhaps the only optical diagnostic technique that permits the simultaneous (single-shot) measurement of all major species (N2, O2, CO2, H2O, CO, H2, and CH4) as well as temperature in combustion systems. The preliminary data acquired with this new system in a 20-atm hydrogen-air (H2-air) flame show excellent spectral coverage, good resolution, and a signal-to-noise ratio high enough for the data to serve as a calibration standard. This new SRS diagnostic system is used in conjunction with the newly developed High- Pressure Gaseous Burner facility (ref. 1). The main purpose of this diagnostic system and the High-Pressure Gaseous Burner facility is to acquire and establish a comprehensive Raman-scattering spectral database calibration standard for the combustion diagnostic community. A secondary purpose of the system is to provide actual measurements in standardized flames to validate computational combustion models. The High-Pressure Gaseous Burner facility and its associated SRS system will provide researchers throughout the world with new insights into flame conditions that simulate the environment inside the ultra-high-pressure-ratio combustion chambers of tomorrow s advanced aircraft engines.

Nguyen, Quang-Viet↗

AmeriFlux FLUXNET-1F US-SRS Santa Rita Savanna

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-SRS Santa Rita Savanna. This is the FLUXNET version of the carbon flux data for the site US-SRS Santa Rita Savanna produced by applying the standard ONEFlux (1F) software. Site Description - The study site is located in the Santa Rita Experimental Range, approximately 45 km south of Tucson, Arizona, within the Sonoran Desert. The rangeland has undergone a shift from a semiarid grassland to a savanna due to the encroachment of the woody leguminous tree Prosopis velutina Woot., or velvet mesquite. A pair of adjacent watersheds of similar size ( 1.08 ha and 1.10 ha) was established to investigate the effects of mesquite removal on hydrologic processes. In 1974, diesel oil was applied basally to all trees in one watershed, with reapplication as needed and dead tree removal for wood, whereas the other watershed, where the flux tower is located, has continued in the woody plant encroachment process. In 2016, an herbicide process was applied to the area around the EC flux tower.

Vivoni, Enrique R.↗

Colloid-Facilitated Actinide Transport in a Cementitious-Impacted SRS Groundwater

The objective of this report is to provide a literature review relevant to the question of whether colloid facilitated transport of plutonium is enhanced in a cementitious groundwater system on the Savannah River Site (SRS). Contaminant transport is commonly described as taking place in a system with a mobile aqueous phase and an immobile solid phase. There has been an increasing awareness of a third phase, a mobile solid phase, also referred to as a mobile colloidal phase. Mobile colloids consist of organic and/or inorganic submicron-particles that move with groundwater flow. When radionuclides are associated with the mobile colloids, the net effect is that radionuclides can move faster through the subsurface system than would be predicted by transport models that do not include mobile colloids. It is important to distinguish between subsurface colloids and subsurface mobile colloids. The subsurface environment includes an enormous reservoir of colloids, but only a tiny fraction, if any, are mobile. Mobile colloid formation is commonly described as involving a three-step process: genesis, stabilization, and transport. It was concluded that there is a strong likelihood that submicron colloids of plutonium exist near the source term, (i.e., the genesis step is likely completed). While such particles have not been directly detected, it is highly likely that plutonium could either attach to submicron particles in the sediment or that submicron plutonium fragments exist at the source. However, the tendency for these plutonium colloids to move in the SRS subsurface is extremely low, especially in engineered cementitious environments where the ionic strength of the solution and the elevated concentrations of divalent cations greatly curtails colloid suspension stability (i.e., the stabilization step is likely not completed). Together these data strongly indicate that plutonium-bearing colloids would likely exist in the near field of a tank closure facility, but the colloids would be unlikely to be mobile, thereby providing a vector for enhanced transport. Under cementitious leachate impacted groundwater conditions, it is reasonable to assume plutonium transport occurs primarily as a two-phase system, a mobile aqueous phase and an immobile solid phase.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Applications of Alternate Actinide Calibration on Inductively Coupled Plasma Mass Spectrometry (ICPMS) Analysis of H-Canyon Highly Enriched Uranium Legacy Material at the Savannah River Site (SRS)

The Savannah River National Laboratory (SRNL) uses Inductively Coupled Plasma Mass Spectrometry (ICPMS) to support numerous programs at the Savannah River Site (SRS). As part of an objective to prepare high assay low enriched uranium (HALEU), the SRS H-Canyon needed analysis of legacy uranyl nitrate that is stored at its Outside Facilities (HOF). With the application of a standard practice for alternate actinide calibration on ICP-MS, SRNL has successfully demonstrated its capability to characterize the uranium/actinide composition of the HOF tanks that are intended for consolidation prior to preparation of the HALEU. A comparison of the uranium analytical results between recently upgraded SRNL ICP-MS and Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) instrumentation shows the alternate actinide calibration is a valid complementary method when used in conjunction with other analytical techniques (Davies-Gray Potentiometric Titration). The methods, instrumentation, and ongoing developments on ICP-MS at SRNL will be discussed.

Jones, Mark A.↗

Utilizing HYSPLIT for Emergency Response Modeling at SRS

The threat of a disaster happening at the Savannah River Site (SRS) is low, but not zero. When an emergency arises, emergency responders utilize a variety of tools to detect, track, and mitigate the disaster. HYSPLIT is a community atmospheric dispersion model that is highly configurable and has been used operationally to simulate particle, chemical, and radionuclide releases. We have developed a preliminary user interface (UI) that configures HYSPLIT to run for a variety of Emergency Action Level (EAL) scenarios at SRS. Using a hypothetical EAL scenario of an accidental release of Pu-238 in H-area and K-area onsite, an analysis was done to show how a preliminary UI framework allows HYSPLIT to be run on a terminal without the need form an active network connection. The study was successful in multiple aspects. For the preliminary UI, users were able to input certain characteristics of the hypothetical EAL such as hours of emission (how long was Pu-238 being released), curies of release, release start time (when does the model run start), and type of radionuclide directly into the terminal. For HYSPLIT, the model was successful in being able to take the UI input, calculate the results from the inputs and output multiple figures of both total volumetric airborne concentrations and surface deposition. We used the Pu-238 Derived Intervention Level (DIL) deposition thresholds for produce, dairy, and beef for visualization of the surface deposition, showing how a release would impact ingestion pathways.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Utilizing HYSPLIT for Emergency Response Modeling at SRS

At SRS, emergency responders use a variety of tools to detect, track, and mitigate hazardous material releases into the atmosphere. Two models currently used at SRS are Puff-Plume and the Lagrangian Particle Dispersion Model (LPDM), a Gaussian and Lagrangian model, respectively. A decision has been made to replace LPDM with the more widely-supported Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model for evaluating inhalation and ingestion doses following a release. HYSPLIT is designed to compute complex dispersion and deposition simulation To achieve the implementation of HYSPLIT, we have developed a preliminary UI framework that will allow HYSPLIT to be run on ATG computers without the need for active network connections, thus avoiding the loss of capabilities in the event of a network outage during an emergency.

Earley, Ian↗

Literature Review Investigating Historical Plutonium Solubility in SRS Tank Waste

The Savannah River Site (SRS) has designed the Accelerated Basin De-inventory (ABD) program to accelerate the de-inventory of L-Basin and accelerate the Spent Nuclear Fuel (SNF) disposition mission. Similarly, the H-Canyon facility at SRS is reestablishing the 6.3D electrolytic dissolver for dissolving unirradiated stainless-steel (SS) clad Fast Critical Assembly (FCA) fuel. In both discard types (ABD and FCA), plutonium is present and its complex solubility when composited to Concentration, Storage, and Transfer Facility (CSTF) sludge is being investigated as it may have downstream impacts to the liquid waste (LW) organization. This literature review aims to highlight and compile the existing literature on plutonium solubility in waste streams relevant to ABD and FCA discards, as well as discuss some considerations in analyzing solubility data of plutonium. This review serves to help define the analysis methods for future experiments involving plutonium (and other actinides) and in designing appropriate testing conditions surrounding these studies. This review is broken up into five parts and will discuss: (i) The possible effects of testing hold time and temperature on plutonium solubility, (ii) the influence of neutralization rate and particle size of freshly precipitated discards, (iii) the coprecipitation of plutonium with iron and uranium, (iv) predictive solubility modeling and the influence of supernate anions on solubility, and (v) the speciation of plutonium in solutionas a result of supernate anions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

SRS 2022 Annual Site Environmental Report (ASER)

ASER stands for the Annual Site Environmental Report and is the primary document that the U.S. Department of Energy uses to inform the public of environmental performance and conditions at SRS. • ASERs are required by U.S. Department of Energy to provide the public and stakeholders information on: – Environmental program performance – Site wide environmental monitoring and surveillance effectiveness – Compliance status with environmental standards and requirements • SRS published its first ASER in 1959

DAVIS, COLLEEN↗

History of Ultrasonic Inspection of High-Level Waste Tanks at SRS - 20220

The Liquid Waste Disposition Projects (LWDP) Structural Authority and Inspection Engineering Support Group has teamed with the Materials Science and Technology Non-destructive Evaluation Group of Savannah River National Laboratory (SRNL) to implement a comprehensive In-Service Inspection (ISI) program for the High-Level Waste (HLW) tanks in the sites tank farms. The purpose of this program is to demonstrate the structural and leak integrity of the tanks to maintain the function of waste containment throughout the desired service life. Four types of waste tanks were constructed at Savannah River Site (SRS) from 1951 thru 1981 to store radioactive nuclear waste from the separations process. The Type I, II and III are carbon steel cylindrical tanks with varying degrees of access to the side walls and very limited access to the tank bottom. The tanks contain 750,000 to 1.3 million gallons of waste and are buried or backfilled with soil. The tanks are 75'-85' in diameter and 24'-33' from tank bottom to the tank roof. Inspection of the HLW tanks is made difficult by radiation, contamination, and small access openings. Through the years these challenges have been overcome by progressive improvements to programs and equipment resulting in the sophisticated wall crawler Ultrasonic Testing (UT) technology of today. A formal inspection program was developed and put in service in 1972. UT thickness measurements were first made in 1967 and 1969 of selected waste tanks using an analog-type instrument to measure the thickness of the carbon steel walls. Routine inspections for thinning were performed from 1972-1985 and then discontinued because no thinning had been observed and this technique could not detect pitting or cracking. UT inspections resumed in 1994 using a sophisticated robotic wall crawler with UT technology capable of detecting thinning, cracking and pitting. The current program focuses on the newer Type III tanks that are used primarily for storage. The program was upgraded in 2003 to include selected regions of the tank wall, secondary wall and annulus floor on a 7 to 10-year frequency. The facility is currently in its third cycle of tank inspections. Thus far, there have been no reportable indications of service induced degradation. This result provides assurance that the chemistry control program has been effective at mitigating corrosion and that the tanks remain structurally sound even after more than 40 years of service. This paper will present the UT technology first used at SRS and the evolution to the current systems and their capabilities. Additionally, plans for equipment upgrades that will improve the extent of inspection will be discussed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

SRS Strategy for Tank 3 Salt Dissolution - Performance and Lessons Learned - 20441

The Savannah River Site (SRS) Tank Farms have 51 underground waste tanks used to store and process liquid nuclear waste materials. There are 4 different tank types, ranging in capacity from 2,840,000 to 4,920,000 L (750,000 to 1,300,000 Gal). Twenty-four of the tanks are older style and do not meet full secondary containment standards. The older style tanks are the initial focus of waste removal efforts for tank closure at SRS. Eight of these twenty-four tanks have completed waste removal and are filled with grout. Prior to salt dissolution, Tank 3 was a dry salt tank that contained 5.06 m (199.3 in) of salt and sludge waste. Additional salt waste was present on cooling coils above the salt layer up to approximately 5.59 m (220 in). Three mixing eductors were installed in Tank 3 to aid in dissolving salt waste in three tank riser access ports. A transfer pump was installed, and the transfer pump suction was located 25.4 cm (10 in) from the tank bottom. Well water was added to the tank through a downcomer until the dry bulk salt was covered with liquid. During the initial fill of Tank 3, approximately 242,000 L (64,000 Gal) of rain water were added from periodic F-Tank Farm (FTF) Catch Tank additions and approximately 17,000 L (4,500 Gal) of well water were added. Following liquid additions to cover the dry bulk salt, well water was added through the three mixing eductors in batches during each stage. Additionally, during the salt dissolution campaigns, the FTF Catch Tank was utilized to add rain water through a downcomer in the center tank riser access port as needed for volume relief in the FTF Catch Tank. Following liquid additions, the water was recirculated (internal to the tank) using the transfer pump, and a sample was pulled to confirm the target specific gravity (SpG) of the dissolved salt solution was achieved. The dissolved salt solution was then transferred to the receipt tank (Tank 7), and the mixing eductors were lowered as close to the new bulk salt layer as possible, to support subsequent dissolution campaigns. While the mixing jets were able to dissolve salt successfully in Tank 3, they did not do so in a completely uniform manner. Throughout dissolution, mounds were discovered under Riser 1, Riser 2, and the Center Riser. The mixing jets dissolved the salt around the edges of the tank well but were not as effective toward the center of the tank. FTF Catch Tank additions through the center tank riser access port downcomer were required to impact the mound under the center tank riser. FTF Catch Tank additions were sporadic as they were dependent on rainfall in the area. Additionally, all mixing jets were rarely able to be lowered to the same elevation, indicating some mounding in the bulk salt layer. Indexing of the mixing jets was also utilized to impact the salt mounds. Overall, Tank 3 salt dissolution was successful as approximately 1,476,000 L (390,000 Gal) of dissolved salt solution was transferred to Tank 7 over six stages. Slightly less than 852,000 L (225,000 Gal) of water were added to Tank 3. The original material balance prediction estimated that the bulk salt level in Tank 3 would be 3.88 m (152.8 in) after six salt dissolution stages. After six stages the actual bulk salt level was 3.38 m (133 in). This paper will discuss the salt removal strategy, each salt dissolution stage, and lessons learned for future salt dissolution. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Materials Data on SrS by Materials Project

SrS is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sr2+ is bonded in a body-centered cubic geometry to eight equivalent S2- atoms. All Sr–S bond lengths are 3.18 Å. S2- is bonded in a body-centered cubic geometry to eight equivalent Sr2+ atoms.

36 MATERIALS SCIENCE↗