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Materials Data on Sr3P2 by Materials Project

Sr3P2 is alpha Rhenium trioxide-like structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one phosphine molecule and one Sr3P framework. In the Sr3P framework, Sr2+ is bonded in a linear geometry to two equivalent P3- atoms. Both Sr–P bond lengths are 2.83 Å. P3- is bonded to six equivalent Sr2+ atoms to form corner-sharing PSr6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗