Materials Data on Sr3Co(CN)3 by Materials Project
Sr3Co(CN)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Sr2+ is bonded in a 1-coordinate geometry to four equivalent N3- atoms. There are a spread of Sr–N bond distances ranging from 2.56–3.00 Å. Co1+ is bonded in a trigonal planar geometry to three equivalent C+0.67+ atoms. All Co–C bond lengths are 1.76 Å. C+0.67+ is bonded in a distorted linear geometry to one Co1+ and one N3- atom. The C–N bond length is 1.25 Å. N3- is bonded in a 1-coordinate geometry to four equivalent Sr2+ and one C+0.67+ atom.
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