Materials Data on Sr3As2 by Materials Project
Sr3AsAs is alpha Rhenium trioxide-like structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one arsenic molecule and one Sr3As framework. In the Sr3As framework, Sr2+ is bonded in a linear geometry to two equivalent As3- atoms. Both Sr–As bond lengths are 2.90 Å. As3- is bonded to six equivalent Sr2+ atoms to form corner-sharing AsSr6 octahedra. The corner-sharing octahedral tilt angles are 0°.
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