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The Potential for Electrons to Molecules Using Solar Energy

Solar photovoltaics (PV) do and will continue to play an important role in the electric power sector and can potentially support other sectors that are in need of decarbonized energy sources. Chemicals such as hydrogen, ammonia, and hydrocarbons including ethylene are currently produced from natural gas and crude oil. Thus, processes to produce them emit carbon dioxide and other greenhouse gases both directly and in upstream feedstock recovery processes. Electrons-to-molecules (E2M) technologies are being developed to convert carbon dioxide, water, and atmospheric nitrogen to desired chemical products and they are large electricity loads. Thus, they are emerging as a potential applications for PV. In its essence, they can act as electrochemical energy storage, thereby providing a means to further utilize the energy generated from PV and store it in molecular form. E2M systems offer an array of potential products and system designs that can be tailored to different end-uses and applications. It involves electrochemical conversion which uses electricity to break molecular bonds and produce new molecules. Various electrochemical conversion technologies split water into hydrogen and oxygen, reduce carbon dioxide into other hydrocarbon molecules, and several other possible combinations. While this Chapter does not attempt to provide an exhaustive summary or analysis of the potential products from E2M systems, it does provide an initial overview of the potential opportunities and challenges for PV and E2M systems in this space. This Chapter considers the potential for E2M to produce key chemicals and fuels that currently rely on hydrocarbons for production, either as a reactant or a source of high-grade heat.

14 SOLAR ENERGY↗

Solar Energy Technologies Office Fact Sheet

The U.S. Department of Energy Solar Energy Technologies Office (SETO) supports early-stage research and development to improve the affordability, reliability, and performance of solar technologies on the grid. The office invests in innovative research efforts that securely integrate more solar energy into the grid, enhance the use and storage of solar energy, and lower solar electricity costs.

Solar Energy Technologies Office Fact Sheet, SunSh↗

Best Practices Handbook for the Collection and Use of Solar Resource Data for Solar Energy Applications: Second Edition

As the world looks for low-carbon sources of energy, solar power stands out as the single most abundant energy resource on Earth. Harnessing this energy is the challenge for this century. Photovoltaics, solar heating and cooling, and concentrating solar power (CSP) are primary forms of energy applications using sunlight. These solar energy systems use different technologies, collect different fractions of the solar resource, and have different siting requirements and production capabilities. Reliable information about the solar resource is required for every solar energy application. This holds true for small installations on a rooftop as well as for large solar power plants; however, solar resource information is of particular interest for large installations, because they require substantial investment, sometimes exceeding 1 billion dollars in construction costs. Before such a project is undertaken, the best possible information about the quality and reliability of the fuel source must be made available. That is, project developers need reliable data about the solar resource available at specific locations, including historic trends with seasonal, daily, hourly, and (preferably) subhourly variability to predict the daily and annual performance of a proposed power plant. Without this data, an accurate financial analysis is not possible. Additionally, with the deployment of large amounts of distributed photovoltaics, there is an urgent need to integrate this source of generation to ensure the reliability and stability of the grid. Forecasting generation from the various sources will allow for larger penetrations of these generation sources because utilities and system operators can then ensure stable grid operations. Developed by the foremost experts in the field who have come together under the umbrella of the International Energy Agency's Solar Heating and Cooling Task 46, this handbook summarizes state-of-the-art information about all the above topics.

14 SOLAR ENERGY↗

Best Practices Handbook for the Collection and Use of Solar Resource Data for Solar Energy Applications: Third Edition

As the world looks for low-carbon sources of energy, solar power stands out as the single most abundant energy resource on Earth. Harnessing this energy is the challenge for this century. Photovoltaics, solar heating and cooling, and concentrating solar power (CSP) are primary forms of energy applications using sunlight. These solar energy systems use different technologies, collect different fractions of the solar resource, and have different siting requirements and production capabilities. Reliable information about the solar resource is required for every solar energy application. This holds true for small installations on a rooftop as well as for large solar power plants; however, solar resource information is of particular interest for large installations because they require substantial investment, sometimes exceeding 1 billion dollars in construction costs. Before such a project is undertaken, the best possible information about the quality and reliability of the fuel source must be made available. That is, project developers need reliable data about the solar resource available at specific locations, including historic trends with seasonal, daily, hourly, and (preferably) subhourly variability to predict the daily and annual performance of a proposed power plant. Without these data, an accurate financial analysis is not possible. Additionally, with the deployment of large amounts of distributed photovoltaics, there is an urgent need to integrate this source of generation to ensure the reliability and stability of the grid. Forecasting generation from the various sources will allow for larger penetrations of these generation sources because utilities and system operators can then ensure stable grid operations. Developed by the foremost experts in the field who have come together under the umbrella of the International Energy Agency’s Solar Heating and Cooling Task 46, this handbook summarizes state-of-the-art information about all these topics.

14 SOLAR ENERGY↗

Ultrafast probes at the interfaces of solar energy conversion materials

Ultrafast carrier dynamics at interfaces plays a major role in governing solar energy conversion efficiency in solar conversion systems, especially in solar cells and photoelectrochemical devices. Here, we discuss recent advances in ultrafast spectroscopic probes to understand the dynamics at such interfaces. Transient reflectance (TR) enables monitoring of the surface carriers that are within ~10 nm of the surface or interface of interest. Crucial parameters such as surface recombination velocity and carrier diffusion can be determined. When a strong surface or interfacial field is present the reflectance spectrum will exhibit Franz–Kelydesh oscillations. Monitoring the transient formation or decay of such oscillations informs about the interfacial field and is referred to as transient photoreflectance (TPR). Such fields are helpful in designing systems in order to move carriers away from surfaces where photocorrosion can occur and towards catalytic surfaces. Finally, we discuss transient infrared attenuated total reflection (TATR) to probe the ultrafast reaction intermediates in a photo-driven chemical reaction.

14 SOLAR ENERGY↗

Senior Housing Complex Energy Efficiency and Solar Energy Project

As part of a longer-term energy efficiency and solar development program on the Coeur d'Alene reservation, the Coeur d'Alene Tribe completed energy efficiency measures and deployed a solar photovoltaic system at its Senior Housing Complex. The project generated nearly 68,000 kWh of solar energy in its first year, and reduced energy used at the senior housing complex by 95,192 kWh, saving $7,144.56 in energy costs, and saving 48.1 metric tons of carbon dioxide.

14 SOLAR ENERGY↗

Reducing the Costs of Paying for Consumed Electric Energy by Utilizing Solar Energy

The use of a low-power solar network and standalone power plants is the most promising for the needs of the housing and utilities sector, small industrial enterprises, social and public health facilities, recreation areas, remote objects, and agricultural industries; this will make it possible to reduce the load on the energy system at peak moments, as well as to decrease losses when transporting electric energy in its elements. It is assumed that the minimum value of the unit cost of generated electric energy is used as the criterion for configuring and selecting the parameters of solar power equipment, which will make it possible to set up an economically feasible additional power supply to the consumer, since it excludes the use of storage devices and rearrangement of the power supply system.

14 SOLAR ENERGY↗

Solar Energy Innovation Network 2017-2024: Abbreviated Final Technical Report

This material is based upon work supported by the U.S. Department of Energy's (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Solar Energy Technologies Office under the Agreement/Award Number 32954 for Solar Energy Innovation Network (SEIN) Project, 2017-2024. SEIN is a dynamic program that assembles diverse teams of stakeholders to research solutions to real-world challenges associated with solar energy adoption. In conjunction with its partner organizations, NREL implemented the program by providing research, analysis, and technical expertise directly to project teams and groups of teams (cohorts), by facilitating networked learning through cohorts and peer exchange, and by facilitating dissemination and replication of solutions and lessons learned among stakeholders across the U.S. with similar challenges.

14 SOLAR ENERGY↗

Solar Energy Technical Publications Catalog: Solar Thermal Technology

The research and development described in these documents was conducted within the U.S . Department of Energy's (DOE) Solar Thermal Technology Program. The goal of this program is to advance the engineering and scientific understanding of solar thermal technology and to establish the technology base from which private industry can develop solar thermal power production options for introduction into the competitive energy market. Solar thermal technology concentrates the solar flux using tracking mirrors or lenses onto a receiver where the solar energy is absorbed as heat and converted into electricity or incorporated into products as process heat. The two primary solar thermal technologies, central receivers and distributed receivers, employ various point and line-focus optics to concentrate sunlight. Current central receiver systems use fields of heliostats (two-axis tracking mirrors) to focus the sun's radiant energy onto a single, tower- mounted receiver. Point focus concentrators up to 17 meters in diameter track the sun in two axes and use parabolic dish mirrors or Fresnel lenses to focus radiant energy onto a receiver. Troughs and bowls are line-focus tracking reflectors that concentrate sunlight onto receiver tubes along their focal lines. Concentrating collector modules can be used alone or in a multimodule system. The concentrated radiant energy absorbed by the solar thermal receiver is transported to the conversion process by a circulating work fluid. Receiver temperatures range from l00 degrees C in low-temperature troughs to over 1500 degrees C in dish and central receiver systems. The Solar Thermal Technology Program is directing efforts to advance and improve each system concept through solar thermal materials, components, and subsystems research and development and by testing and evaluation. These efforts are carried out with the technical direction of DOE and its network of field laboratories that works with private industry. Together they have established a comprehensive, goal-directed program to improve performance and provide technically proven options for eventual incorporation into the nation's energy supply. To successfully contribute to an adequate energy supply at reasonable cost, solar thermal energy must be economically competitive with a variety of other energy sources. The Solar Thermal Technology Program has developed components and system-level performance targets as quantitative program goals. These targets are used in planning research and development activities, measuring progress, assessing alternative technology options, and developing optimal components. These targets are pursued vigorously to ensure a successful program. This catalog represents part of an effort to provide information on publications about solar thermal research and development activities conducted by DOE's laboratories. Publications listed include technical and research reports and special publications. The following national laboratories are represented in this edition: Sandia National Laboratories, Solar Energy Research Institute, Jet Propulsion Laboratory. This catalog is a product of the DOE Solar Technical Information Program, which is dedicated to providing information to scientific and industrial users in ways most convenient and useful to them. This catalog focuses on solar thermal technologies, and its purpose is to keep the scientific and industrial communities informed of the latest developments in federally sponsored research in this technology.

140000* -- Solar Energy↗

The Evolving Solar Energy Innovation Ecosystem in Puerto Rico

This report presents initial findings from the research project, “Developing socially and economically generative, resilient PV-energy systems for low- and moderate-income communities: Applications for Puerto Rico.” This material is based upon work supported primarily by the US Department of Energy’s Office of Energy Efficiency and Renewable Energy under the Solar Energy Technology Office Fiscal Year 2018 Funding Program award number DE-EE0008570 and in part by the National Science Foundation (NSF) and the Department of Energy (DOE) under NSF CA No. EEC-1041895. This project is a joint effort of Arizona State University’s Center for Energy and Society; the University of Puerto Rico-Mayaguez’s Center for Hemispheric Cooperation in Research and Education in Engineering and Applied Science, Sustainable Energy Center, and National Institute for Energy and Island Sustainability; and the National Renewable Energy Laboratory. The project seeks to understand the place of energy in low-income communities in Puerto Rico, the opportunities for solar energy to provide solutions to the energy challenges facing these communities, and the capacity of the solar energy innovation ecosystem in Puerto Rico to deliver relevant solar solutions for these communities. We define the solar energy innovation ecosystem as the diverse actors and stakeholders whose collective networks and actions—and the flows among them of ideas, knowledge, data, influence, money, and equipment, as well as the rules that govern those flows—are essential to the success of renewable energy markets and projects. This report presents results from the first year of the project’s research, which has concentrated on several key goals: (1) characterizing the trajectory of solar energy development in Puerto Rico in the three years since Hurricane María; (2) mapping and characterizing the current solar energy innovation ecosystem in Puerto Rico, including the technical potential for solar energy in Puerto Rico, and the business and policy landscape shaping solar developments; and (3) beginning to characterize the broad landscape of community energy initiatives underway in Puerto Rico. To pursue these goals, we engaged in a systematic review of solar energy developments in Puerto Rico and conducted interviews with over 100 members of the solar energy innovation, including policy, business, finance, research, and civil society leaders, as well as solar users. Solar technical potential data for Puerto Rico was developed by the National Renewable Energy Laboratory (NREL) and is publicly available at: https://data.nrel.gov/submissions/144. The documentation for the NREL dataset is included as Appendix A.

14 SOLAR ENERGY↗

New Industry Partnerships: Solar Energy Technologies Office Support for Early Projects in the Energy Systems Integration Facility: An Agreement Closeout Summary Report

The U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Solar Energy Technologies Office (SETO)-funded New Industry Partnerships (NIPs) agreement established multiple new cooperative research projects with industry partners. Each project demonstrated the use of the National Renewable Energy Laboratory's Energy Systems Integration Facility (ESIF) as a national asset for research and development, testing, and validation of new technologies to support high penetrations of solar energy on the electric grid. The agreement was launched in 2013 and represented the SETO portion of the DOE EERE-wide Integrated Network Testbed for Energy Grid Research and Technology Experimentation (INTEGRATE) program. The focus of INTEGRATE was on multi-energy system testing and on testing the interactions of energy systems with information technology, communications, and telecommunications (ICT) systems. The NIPs agreement was a bit different from traditional research projects because it was specifically structured to enable partnerships for ESIF testing and as such required at least a 1:1 funds-in cost share from industry partners. In the end, the project engaged six different industry partnerships and resulted in testing a large number of innovative technologies. These included tiny inverters; power-to-gas technologies; and advanced simulation, analysis, and power-hardware-in-the-loop testing techniques. The agreement also provided significant impact for both research and industrial communities. This summary report provides a brief, high-level overview of these projects and their highlights along with lists of citations and other impacts. Readers are referred to the corresponding project reports for more in-depth information.

14 SOLAR ENERGY↗

Solar Energy Technologies Office Workforce Request for Information and Convenings (Summary)

On May 4, 2021, the U.S. Department of Energy (DOE) Solar Energy Technologies Office (SETO) published a Request for Information (RFI) on programs that support the development of a diverse and skilled clean energy workforce. The purpose of the RFI was to solicit feedback from industry, academia, government agencies, worker organizations (including unions), and other stakeholders on issues related to the employment needs of the solar industry, and the perceived value of different workforce development programs, training strategies, and tools. To supplement the RFI, SETO hosted four virtual convenings that brought together the utility-scale solar industry, the distributed generation solar industry, and labor and other workforce training organizations to hear direct feedback on the questions in the RFI. In addition, SETO held listening sessions with about a dozen other organizations and staff who could not participate in the virtual convenings. Altogether, SETO received 45 responses from the RFI and heard directly from 80-100 other stakeholders via the convenings and listening sessions. This document summarizes the stakeholder feedback that SETO received as a result of this process. While both the RFI and convening series were focused on solar deployment and solar industry members, much of this information is relevant across clean energy technologies and programs. It is important to recognize that DOE is intentionally reviewing our workforce development programming and support to focus on clean energy careers more holistically.

14 SOLAR ENERGY↗

Roadmap for Solar Photovoltaic (PV) Cybersecurity: A vision for improving cyber maturity of distributed and utility-scale solar energy installations

As the solar energy sector continues to expand, its integration into the broader energy infrastructure presents both unprecedented opportunities and new risks. The increasing reliance on digital technologies and interconnected systems in solar energy creates an expanded attack surface for motivated cyber adversaries. Cyberattacks have the potential to cause disruptions in energy production, damage to equipment, financial losses, and compromises in national security. Therefore, ensuring robust cybersecurity measures is paramount to protect the integrity, availability, confidentiality, and access control of solar energy systems. However, there are still key gaps and challenges to be addressed in industry and research, which stakeholders must race to address as they combat a growing number of real-world cyber incidents that affect solar energy systems and a growing number of vulnerabilities discovered and disclosed in key types of equipment. This roadmap explore the current state of solar PV cybersecurity and the gaps and challenges still to be addressed.

14 - SOLAR ENERGY↗

Charge Carrier Activity on Single-Particle Photo(electro)catalysts: Toward Function in Solar Energy Conversion

Understanding the fundamental properties of charge carriers on the surface of semiconductor photo(electro)catalysts is key to the rational design of efficient photo(electro)catalytic devices for sunlight-driven energy conversion. Here high spatial resolution information is always desirable because of the ubiquitous heterogeneity in semiconductor particles. In this Perspective, we review the latest advances in nanoscale imaging and quantitative analysis of charge carrier activities on individual semiconductor particles down to subparticle resolution, covering the approaches of single-molecule super-resolution fluorescence imaging, scanning electron microscopy, and photoluminescence microscopy. We further highlight direct, operando functional assessments of their performances toward the targeted photo(electro)-catalytic processes through single- and subparticle photocurrent measurements. Here, we also discuss the significance of establishing quantitative relations between the desired functions of photo(electro)catalysts and their surface charge carrier activities. These fundamental relations can provide guiding principles for rationally engineering photo(electro)catalytic systems, for example with cocatalysts, for a broad range of applications.

14 SOLAR ENERGY↗