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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1990

Space Electrochemical Research and Technology Conference, 2nd, Cleveland, OH, Apr. 11-13, 1989, Proceedings

Attention is given to topics of advanced concepts, hydrogen-oxygen fuel cells and electrolyzers, nickel electrodes, and advanced rechargeable batteries. Papers are presented on human exploration mission studies, advanced rechargeable sodium batteries with novel cathodes, advanced double-layer capacitors, recent advances in solid-polymer electrolyte fuel cell technology with low platinum loading electrodes, electrocatalysts for oxygen electrodes in fuel cells and water electrolyzers for space applications, and the corrosion testing of candidates for the alkaline fuel cell cathode. Other papers are on a structural comparison of nickel electodes and precursor phases, the application of electrochemical impedance spectroscopy for characterizing the degradation of Ni(OH)2/NiOOH electrodes, advances in lightweight nickel electrode technology, multimission nickel-hydrogen battery cell for the 1990s, a sodium-sulfur battery flight experiment definition study, and advances in ambient-temperature secondary lithium cells.

O'Donnell, Patricia M.↗

NASA NTRS1992

Lidar Measurements of Metallic Species in Mesopause Region

Sodium density distributions were measured over more than 20 nights since Jul. 1991 at Tokyo Metropolitan University. Our sodium lidar specifications are shown. The lidar consists of a dye laser that is pumped by a pulsed Nd:YAG laser. The dye laser is tuned to the D2 resonant absorption line of Na at the wavelength of 589 nm. A small fraction of the output beam is directed to a hollow-cathode lamp. The precise tuning of the Na D2 line is accomplished by monitoring the signal obtained from the hollow-cathode lamp and controlling the grating in the dye laser oscillator cavity. The raw data for each profile were obtained by firing the laser 5000 times for approximately 8.5 minutes. We have observed the sporadic sodium layers three times during the observation period. Recently, lidar measurements of iron atoms were also performed. Other aspects of this investigation are presented.

Nagasawa, Chikao↗

NASA NTRS1995

Ni/NiCI(2) Reference Electrodes For Na/NiCI(2) Cells

Reference electrodes made of nickel cores with surface layers of nickel chloride proposed for use in molten sodium tetracholoroaluminate electrolytes in experimental sodium/nickel chloride electrochemical cells. These and other sodium/metal chloride cells investigated for use in several applications, including powering electric vehicles and leveling loads in power-distribution systems. Offers potential advantages of greater durability, greater stability and reproducibility of electrochemical potentials, less sensitivity of electrochemical potentials to variations in compositions of electrolytes, and greater compatibility with cathodes, made of nickel chloride.

Bugga, Ratnakumar↗

NASA NTRS1974

Development of sputtered techniques for thrust chambers, task 1

Filler materials proposed for use in the sputter fabrication regeneratively cooled thrust chambers were evaluated. Low melting castable alloys, CERROBEND. CERROCAST, and CERROTRU, slurry applied SERMETEL 481 and flame-sprayed aluminum were investigated as filler materials. Sputter deposition from a cylindrical cathode inverted magnestron was used to apply an OFHC copper closeout layer to filled OFHC copper ribbed-wall cylindrical substrates. The sputtered closeout layer structure was evaluated with respect to filler material contamination, predeposition machining and finishing operations, and deposition parameters. The application of aluminum by flame-spraying resulted in excessiver filler porosity. Though the outgassing from this porosity was found to be detrimental to the closeout layer structure, bond strengths in excess of 10,500 psi were achieved. Removal of the aluminum from the grooves was readily accomplished by leaching in a 7.0 molar solution of sodium hydroxide at 353 K. Of the other filler materials evaluated, CERROTRU was found to be the most suitable material with respect to completely filling the ribbed-wall cylinders and vacuum system compatibility. However, bond contamination resulted in low closeout layer bond strength with the CERROTRU filler. CERROBEND, CERROCAST, and SERMETEL 481 were found to be unacceptable as filler materials.

Mullaly, J. R.↗