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DOE OSTI2020

Materials Data on SnH4(NF)2 by Materials Project

SnH4(NF)2 crystallizes in the monoclinic C2/m space group. The structure is one-dimensional and consists of two SnH4(NF)2 ribbons oriented in the (0, 1, 0) direction. Sn4+ is bonded to four equivalent N3- and two equivalent F1- atoms to form edge-sharing SnN4F2 octahedra. All Sn–N bond lengths are 2.18 Å. Both Sn–F bond lengths are 2.05 Å. N3- is bonded in a distorted water-like geometry to two equivalent Sn4+ and two H1+ atoms. There is one shorter (1.02 Å) and one longer (1.03 Å) N–H bond length. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N3- atom. F1- is bonded in a single-bond geometry to one Sn4+ atom.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on SnH4 by Materials Project

SnH4 crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 7440-31-5 molecules and four hydrogen molecules.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on SnH4 by Materials Project

SnH4 crystallizes in the orthorhombic Ama2 space group. The structure is two-dimensional and consists of four hydrogen molecules and two H2Sn sheets oriented in the (0, 0, 1) direction. In each H2Sn sheet, Sn2+ is bonded in a 2-coordinate geometry to four equivalent H+0.50- atoms. There are two shorter (1.94 Å) and two longer (2.34 Å) Sn–H bond lengths. H+0.50- is bonded in a distorted bent 120 degrees geometry to two equivalent Sn2+ atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on SnH4 by Materials Project

SnH4 crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four 7440-31-5 molecules and eight hydrogen molecules.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on SnH4 by Materials Project

SnH4 is Cyanogen Chloride-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two hydrogen molecules and two snh2 molecules.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on SnH4(ClO)2 by Materials Project

SnH2OCl2H2O crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four stannous chloride hydrate molecules and four water molecules.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on SnH10Br4O5 by Materials Project

SnH4(OBr2)2(H2O)3 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twelve water molecules and four SnH4(OBr2)2 clusters. In each SnH4(OBr2)2 cluster, Sn4+ is bonded in an octahedral geometry to two equivalent O2- and four Br1- atoms. Both Sn–O bond lengths are 2.19 Å. There are two shorter (2.58 Å) and two longer (2.60 Å) Sn–Br bond lengths. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. O2- is bonded in a distorted bent 120 degrees geometry to one Sn4+ and two H1+ atoms. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one Sn4+ atom. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Sn4+ atom.

36 MATERIALS SCIENCE↗