Materials Data on SnC8(NCl3)2 by Materials Project
(C4N)2SnCl6 is Fluorite structured and crystallizes in the cubic Fd-3c space group. The structure is zero-dimensional and consists of sixty-four tetramethylammonium molecules and thirty-two SnCl6 clusters. In each SnCl6 cluster, Sn4+ is bonded in an octahedral geometry to six equivalent Cl1- atoms. All Sn–Cl bond lengths are 2.49 Å. Cl1- is bonded in a single-bond geometry to one Sn4+ atom.
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