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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on Sn4Rh by Materials Project

RhSn4 crystallizes in the trigonal P3_121 space group. The structure is three-dimensional. Rh is bonded in a 8-coordinate geometry to eight Sn atoms. There are a spread of Rh–Sn bond distances ranging from 2.76–2.90 Å. There are three inequivalent Sn sites. In the first Sn site, Sn is bonded in a 2-coordinate geometry to two equivalent Rh atoms. In the second Sn site, Sn is bonded in a distorted water-like geometry to two equivalent Rh atoms. In the third Sn site, Sn is bonded in a distorted bent 120 degrees geometry to two equivalent Rh atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Sn4Rh by Materials Project

RhSn4 crystallizes in the tetragonal I4_1/acd space group. The structure is two-dimensional and consists of four RhSn4 sheets oriented in the (0, 0, 1) direction. Rh is bonded in a 8-coordinate geometry to eight equivalent Sn atoms. There are four shorter (2.78 Å) and four longer (2.79 Å) Rh–Sn bond lengths. Sn is bonded in a 2-coordinate geometry to two equivalent Rh atoms.

36 MATERIALS SCIENCE↗