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Sn3P crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. Sn is bonded in a 12-coordinate geometry to eight equivalent Sn and two equivalent P atoms. There are a spread of Sn–Sn bond distances ranging from 3.15–3.36 Å. Both Sn–P bond lengths are 3.21 Å. P is bonded in a distorted hexagonal planar geometry to six equivalent Sn atoms.
Sn3P is Uranium Silicide structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sn is bonded in a 12-coordinate geometry to eight equivalent Sn and four equivalent P atoms. All Sn–Sn bond lengths are 3.28 Å. All Sn–P bond lengths are 3.28 Å. P is bonded in a 12-coordinate geometry to twelve equivalent Sn atoms.
Sn3P is alpha bismuth trifluoride structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. there are two inequivalent Sn sites. In the first Sn site, Sn is bonded in a body-centered cubic geometry to four equivalent Sn and four equivalent P atoms. All Sn–Sn bond lengths are 3.18 Å. All Sn–P bond lengths are 3.18 Å. In the second Sn site, Sn is bonded in a body-centered cubic geometry to eight equivalent Sn atoms. P is bonded in a body-centered cubic geometry to eight equivalent Sn atoms.