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Materials Data on Sn(NF2)4 by Materials Project

SnF6(FN2)2 crystallizes in the orthorhombic Pccn space group. The structure is zero-dimensional and consists of four tetrafluorostannane;dihydrofluoride molecules and eight FN2 clusters. In each FN2 cluster, there are two inequivalent N1+ sites. In the first N1+ site, N1+ is bonded in a bent 150 degrees geometry to one N1+ and one F1- atom. The N–N bond length is 1.11 Å. The N–F bond length is 1.94 Å. In the second N1+ site, N1+ is bonded in a single-bond geometry to one N1+ atom. F1- is bonded in a single-bond geometry to one N1+ atom.

36 MATERIALS SCIENCE↗