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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

PINCH POINT ANALYSIS OF GAS COOLERS IN TRANSCRITICAL R1336mzz(Z) HIGH-TEMPERATURE HEAT PUMPS

The majority of high-temperature heat pumps (HTHPs) operate subcritical vapor compression cycles, where the maximum sink temperature is limited by the critical temperature of refrigerants. In HTHPs with a sink temperature of ≥ 150°C, transcritical cycles overcome this limitation by rejecting heat in the supercritical regions of refrigerant. Supercritical refrigerants in gas coolers have a large temperature glide and substantial nonlinear variation in specific heat capacity vs. temperature. Closely matching the refrigerant glide temperature and the heat sink temperature profile greatly impacts the heat transfer characteristic of gas coolers and the overall performance of HTHPs. This study conducts a pinch point analysis for the gas cooling process of supercritical R1336mzz(Z) in HTHPs. A finite volume element model of a supercritical R1336mzz(Z) counterflow gas cooler is built and solved. This study evaluates the influences of operating conditions, including inlet and outlet of coolants, refrigerant evaporation temperature and superheat degree, pinch temperature difference, and heat rejection pressure, on the performance of HTHPs. The optimal discharge pressures in gas coolers are proposed for industrial spray dryers in providing drying air at 170°C−210°C. The results of the present study help design gas coolers in transcritical R1336mzz(Z) HTHPs.

Wang, Pengtao↗
DOE OSTI2020

Evaluation of the DC bus link capacitors and power transistor modules in the qualification testing of PV inverters

To achieve useful, fair, and cost-effective design qualification and type approval testing for PV inverters, two procedures were developed and demonstrated to evaluate the bus link capacitors and power transistor—and where applicable, its module—for long-term reliability. We evaluate the inverter under simulated use conditions with heat run tests to find the highest operating temperatures reached by these components. The procedures are demonstrated in this study with a 4-kVA class string inverter. The maximum temperature of the DC bus link capacitors was determined to be 76.4°C when the ambient temperature was at the inverter's maximum rated temperature of 60°C with derating occurring. On the other hand, the power transistor module's maximum temperature using the heat sink temperature as the index, 92.6°C, occurred in an ambient of 40.8°C when derating was not occurring. The conditions found for upper temperatures exhibited by these components are, respectively, proposed for implementation in the dry heat and thermal cycling tests in the IEC 62093 “Power conversion equipment for photovoltaic systems – Design qualification testing” international standard draft so that the levels applied in the tests are in proportion to those experienced in the field. Finally as a result, fairer evaluation of inverter reliability is realized.

14 SOLAR ENERGY↗
DOE OSTI2023

Demand reduction and energy saving potential of thermal energy storage integrated heat pumps [Réduction de la demande et potentiel d'économie d'énergie des pompes à chaleur avec stockage d'énergie thermique intégré]

A heat pump (HP) moves heat from a low-temperature source to a high-temperature sink with an input of energy. Often, one temperature body fluctuates with time (e.g., diurnal ambient temperature), causing the HP efficiency to vary. Integrating thermal energy storage (TES) into a HP system adds a third temperature body, enabling the HP to be advantageously coupled to any two: the application, the ambient, or the TES at strategic times. Although TES integration with HPs is an important emerging technology to lower energy consumption and decrease energy demand during critical times, the favorable circumstances for TES integration are poorly understood. Here, this paper establishes the energy reduction and demand reduction potential of TES-integrated HPs with both analytical and numerical HP models. All possible temperature arrangements are considered for HP-TES systems with two fixed temperature bodies (application and TES) and one variable temperature (ambient). Results show that overall energy savings are most attainable when the TES temperature is near the application temperature, whereas a large temperature difference between the TES and the application leads to the most peak demand reduction. The potential for overall energy savings increases as the magnitude of ambient temperature fluctuations increases.

25 ENERGY STORAGE↗
DOE OSTI2023

Cooling performance of an active-passive hybrid composite phase change material (HcPCM) finned heat sink: Constant operating mode

Here, the present study explores a hybrid thermal management technology based on air cooling and hybrid composite phase change material (HcPCM) filled finned heat sink for cooling performance of lower to medium heat flux dissipating electronic devices. Two-dimensional numerical simulations are conducted to study the conjugate heat transfer effects of three types of finned heat sink: air-cooled finned heat sink, HcPCM-cooled finned heat sink, and hybrid (air-HcPCM) cooled finned heat sink. A heat sink with a constant volume faction of plate-fins is designed in all cases and simultaneous effects of hybrid nanoparticles and air are investigated to keep the heat sink temperature at safe operating conditions between 40–60°C. The effect of air is incorporated into the heat sink by applying the convective heat transfer coefficient of h c = 10–100W /m 2 .K which tends to create the natural convection and forced convection heat transfer characteristics. The heat flux is varied from 25–40kW /m 2 in the current study. The hybrid nanoparticles of carbon additives (GO and MWCNTs) are dispersed into the RT-35HC, used as a PCM, with a volume fraction of 0% to 6%. Transient simulations are carried out using COMSOL Multiphysics to solve the governing equations for PCM based conjugate heat transfer model. The results showed that forced convection heat transfer improved the cooling performance of the hybrid heat sink compared to natural convection heat transfer. The addition of nanoparticles further enhanced thermal enhancement and uniform melting distribution of PCM inside the finned heat sink. The h c between 30 to 50W/m 2 .K shows optimized values for forced convection heat transfer operating conditions. The volume fraction of 2% of GO+MWCNTs nanoparticles in recommended or optimum concentration for uniform melting of PCM inside the finned heat sink.

36 MATERIALS SCIENCE↗
DOE OSTI2024

High Temperature Heat Pumps and Their Roles in the Decarbonization of Building and Industry

Heat pumps have been sought as a promising technology for air and water heating processes in buildings. Several OEMs have been commercializing heat pumps with varying capacities; However, the application has been limited to lower temperatures (less than 70℃). With the recently growing interest in replacing gas-fired equipment for buildings and industrial processes, a new class of heat pumps, known as high-temperature heat pumps, is gaining substantial interest where the target temperatures are higher than the conventional heat pump technology (greater than 90℃). The current study is focused on this class of heat pumps and aims to provide a holistic overview of state-of-the-art technology while highlighting major challenges and opportunities. The discussion will be focused on the availability of technology to enable higher sink temperatures, deployment-based applications, waste heat recovery, and process integration and controls.

Nawaz, Kashif↗
DOE OSTI2023

Exploration of Heat-Driven Ejector High-Temperature Heat Pumps

Heat-driven ejector heat pumps use a supersonic ejector as a thermo-compressor to replace the mechanical compressor. Supersonic ejectors have many advantages in high-temperature heat pump (HTHP) applications, including high operating temperature tolerance, no need for lubrication, low maintenance, and low cost. The coefficient of performance of ejector HTHPs could be improved by selecting binary fluids with unique thermodynamic properties. Although supersonic ejectors have been widely used in refrigeration systems, their application in spaces and water heating is limited. This study explores the theoretical potential of ejector HTHPs with a sink temperature of 100°C–130°C and a lift temperature of 10°C–30°C. Ejector HTHPs were evaluated with single-fluid ejectors (SFEs) and binary-fluid ejectors (BFEs). A comprehensive, geometry-free theoretical model of BFEs was developed to predict the theoretical maximum entrainment ratios. HFE7500 and R718 (water) were selected as working fluids for SFEs and BFEs. SFEs operating with R718 provided a higher coefficient of performance of ejector HTHPs than SFEs operating with HFE7500 and BFEs. This study preliminarily demonstrates the technical potential of ejector HTHP applications in recovering moderate-temperature heat sources

Wang, Pengtao↗
DOE OSTI2024

Impact of Heaters on Molten Salt Reactors Dynamics

Recently, there has been renewed interest in the Molten Salt Reactor (MSR) concept. This interest is mainly due to its advantages over Light Water Reactors (LWRs). Among these advantages are the flexibility in the fuel choice and the possibility to burn actinides [1]. Currently, two molten research reactors are under development. A 2 MW molten salt experimental reactor has been constructed and is planned for operation in China. A 1 MW Molten Salt Research Reactor is under construction in the United States [2]. Thus, Research and Development (R&D) programs are needed for the MSR technology. Reactor dynamics studies are crucial safety evaluation studies. The development of reactor dynamics tools for MSRs started during the Molten Salt Reactor Program (MSRP) at ORNL, focusing on the Molten Salt Reactor Experiment (MSRE) [3]. Although various dynamic simulation tools are available, R&D efforts to develop specialized tools for MSRs are still ongoing [4]. The primary motivation for this interest is the goal of commercializing MSRs. Developing a dynamics tool for MSRs is crucial for analyzing their safety and supporting their demonstration efforts. A crucial safety issue in MSRs is ensuring that the fuel salt in the primary loop remains molten. This concern becomes particularly important when the reactor operates at lower power levels. Most chloride and fluoride salts used as fuel have a melting point of approximately 450 °C [5]. Therefore, maintaining fuel salt temperatures above this melting point is essential to prevent it from freezing. Freezing of the fuel salt can lead to volume expansion, potentially causing damage to reactor components [6]. Moreover, it can create local blockages within fuel salt channels, reducing cooling efficiency and resulting in hot spots [7]. Various methods can prevent fuel salt from freezing at low power levels. These include reducing the fuel mass flow rate in the primary loop, decreasing heat exchange between the primary and secondary loops in the reactor, and using electric fuel salt heaters. Reducing the mass flow rate of fuel salt in the primary loop can increase the fuel salt transit time in the core, enhancing heat production and increasing temperature. However, it can potentially lead to challenges. These include increasing the potential for fuel salt deposition on the reactor channel walls [8], affecting the overall heat transfer processes. Thus, alternative methods should be used [9]. This research investigates the effects of fuel salt heaters on the dynamics and stability during MSR operation. The investigation includes studying the reactor stability with the fuel salt heaters on and off. In addition, the reactor response to transients is compared with and without the operation of fuel salt heaters. These transients include reactivity insertion, primary and secondary pump failure, and heat sink temperature increase. The results of the reactivity insertion transient are presented in the summary.

73 - NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Performance Analysis of High-Temperature Heat Pumps with Two-Phase Ejectors

A two-phase ejector recovers the energy in the refrigerant cycles’ throttling process, improving the coefficient of performance (COP) of high-temperature heat pumps (HTHPs). This study investigated the effects of the mixing pressure on the performance of two-phase ejectors and ejector-assisted HTHPs. A 1D theoretical model of a two-phase ejector was built to predict the internal fluid dynamics and evaluate ejector performance. A thermodynamic model of an ejector-assisted HTHP was built to evaluate the COP of HTHPs and the volumetric heating capacity of low-global warming potential refrigerants. The results demonstrate that an optimum mixing pressure in a two-phase ejector provides the best performance of a two-phase ejector and ejector-assisted HTHP. The optimum mixing pressure was slightly lower than the evaporation pressure. At this pressure, the two-phase flow in the ejector was subsonic. For ejector-assisted HTHPs using low–global warming potential refrigerants at a sink temperature of 120°C, temperature lift of 40°C, and subcooling of 10°C, a two-phase ejector has an average ejector efficiency of 0.334, and the COP and volumetric heating capacity were improved by 7.2% and 7.3%, respectively.

Wang, Pengtao↗
DOE OSTI2021

Thermodynamic Modeling of Heat Engines Including Heat Transfer and Compression–Expansion Irreversibilities

In this paper, a thermodynamic model based on an endoreversible engine approach is developed to analyze the performance of heat engines operating under different thermodynamic cycles. The model considers finite heat transfer rate, variable heat source and sink temperatures, and irreversibilities associated with the expansion and compression. Expressions for the maximum power and efficiency at maximum power output are obtained as a function of hot and cold reservoir temperatures, the equivalent isentropic efficiency of compression and expansion components, and the effective conductance ratio between heat exchangers. In all cases, the Curzon–Ahlborn efficiency is retrieved at constant reservoir temperatures and neglected compression–expansion irreversibilities. The proposed model allows assessing the effect of isentropic efficiencies and heat exchanger design and operation characteristics for different thermodynamic cycles.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2025

In-flight performance of the XRISM/Resolve detector system

The Resolve instrument was launched on board the XRISM observatory in early September 2023. The Resolve spectrometer is based on a high-sensitivity X-ray calorimeter detector system (DS) that has been successfully deployed in many ground and sub-orbital spectrometers. However, the Resolve instrument is the first long-term implementation in space. The instrument will provide essential diagnostics for nearly every class of X-ray emitting objects, from galactic supernova remnants to the outskirts of galaxy clusters, without degradation for spatially extended objects. The Resolve DS consists of a 36-pixel microcalorimeter array operated at a heat sink temperature of 50 mK. In pre-flight testing, the DS demonstrated a resolving power of better than 1300 at 6 keV with a simultaneous bandpass from below 0.3 keV to above 12 keV and a timing precision better than 100μs. An anti-coincidence detector placed directly behind the microcalorimeter array effectively suppresses background. The detector energy-resolution budget included terms for interference from the Resolve cooling system and the spacecraft. Additional terms for energy-scale stability, on-orbit effects, and use of mid-grade events were also included, predicting an end-of-life, on-orbit performance for high- and mid-resolution grade events that meet the requirement of 7 eV FWHM at 6 keV. Here, we discuss the actual on-orbit performance of the Resolve DS and compare this with the performance in pre-flight testing, on-orbit predictions, and the almost identical Hitomi/SXS instrument. We will also discuss the on-orbit gain stability, an assessment of on-orbit interference, and measurements of the on-orbit background.

Astronomy and AstroPhysics↗
DOE OSTI2022

Efficiency and Capacity Performance of a Stirling-Cycle Water-to-Water Heat Pump

The performance of a 10 kW (2.8 ton) heat pump has been modeled in preparation for evaluation in a controlled-atmosphere psychrometric facility. The heat pump uses an electrically driven Stirling engine with nitrogen as a working fluid. The appropriate standards for testing are ANSI/AHRI/ASHRAE ISO Standard 13256-2:1998 (RA 2012), Water-Source Heat Pumps—Testing and Rating for Performance—Part 2: Water-to-Water and Brine-to-Water Heat Pumps. The heating and cooling efficiency and capacity of the device has been modeled at different hot and cold sink temperatures spanning a wide range of possible operating conditions. The heat pump was designed for a seasonal efficiency energy ratio (SEER) of 22. The high efficiency of this product coupled with the use of nitrogen as a working fluid makes it an important tool for the decarbonization of residential, commercial, and industrial HVAC&R applications.

Kowalski, Steve↗
DOE OSTI2026

Dual Purpose – Heating & Cooling – Thermal Battery for Flexible and Energy-Efficient Heat Pump Systems

The integration of heat pumps with thermal energy storage (HP-TES) systems is gaining attention as a viable solution for managing peak building demand driven by immense cooling and heating loads. With growing reliance on renewable energy sources, thermal energy storage offers an excellent opportunity to mitigate mismatches in thermal load between energy supply and demand. The use of phase-change material (PCM) TES is especially promising, as PCMs offer significant latent energy storage capacity with smaller temperature glides in smaller volumes compared to other TES technologies. However, challenges arise because current HP-TES architectures can load-shift only cooling or heating, not both, requiring two systems and thus doubling cost, weight, and footprint. Furthermore, current research efforts lack specific tools and techniques to advance integrated systems from concept design to end-user application, focusing on only discharge performance. To address these challenges, this research proposes a dual-mode (heating and cooling) integrated HP-TES system that uses room-temperature PCM-TES as a high-temperature heat source in heating mode and a low-temperature heat sink in cooling mode, thereby reducing temperature lifts and compressor power. Design criteria for PCM-TES heat exchangers were developed, balancing thermal-hydraulic performance with practical constraints such as available building space and weight requirements along with PCM selection considerations such as shipping conditions, moisture exposure, and number of available cycles. A detailed transient model for HP-TES systems was developed to enable rapid annual performance assessments in any US climate zone.

42 ENGINEERING↗
DOE OSTI2023

Effect of Production Bias on Radiation-Induced Segregation in Ni-Cr Alloys

We present an in-depth investigation into the Radiation-Induced Segregation (RIS) phenomenon in Ni-Cr alloys. All the pivotal factors affecting RIS such as surface’s absorption efficiency, grain size, production bias, dose rate, temperature, and sink density were systematically studied. Through comprehensive simulations, the individual and collective impacts of these factors were analyzed, enabling a refined understanding of RIS. A notable finding was the significant influence of production bias on point defects’ interactions with grain boundaries/surfaces, thereby playing a crucial role in RIS processes. Production bias alters the neutrality of these interactions, leading to a preferential absorption of one type of point defect by the boundary and consequent establishment of distinct surface-mediated patterns of point defects. These spatial patterns further result in non-monotonic spatial profiles of solute atoms near surfaces/grain boundaries, corroborated by experimental observations. In particular, a positive production bias, signifying a higher production rate of vacancies over interstitials, drives more Cr depletion at the grain boundary. Moreover, a temperature-dependent production bias must be considered to recover the experimentally reported dependence of RIS on temperature. The severity of radiation damage and RIS becomes more pronounced with increased production bias, dose rate, and grain size, while high temperatures or sink density suppress the RIS severity. Model predictions were validated against experimental data, showcasing robust qualitative and quantitative agreements. The findings pave the way for further exploration of these spatial dependencies in subsequent studies, aiming to augment the comprehension and predictability of RIS processes in alloys.

36 MATERIALS SCIENCE↗
DOE OSTI2024

First-principles investigation of lanthanides diffusion in HCP zirconium via vacancy-mediated transport

The diffusion of lanthanide fission products plays an important role in the growth of the fuel-cladding chemical interaction (FCCI) region in metallic fuels. The use of a Zr interdiffusion barrier may mitigate the transport of lanthanides from the fuel to the cladding, but the efficacy of such a liner is not yet known. In this paper, the stability and vacancy-mediated diffusion of La, Ce, Pr, and Nd in hexagonal close-packed (HCP) Zr is investigated via density functional theory (DFT) calculations and self-consistent mean field (SCMF) analysis. DFT is used to calculate the formation, binding, and migration energies of vacancies and vacancy-solute pairs. The DFT energetics are used in the KineCluE code to calculate the Onsager transport coefficients. La is found to be the fastest diffusing species in HCP Zr and experiences an almost isotropic diffusion behavior. The other three species (Ce, Pr, and Nd) demonstrate anisotropic diffusion where the diffusion in the basal planes is significantly faster than that along the c-axis. Further, the calculated lanthanide diffusivities in HCP Zr are fitted to an Arrhenius relation and the activation energies and prefactors are reported for the first time. Furthermore, the vacancy drag and the segregation tendencies were analyzed using the calculated off-diagonal transport coefficients. According to our vacancy-mediated diffusion model, lanthanides are expected to be enriched at vacancy sinks at low temperatures, while at high temperatures, lanthanides are depleted at sinks and will preferably diffuse into the bulk. The enrichment/depletion transition temperature depends on the diffusion direction (basal or axial) and hence will be controlled by the grain texture and orientation.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2023

THOR-aLEU Report

The advanced low enriched uranium (aLEU)-THOR experiment vehicle is designed to irradiate fresh fuel rodlet specimens containing UO 2 (uranium dioxide) in the Temperature Heat-sink Overpower Response (THOR) capsule. The goal of the experiments are to compare the behaviors of standard UO 2 pellets to an aLEU concept in which molybdenum (Mo) foils separate UO 2 wafers increasing the thermal conductivity of the fuel. This experiment is designed to be conducted in the Transient Reactor Test facility (TREAT) using the Minimal Activation Retrievable Capsule Holder (MARCH) irradiation system. The goal of these experiments is to assess the effect of thermally conductive inserts in UO 2 by measuring their net effect on radial thermal conductivity using transient nuclear heating and then to determine their power-to-melt threshold in transient overpower ramps. The objective of the aLEU-THOR fuels experiment is to determine the viability and study the performance of UO 2 fuel pellets employing newly upgraded TREAT capability. A novel transient measurement technique will be used with the THOR capsule, which has a solid heat sink to generate the transient temperature gradient for conductivity measurement.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Thermodynamic analysis and optimization of supercritical carbon dioxide Brayton cycles for use with low-grade geothermal heat sources

The transcritical carbon dioxide Rankine cycle has emerged as an alternative for power generation in low-grade heat applications. However, the low heat rejection temperatures required for condensing the carbon dioxide is almost prohibitive for many locations. A simple solution is the adoption of a supercritical carbon dioxide Brayton cycle which does not need such low temperature heat sinks. This power cycle has been poorly studied previously in low-grade heat applications. Therefore, with the aim of determining the performance and feasibility of the supercritical carbon dioxide Brayton cycle from thermodynamic viewpoint, using a low-grade geothermal heat source, this paper presents a comparative thermodynamic analysis between four different supercritical carbon dioxide Brayton cycles. For this purpose, detailed models were developed and solved by coupling the thermodynamic model with the thermal-hydraulic model of a Printed Circuit Heat Exchanger. Subsequently, simulations of a base case, a parametric analysis, and an optimization using Genetic Algorithms, were carried out. Results show that there is a combination of operating conditions that maximizes the electrical output of the system. Besides, some values of the minimum pressure of the cycles can increase substantially the precooler cooling water pumping power. At the optimum design point, using a 20 kg/s geothermal brine stream at 150 °C as heat source with a minimum allowable reinjection temperature of 70 °C, the Intercooled Recuperated Brayton Cycle achieved the highest electric power output, energy and exergy efficiencies, obtaining values of 779.99 kW, 11.51%, and 52.49%, respectively. The other feasible alternatives were the Recuperated Brayton Cycle, the Simple Brayton Cycle and the Intercooled Brayton Cycle, ranked, in that order.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2022

Dynamic optimization with flexible heat integration of a solar parabolic trough collector plant with thermal energy storage used for industrial process heat

There is an increasing need to reduce fossil fuel consumption used for industrial process heat to slow the effects of climate change. Using solar thermal heat is a viable way to replace fossil fuel use, but solar industrial process heat plants have limited implementation due to large upfront costs and inefficiencies from the inherent variability from solar energy. Having more flexible and optimized control over these plants can enable them to be more efficient. Here in this work, a solar industrial process heat plant with thermal energy storage that can flexibly collect and deliver heat to two industrial processes (flexible heat integration) is dynamically modeled with control setpoints found by a dynamic optimization method. The optimized case can increase the solar efficiency of the plant by 7.5% on average relative to a base case. The results show that it is best to collect heat at lower temperatures for all but ideal solar conditions, only medium to high quality heat should be stored in large quantities, and exchanging heat with a lower temperature heat sink is generally more efficient. The optimized case is able to reduce the levelized cost of heat of the plant to $31.83/MWh th compared to a base case value of $34.10/MWh th . The optimized case can reduce emissions by 22.2% compared to a plant which uses only natural gas. This work shows that dynamic optimization with flexible heat integration can be a cost-effective way to increase efficiency so that more of these types of plants can be implemented.

14 SOLAR ENERGY↗
DOE OSTI2021

Site Ambient Temperatures and Operating Schedules for EIC - Utility CW Considerations

The heat dissipated by the EIC accelerator system and components is ultimately removed by the conventional water-cooling systems that will be ultimately dissipated the waste heat to the atmosphere. An estimated 45 MW of heat will be dissipated to water during full beam operation and that will need to be effectively rejected to the atmosphere. Approximately 50% of the heat is required to be rejected to a low temperature heat sink that cannot be achieved by an evaporative cooling tower during summer. To operate during these summer months, a secondary chilled water refrigeration system will be required that would increase the cost of the cooling water system. Further, operating chiller compressor in the summer months will increase the energy consumption of the machine. This analysis is being prepared to evaluate the impact on operating and capital costs on the cooling system for various summer operating schedules while utilizing the most cost-effective scenario of an evaporative cooling system. The technology selection for the various heat sinks is addressed in a separate write-up and are not expected to change the conclusions of this write-up.

43 PARTICLE ACCELERATORS↗