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RhSi is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Rh4+ is bonded in a body-centered cubic geometry to eight equivalent Si4- atoms. All Rh–Si bond lengths are 2.58 Å. Si4- is bonded in a body-centered cubic geometry to eight equivalent Rh4+ atoms.
YbRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Yb2+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Yb–Si bond lengths are 3.16 Å. Rh3+ is bonded to four equivalent Si4- atoms to form a mixture of corner and edge-sharing RhSi4 tetrahedra. All Rh–Si bond lengths are 2.39 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Yb2+, four equivalent Rh3+, and one Si4- atom. The Si–Si bond length is 2.49 Å.
RhSi is alpha-derived structured and crystallizes in the cubic P2_13 space group. The structure is three-dimensional. Rh4+ is bonded in a 7-coordinate geometry to seven equivalent Si4- atoms. There are a spread of Rh–Si bond distances ranging from 2.50–2.55 Å. Si4- is bonded in a 7-coordinate geometry to seven equivalent Rh4+ atoms.
Ba(RhSi)2 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Ba2+ is bonded in a 6-coordinate geometry to six Si4- atoms. There are a spread of Ba–Si bond distances ranging from 3.39–3.55 Å. There are two inequivalent Rh3+ sites. In the first Rh3+ site, Rh3+ is bonded to four Si4- atoms to form a mixture of edge and corner-sharing RhSi4 tetrahedra. There are a spread of Rh–Si bond distances ranging from 2.34–2.43 Å. In the second Rh3+ site, Rh3+ is bonded to four Si4- atoms to form a mixture of distorted edge and corner-sharing RhSi4 tetrahedra. There are a spread of Rh–Si bond distances ranging from 2.38–2.44 Å. There are two inequivalent Si4- sites. In the first Si4- site, Si4- is bonded in a 4-coordinate geometry to three equivalent Ba2+ and four Rh3+ atoms. In the second Si4- site, Si4- is bonded in a 4-coordinate geometry to three equivalent Ba2+ and four Rh3+ atoms.
Np(RhSi)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Np is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Np–Rh bond lengths are 3.22 Å. All Np–Si bond lengths are 3.05 Å. Rh is bonded to four equivalent Np and four equivalent Si atoms to form a mixture of distorted edge, corner, and face-sharing RhNp4Si4 tetrahedra. All Rh–Si bond lengths are 2.41 Å. Si is bonded in a 9-coordinate geometry to four equivalent Np, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.34 Å.
GdRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Gd is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Gd–Rh bond lengths are 3.24 Å. All Gd–Si bond lengths are 3.14 Å. Rh is bonded to four equivalent Gd and four equivalent Si atoms to form a mixture of distorted corner, edge, and face-sharing RhGd4Si4 tetrahedra. All Rh–Si bond lengths are 2.41 Å. Si is bonded in a 9-coordinate geometry to four equivalent Gd, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.47 Å.
EuRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Eu2+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Eu–Si bond lengths are 3.20 Å. Rh3+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing RhSi4 tetrahedra. All Rh–Si bond lengths are 2.41 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Eu2+, four equivalent Rh3+, and one Si4- atom. The Si–Si bond length is 2.62 Å.
Pu(RhSi)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Pu is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Pu–Rh bond lengths are 3.23 Å. All Pu–Si bond lengths are 3.08 Å. Rh is bonded to four equivalent Pu and four equivalent Si atoms to form a mixture of distorted corner, edge, and face-sharing RhPu4Si4 tetrahedra. All Rh–Si bond lengths are 2.41 Å. Si is bonded in a 9-coordinate geometry to four equivalent Pu, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.38 Å.
RhSi crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Rh4+ is bonded in a 6-coordinate geometry to six equivalent Si4- atoms. There are a spread of Rh–Si bond distances ranging from 2.43–2.60 Å. Si4- is bonded in a 6-coordinate geometry to six equivalent Rh4+ atoms.
TbRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Tb is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Tb–Rh bond lengths are 3.23 Å. All Tb–Si bond lengths are 3.13 Å. Rh is bonded to four equivalent Tb and four equivalent Si atoms to form a mixture of distorted edge, corner, and face-sharing RhTb4Si4 tetrahedra. All Rh–Si bond lengths are 2.41 Å. Si is bonded in a 9-coordinate geometry to four equivalent Tb, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.44 Å.
LuRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Lu is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Lu–Rh bond lengths are 3.19 Å. All Lu–Si bond lengths are 3.10 Å. Rh is bonded to four equivalent Lu and four equivalent Si atoms to form a mixture of distorted edge, face, and corner-sharing RhLu4Si4 tetrahedra. All Rh–Si bond lengths are 2.39 Å. Si is bonded in a 9-coordinate geometry to four equivalent Lu, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.38 Å.
YRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Y is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Y–Rh bond lengths are 3.23 Å. All Y–Si bond lengths are 3.13 Å. Rh is bonded to four equivalent Y and four equivalent Si atoms to form a mixture of distorted face, edge, and corner-sharing RhY4Si4 tetrahedra. All Rh–Si bond lengths are 2.41 Å. Si is bonded in a 9-coordinate geometry to four equivalent Y, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.44 Å.
NdRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Nd2+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Nd–Si bond lengths are 3.17 Å. Rh3+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing RhSi4 tetrahedra. All Rh–Si bond lengths are 2.42 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Nd2+, four equivalent Rh3+, and one Si4- atom. The Si–Si bond length is 2.54 Å.
Sm(RhSi)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Sm2+ is bonded in a distorted body-centered cubic geometry to eight equivalent Si4- atoms. All Sm–Si bond lengths are 3.15 Å. Rh3+ is bonded to four equivalent Si4- atoms to form a mixture of edge and corner-sharing RhSi4 tetrahedra. All Rh–Si bond lengths are 2.42 Å. Si4- is bonded in a 9-coordinate geometry to four equivalent Sm2+, four equivalent Rh3+, and one Si4- atom. The Si–Si bond length is 2.49 Å.
HoRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ho is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Ho–Rh bond lengths are 3.22 Å. All Ho–Si bond lengths are 3.12 Å. Rh is bonded to four equivalent Ho and four equivalent Si atoms to form a mixture of distorted face, edge, and corner-sharing RhHo4Si4 tetrahedra. All Rh–Si bond lengths are 2.40 Å. Si is bonded in a 9-coordinate geometry to four equivalent Ho, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.42 Å.
CeRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Ce is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Ce–Rh bond lengths are 3.26 Å. All Ce–Si bond lengths are 3.15 Å. Rh is bonded to four equivalent Ce and four equivalent Si atoms to form a mixture of distorted face, edge, and corner-sharing RhCe4Si4 tetrahedra. All Rh–Si bond lengths are 2.43 Å. Si is bonded in a 9-coordinate geometry to four equivalent Ce, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.47 Å.
Th(RhSi)2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Th is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Th–Rh bond lengths are 3.28 Å. All Th–Si bond lengths are 3.17 Å. Rh is bonded to four equivalent Th and four equivalent Si atoms to form a mixture of distorted corner, edge, and face-sharing RhTh4Si4 tetrahedra. All Rh–Si bond lengths are 2.44 Å. Si is bonded in a 9-coordinate geometry to four equivalent Th, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.46 Å.
PrRh2Si2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Pr is bonded in a 8-coordinate geometry to eight equivalent Rh and eight equivalent Si atoms. All Pr–Rh bond lengths are 3.29 Å. All Pr–Si bond lengths are 3.19 Å. Rh is bonded to four equivalent Pr and four equivalent Si atoms to form a mixture of distorted face, edge, and corner-sharing RhPr4Si4 tetrahedra. All Rh–Si bond lengths are 2.43 Å. Si is bonded in a 9-coordinate geometry to four equivalent Pr, four equivalent Rh, and one Si atom. The Si–Si bond length is 2.57 Å.