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8 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on SiB4 by Materials Project

SiB4 crystallizes in the trigonal R-3m space group. The structure is three-dimensional. there are two inequivalent B sites. In the first B site, B is bonded in a 1-coordinate geometry to five B and two Si atoms. There are a spread of B–B bond distances ranging from 1.75–1.86 Å. There are one shorter (2.01 Å) and one longer (2.63 Å) B–Si bond lengths. In the second B site, B is bonded in a 6-coordinate geometry to six B atoms. There is one shorter (1.85 Å) and two longer (1.92 Å) B–B bond length. There are two inequivalent Si sites. In the first Si site, Si is bonded in a 4-coordinate geometry to three equivalent B and one Si atom. The Si–Si bond length is 2.17 Å. In the second Si site, Si is bonded in a 2-coordinate geometry to six equivalent B and two equivalent Si atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Y5(SiB4)2 by Materials Project

Y5Si2B8 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. there are two inequivalent Y sites. In the first Y site, Y is bonded in a 12-coordinate geometry to nine B and three equivalent Si atoms. There are a spread of Y–B bond distances ranging from 2.64–2.97 Å. There are one shorter (3.07 Å) and two longer (3.13 Å) Y–Si bond lengths. In the second Y site, Y is bonded to two equivalent B and four equivalent Si atoms to form corner-sharing YSi4B2 octahedra. The corner-sharing octahedral tilt angles are 57°. Both Y–B bond lengths are 2.74 Å. All Y–Si bond lengths are 2.91 Å. There are three inequivalent B sites. In the first B site, B is bonded in a 9-coordinate geometry to four equivalent Y and five B atoms. There are a spread of B–B bond distances ranging from 1.76–1.83 Å. In the second B site, B is bonded in a 3-coordinate geometry to six equivalent Y and three B atoms. The B–B bond length is 1.85 Å. In the third B site, B is bonded in a 9-coordinate geometry to five Y and four equivalent B atoms. Si is bonded in a 9-coordinate geometry to eight Y and one Si atom. The Si–Si bond length is 2.35 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Dy5(SiB4)2 by Materials Project

Dy5Si2B8 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. there are two inequivalent Dy sites. In the first Dy site, Dy is bonded in a 12-coordinate geometry to nine B and three equivalent Si atoms. There are a spread of Dy–B bond distances ranging from 2.63–2.97 Å. There are one shorter (3.06 Å) and two longer (3.12 Å) Dy–Si bond lengths. In the second Dy site, Dy is bonded to two equivalent B and four equivalent Si atoms to form corner-sharing DySi4B2 octahedra. The corner-sharing octahedral tilt angles are 57°. Both Dy–B bond lengths are 2.73 Å. All Dy–Si bond lengths are 2.91 Å. There are three inequivalent B sites. In the first B site, B is bonded in a 9-coordinate geometry to four equivalent Dy and five B atoms. There are a spread of B–B bond distances ranging from 1.76–1.83 Å. In the second B site, B is bonded in a 3-coordinate geometry to six equivalent Dy and three B atoms. The B–B bond length is 1.84 Å. In the third B site, B is bonded in a 9-coordinate geometry to five Dy and four equivalent B atoms. Si is bonded in a 9-coordinate geometry to eight Dy and one Si atom. The Si–Si bond length is 2.35 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Sm5(SiB4)2 by Materials Project

Sm5Si2B8 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. there are two inequivalent Sm+2.80+ sites. In the first Sm+2.80+ site, Sm+2.80+ is bonded in a 12-coordinate geometry to nine B+0.75- and three equivalent Si4- atoms. There are a spread of Sm–B bond distances ranging from 2.70–3.03 Å. There are one shorter (3.16 Å) and two longer (3.20 Å) Sm–Si bond lengths. In the second Sm+2.80+ site, Sm+2.80+ is bonded to two equivalent B+0.75- and four equivalent Si4- atoms to form corner-sharing SmSi4B2 octahedra. The corner-sharing octahedral tilt angles are 57°. Both Sm–B bond lengths are 2.88 Å. All Sm–Si bond lengths are 2.97 Å. There are three inequivalent B+0.75- sites. In the first B+0.75- site, B+0.75- is bonded in a 9-coordinate geometry to four equivalent Sm+2.80+ and five B+0.75- atoms. There are a spread of B–B bond distances ranging from 1.79–1.84 Å. In the second B+0.75- site, B+0.75- is bonded in a 3-coordinate geometry to six equivalent Sm+2.80+ and three B+0.75- atoms. The B–B bond length is 1.89 Å. In the third B+0.75- site, B+0.75- is bonded in a 9-coordinate geometry to five Sm+2.80+ and four equivalent B+0.75- atoms. Si4- is bonded in a 9-coordinate geometry to eight Sm+2.80+ and one Si4- atom. The Si–Si bond length is 2.35 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Tb5(SiB4)2 by Materials Project

Tb5Si2B8 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional and consists of four silicon molecules and one Tb5B8 framework. In the Tb5B8 framework, there are two inequivalent Tb+3.20+ sites. In the first Tb+3.20+ site, Tb+3.20+ is bonded in a 9-coordinate geometry to nine B3- atoms. There are a spread of Tb–B bond distances ranging from 2.65–2.98 Å. In the second Tb+3.20+ site, Tb+3.20+ is bonded in a linear geometry to two equivalent B3- atoms. Both Tb–B bond lengths are 2.76 Å. There are three inequivalent B3- sites. In the first B3- site, B3- is bonded in a 9-coordinate geometry to four equivalent Tb+3.20+ and five B3- atoms. There are a spread of B–B bond distances ranging from 1.76–1.84 Å. In the second B3- site, B3- is bonded in a 3-coordinate geometry to six equivalent Tb+3.20+ and three B3- atoms. The B–B bond length is 1.85 Å. In the third B3- site, B3- is bonded in a 9-coordinate geometry to five Tb+3.20+ and four equivalent B3- atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Ho5(SiB4)2 by Materials Project

Ho5Si2B8 crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. there are two inequivalent Ho sites. In the first Ho site, Ho is bonded in a 12-coordinate geometry to nine B and three equivalent Si atoms. There are a spread of Ho–B bond distances ranging from 2.62–2.95 Å. There are one shorter (3.04 Å) and two longer (3.11 Å) Ho–Si bond lengths. In the second Ho site, Ho is bonded to two equivalent B and four equivalent Si atoms to form corner-sharing HoSi4B2 octahedra. The corner-sharing octahedral tilt angles are 57°. Both Ho–B bond lengths are 2.71 Å. All Ho–Si bond lengths are 2.89 Å. There are three inequivalent B sites. In the first B site, B is bonded in a 9-coordinate geometry to four equivalent Ho and five B atoms. There are a spread of B–B bond distances ranging from 1.75–1.83 Å. In the second B site, B is bonded in a 3-coordinate geometry to six equivalent Ho and three B atoms. The B–B bond length is 1.83 Å. In the third B site, B is bonded in a 9-coordinate geometry to five Ho and four equivalent B atoms. Si is bonded in a 9-coordinate geometry to eight Ho and one Si atom. The Si–Si bond length is 2.35 Å.

36 MATERIALS SCIENCE↗
DOE OSTI2021

A Modified Vegetation Photosynthesis and Respiration Model (VPRM) for the Eastern USA and Canada, Evaluated With Comparison to Atmospheric Observations and Other Biospheric Models

Atmospheric CO 2 measurements from a dense surface network can help to evaluate terrestrial biosphere model (TBM) simulations of Net Ecosystem Exchange (NEE) with two key benefits. First, gridded CO 2 flux estimates can be evaluated over regional scales, not possible using flux tower observations at discrete locations for model evaluation. Second, TBM ability to explain atmospheric CO 2 fluctuations due to the biosphere can be directly tested, an important objective for anthropogenic emissions monitoring using atmospheric observations. Here, we customize the Vegetation Photosynthesis and Respiration Model (VPRM) for an eastern North American domain with strong biological activity upwind of urban areas. Parameters are optimized using flux tower observations from a historical database with sites in (and near) the domain. In addition, the respiration model (originally a linear function of temperature) is modified to account for impacts of changing foliage, non-linear temperature, and water stress. Flux estimates from VPRM, the Carnegie-Ames-Stanford Approach (CASA) model and the Simple Biosphere Model v4 (SiB4), are convolved with footprints from atmospheric transport models for evaluation with CO 2 observations at 21 towers in the domain, with roughly half of the towers used here for the first time. Results show that the new respiration model in VPRM helps to correct a growing season sink bias in the atmosphere associated with underestimated summertime respiration using the original model with annual parameters. The new VPRM also better explains fine-scale atmospheric CO 2 variability compared to other TBMs, due to higher resolution diagnostic phenology, the new respiration model, domain-specific parameters, and high-quality input data sets.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Materials Data on SiB by Materials Project

BSi is Wurtzite structured and crystallizes in the hexagonal P6_3mc space group. The structure is three-dimensional. B is bonded to four equivalent Si atoms to form corner-sharing BSi4 tetrahedra. There are one shorter (1.99 Å) and three longer (2.06 Å) B–Si bond lengths. Si is bonded to four equivalent B atoms to form corner-sharing SiB4 tetrahedra.

36 MATERIALS SCIENCE↗