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Derivation of the chemical-equilibrium rate coefficient using scattering theory

Scattering theory is applied to derive the equilibrium rate coefficient for a general homogeneous chemical reaction involving ideal gases. The reaction rate is expressed in terms of the product of a number of normalized momentum distribution functions, the product of the number of molecules with a given internal energy state, and the spin-averaged T-matrix elements. An expression for momentum distribution at equilibrium for an arbitrary molecule is presented, and the number of molecules with a given internal-energy state is represented by an expression which includes the partition function.

Mickens, R. E.

Scattering theories and radar return

Scattering theories and radar return - theory of bistatic radar return from statistically rough surface and literature survey on scattering theories

SURFACE ROUGHNESS

Scatter Theories and Their Application to Lunar Radar Return

The research work being done under this NASA grant is divided into the following three categories: (1) An estimate of the radar return for the NASA Aerobee rocket shot at White Sands Missile Range. (WSMR) (2) Development of new scatter theories, modification and correlation of existing scatter theories, and application of the theories to moon-echo data for estimation of the surface features of the moon. (3) Acoustic modeling of the lunar surface and correlation of the theoretical with both full scale and acoustical experimental results.

Hayre, H. S.

Scattering theory in noncanonical phase space: A Drift-Kinetic collision operator for weakly collisional plasmas

After developing a scattering theory for grazing collisions in general noncanonical phase spaces, we introduce a guiding center collision operator in five-dimensional phase space designed for plasma regimes characterized by long wavelengths (relative to the Larmor radius), low frequencies (relative to the cyclotron frequency), and weak collisionality (where repeated Coulomb collisions induce cumulatively small changes in particle magnetic moment). The collision operator is fully determined by the noncanonical Hamiltonian structure of guiding center dynamics and exhibits a metriplectic structure, ensuring the conservation of particle number, momentum, energy, and interior Casimir invariants. It also satisfies an H-theorem, allowing for deviations from an equilibrium Maxwellian distribution due to the nontrivial kernel of the noncanonical guiding center Poisson tensor, spanned by the magnetic moment. We propose that this collision operator and its underlying mathematical structure may offer valuable insight into the study of turbulence, transport, and self-organizing phenomena in both laboratory and astrophysical plasmas.

Hamiltonian mechanics

Multiple scattering theory of radiative transfer in inhomogeneous atmospheres.

In this paper we treat the multiple scattering theory of radiative transfer in plane-parallel inhomogeneous atmospheres. The treatment presented here may be adopted to model atmospheres characterized by an optical depth dependent coherent scattering phase function. For the purpose of illustration we consider the semi-infinite medium in which the absorption property of the atmosphere is characterized by an exponential function. The methodology employed here is the extension of the case treated previously by the author for homogeneous atmospheres.

Kanal, M.

Comparisons of some scattering theories with recent scatterometer measurements

The paper compares the predictions of two different types of sea scatter theories with recent scatterometer measurements which indicate the variations of the backscattering coefficient with polarization, incident angle, wind speed, and azimuth angle. Wright's theory (1968) differs from that of Chan and Fung (1977) in two major aspects: (1) Wright uses Phillips' sea spectrum (1966) while Chan and Fung use that of Mitsuyasu and Honda, and (2) Wright uses a modified slick sea slope distribution by Cox and Munk (1954) while Chan and Fung use the slick sea slope distribution of Cox and Munk defined with respect to the plane perpendicular to the look direction. Satisfactory agreements between theory and experimental data are obtained when Chan and Fung's model is used to explain the wind and azimuthal dependence of the scattering coefficient.

Fung, A. K.

Scattering theory of frequency-entangled biphoton states facilitated by cavity polaritons

The use of quantum light to probe exciton properties in semiconductor and molecular nanostructures typically occurs in the low-intensity regime. A substantial enhancement of exciton-photon coupling can be achieved with photonic cavities, where excitons hybridize with cavity modes to form polariton states. Here, to provide a theoretical framework for interpreting emerging experimental efforts in this direction, we develop a scattering theory describing the interaction of frequency-entangled photon pairs with cavity polariton and bipolariton states under various coupling regimes. Employing the Tavis-Cummings model in combination with our scattering approach, we present a quantitative analysis of how the interaction of the entangled photon pair with the polariton or bipolariton modifies its joint spectral amplitude (JSA). Specifically, we examine the effects of the cavity-mode steady-state population, exciton-cavity coupling strength, and different forms of the input photon JSA. Our results show that the entanglement entropy of the scattered photons is highly sensitive to the interplay between the input JSA and the spectral line shapes of the polariton resonances, emphasizing the cavity filtering effects. We suggest that biphoton-scattering quantum light spectroscopy best serves as a sensitive probe of polariton and bipolariton states in the photon-vacuum cavity state. Our approach is not only robust to various regimes of cavity-exciton coupling, but also amenable to extensions beyond the Tavis-Cummings model, enabling the representation of a broad class of molecular systems and solid state quantum materials.

36 MATERIALS SCIENCE