Materials Data on ScVO2 by Materials Project
ScVO2 crystallizes in the tetragonal I4_1/amd space group. The structure is three-dimensional. Sc2+ is bonded to six equivalent O2- atoms to form edge-sharing ScO6 octahedra. All Sc–O bond lengths are 2.20 Å. V2+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All V–O bond lengths are 2.16 Å. O2- is bonded to three equivalent Sc2+ and two equivalent V2+ atoms to form a mixture of distorted edge and corner-sharing OSc3V2 trigonal bipyramids.
36 MATERIALS SCIENCE↗