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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on SbN2F5 by Materials Project

N2SbF5 crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of eight ammonia molecules and four SbF5 clusters. In each SbF5 cluster, Sb3+ is bonded in a distorted square pyramidal geometry to five F1- atoms. There is one shorter (1.87 Å) and four longer (1.90 Å) Sb–F bond length. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on SbN2F5 by Materials Project

N2SbF5 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ammonia molecules and four SbF5 clusters. In each SbF5 cluster, Sb3+ is bonded in a distorted square pyramidal geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 1.88–1.90 Å. There are five inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on SbN2F5 by Materials Project

N2SbF5 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia molecules and four SbF5 clusters. In each SbF5 cluster, Sb3+ is bonded in a distorted trigonal bipyramidal geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 1.88–1.90 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.

36 MATERIALS SCIENCE↗