Materials Data on SbH6CN3F4 by Materials Project
CN3H6SbF4 crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four guanidinium molecules and four SbF4 clusters. In each SbF4 cluster, Sb3+ is bonded in a 4-coordinate geometry to four F1- atoms. There are a spread of Sb–F bond distances ranging from 1.98–2.12 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one Sb3+ atom.
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