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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on TmSb by Materials Project

TmSb is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Tm3+ is bonded to six equivalent Sb3- atoms to form a mixture of edge and corner-sharing TmSb6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Tm–Sb bond lengths are 3.07 Å. Sb3- is bonded to six equivalent Tm3+ atoms to form a mixture of edge and corner-sharing SbTm6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on TmSb by Materials Project

TmSb is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Tm3+ is bonded in a body-centered cubic geometry to eight equivalent Sb3- atoms. All Tm–Sb bond lengths are 3.25 Å. Sb3- is bonded in a body-centered cubic geometry to eight equivalent Tm3+ atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on Tm5Sb3 by Materials Project

Tm5Sb3 crystallizes in the hexagonal P6_3/mcm space group. The structure is three-dimensional. there are two inequivalent Tm sites. In the first Tm site, Tm is bonded in a 6-coordinate geometry to six equivalent Sb atoms. All Tm–Sb bond lengths are 3.12 Å. In the second Tm site, Tm is bonded in a 5-coordinate geometry to five equivalent Sb atoms. There are a spread of Tm–Sb bond distances ranging from 3.04–3.41 Å. Sb is bonded in a 9-coordinate geometry to nine Tm atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on TmSb2 by Materials Project

TmSb2 crystallizes in the orthorhombic C222 space group. The structure is two-dimensional and consists of one TmSb2 sheet oriented in the (0, 0, 1) direction. Tm3+ is bonded in a 4-coordinate geometry to four equivalent Sb+1.50- atoms. All Tm–Sb bond lengths are 3.04 Å. Sb+1.50- is bonded in a 2-coordinate geometry to two equivalent Tm3+ atoms.

36 MATERIALS SCIENCE↗