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All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Characterization of Li in the Salton Sea Geothermal Field

Abstract The behavior of lithium during geothermal brine and host-rock interactions in the Salton Sea geothermal field is underconstrained. The lithium brine reservoir inventory is between 4 and 18 million metric tons of lithium carbonate equivalent, with an even larger amount present within the reservoir rock mineral phases. Here, we present bulk-rock and brine Li concentration and δ7Li, and in situ Li concentrations of minerals from the California State 2-14 scientific drill core and commercial wells in the Salton Sea geothermal field to identify the mineral hosts of Li and constrain Li behavior during brine-rock interactions. Lithium contents are highest in chlorite (270–580 ppm, ~2,358 m), which encases pyrite, indicating that Li is fixed from the brine into the host rocks during hydrothermal alteration. Lithium abundances in chlorite decrease with depth (70–100 ppm, ~2,882 m), as does whole-rock Li content, whereas whole-rock δ7Li increases (δ7Li = 2.0–4.3‰, ~2,485-m depth; δ7Li = 4.3–7.9‰ from ~2,819 to ~2,882 m). This change in behavior of Li at ~2,500 m suggests temperature dependent partitioning of Li in chlorite; Li becomes more incompatible in chlorite at depths >~2,500 m, corresponding to ~325°C in the reservoir. The brines have δ7Li = 3.7 to 4.7‰ and calculated isotopic fractionation factors between the brine and the host rock agree with a change in Li behavior at ~325°C. Simple closed-system batch modeling does not describe the geothermal system, suggesting open-system behavior of Li within the Salton Sea geothermal field.

Humphreys, J↗
DOE OSTI2025

Induced seismicity and geothermal energy production in the Salton Sea Geothermal Field, California

We analyze the relationship between geothermal energy production and seismic hazards in the Salton Sea Geothermal Field (SSGF) between 1972 and 2022. A clear increase in seismic activity accompanies geothermal energy production and is greatest to the east of the Brawley fault, where the amount of injection exceeds the amount of production. We estimate that, whereas there was a 2% chance of a M6.07 earthquake nucleating inside the SSGF within a fifty-year period prior to energy production (pre-production), there is an equal probability that a M6.70 earthquake nucleates there in a fifty-year period during which historically average energy production conditions persist (syn-production). Similarly, we estimate a 2% chance of a M7.15 and M6.92 occurring in the broader Brawley Seismic Zone (excluding the SSGF) within a fifty-year period during the pre- and syn-production eras, respectively. We find that linear regression models fail to reliably forecast the background seismicity rate as a function of fluid production and injection.

15 GEOTHERMAL ENERGY↗
DOE OSTI2023

SSGF Mineral Major Elements and Lithium Concentration

Presented are major element and lithium concentrations of minerals from the Salton Sea Geothermal Field (SSGF), located in the Imperial Valley, California. With a recent increase in demand for lithium, the area is now being studied as a source of geothermal brine for lithium extraction. This study was performed to help quantify lithium storage in the SSGF brine and surrounding minerals. Rocks and brines sampled in this study are from surface rhyolitic domes on the South Eastern shore of the Salton Sea, the sedimentary and evaporitic rocks in the Durmid Hills, rhyolitic drill clippings previously studied by Schmitt & Hulen, commercial drill wells, and CA State 2-14 well.

15 GEOTHERMAL ENERGY↗
DOE OSTI2021

Technology for the Recovery of Lithium from Geothermal Brines

Lithium is the principal component of high-energy-density batteries and is a critical material necessary for the economy and security of the United States. Brines from geothermal power production have been identified as a potential domestic source of lithium; however, lithium-rich geothermal brines are characterized by complex chemistry, high salinity, and high temperatures, which pose unique challenges for economic lithium extraction. The purpose of this paper is to examine and analyze direct lithium extraction technology in the context of developing sustainable lithium production from geothermal brines. In this paper, we are focused on the challenges of applying direct lithium extraction technology to geothermal brines; however, applications to other brines (such as coproduced brines from oil wells) are considered. The most technologically advanced approach for direct lithium extraction from geothermal brines is adsorption of lithium using inorganic sorbents. Other separation processes include extraction using solvents, sorption on organic resin and polymer materials, chemical precipitation, and membrane-dependent processes. The Salton Sea geothermal field in California has been identified as the most significant lithium brine resource in the US and past and present efforts to extract lithium and other minerals from Salton Sea brines were evaluated. Extraction of lithium with inorganic molecular sieve ion-exchange sorbents appears to offer the most immediate pathway for the development of economic lithium extraction and recovery from Salton Sea brines. Other promising technologies are still in early development, but may one day offer a second generation of methods for direct, selective lithium extraction. Initial studies have demonstrated that lithium extraction and recovery from geothermal brines are technically feasible, but challenges still remain in developing an economically and environmentally sustainable process at scale.

58 GEOSCIENCES↗
DOE OSTI2021

Salton Sea Geodatabase for Geothermal Exploration Artificial Intelligence

These files contain the geodatabases related to Salton Sea Geothermal Field. It includes all input and output files used with the Geothermal Exploration Artificial Intelligence. Input and output files are sorted into three categories: raw data, pre-processed data, and analysis (post-processed data). In each of these categories there are six additional types of raster catalogs which are titled Radar, SWIR, Thermal, Geophysics, Geology, and Wells. The files are used with the Geothermal Exploration Artificial Intelligence for the Salton Sea Geothermal Site to identify indicators of blind geothermal systems. The included zip file is a geodatabase to be used with ArcGIS and the tar file is an inclusive database that encompasses the inputs and outputs for the Salton Sea Geothermal Site.

15 GEOTHERMAL ENERGY↗
DOE OSTI2023

Using Dark Fiber and Distributed Acoustic Sensing to Characterize a Geothermal System in the Imperial Valley, Southern California

The Imperial Valley, CA, is a tectonically active transtensional basin located south of the Salton Sea; the area hosts numerous geothermal fields, including significant hidden hydrothermal resources without surface manifestations. Development of inexpensive, rugged, and highly sensitive exploration techniques for undiscovered geothermal systems is critical for accelerating geothermal power deployment as well as unlocking a low-carbon energy future. We present a case study utilizing distributed acoustic sensing (DAS) and ambient noise interferometry for geothermal reservoir imaging, utilizing unlit fiber-optic telecommunication infrastructure (dark fiber). The study exploits two days of passive DAS data acquired in early November 2020 over a ~28-km section of fiber from Calipatria, CA to Imperial, CA. We apply ambient noise interferometry to retrieve coherent signals from DAS records and develop a bin stacking technique to attenuate the effects from persistent localized noise sources and to enhance retrieval of coherent surface waves. As a result, we are able to obtain high-resolution two-dimensional (2D) S wave velocity ($V_s$) structure to 3 km depth, based on joint inversion of both the fundamental and higher overtones. We observe a previously unmapped high $V_s$ and low $V_p$/$V_s$ ratio feature beneath the Brawley geothermal system, which we interpret to be a zone of hydrothermal mineralization and lower porosity. This interpretation is consistent with a host of other measurements including surface heat flow, gravity anomalies, and available borehole wireline data. These results demonstrate the potential utility of DAS deployed on dark fiber for geothermal system exploration and characterization in the appropriate geological settings.

Vp/Vs imaging↗
DOE OSTI2023

Environmental Impact Assessment of Lithium Recovery from Geothermal Brines in the SS-KGRA: An Overview

There is increasing interest in securing a reliable, domestic source of lithium in the United States to support an electrified grid and energy secure future. The Salton Sea Known Geothermal Resource Area (SS-KGRA) has garnered attention for this purpose due to the abundance of lithium in brines brought to the surface for geothermal energy production in this region. Geothermal production from this field is already expected to grow from the current 400 MWe to 920 MWe in the next 3-4 years with a potential total geothermal capacity in the region estimated at nearly 2,950 MWe. With this growth, there is potential for construction and operation of new direct lithium recovery and processing facilities to meet domestic demands for lithium. In this work, we estimate the potential impact of geothermal expansion and lithium extraction in the SS-KGRA on water use, direct air emissions from facilities, and solid waste production and management.

Busse, MM↗