C sub 2 swan bands in comets.
Relative populations of vibrational levels of carbon Swan bands in comets excited by resonance fluorescence
SWAN BAND↗
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On the absence of the /0, 0/ C sub 2 Swan band from sunspot spectra - Research note
Diatomic carbon swan band violet line absence from sunspot suggested in accordance with molecular equilibrium predictions
Branch, D.↗
Study of the isotopic features of Swan bands in comets
It is shown from a detailed statistical equilibrium calculation of the (C-12)(C-13) molecule that the interpretation of the observed intensities of Swan bands of the normal and the isotopic molecule of C2 in terms of the abundance ratio of C-12 and C-13 is a reasonable one. The synthetic profile of some isotopic features in the (0.0) Swan band is compared with the observed profiles for comet West.
Krishna Swamy, K. S.↗
C2 Swan bands in comets
Relative population calculation of vibration levels of electronic levels assuming fluorescence mechanism for carbon-carbon bond Swan bands in comets
SWAN BAND↗
A theoretical study of the electronic transition moment for the C2 Swan band system
Large-scale self-consistent-field plus configuration-interaction calculations have been performed for the a 3Pi u and d 3Pi g states of C2. The theoretical potential curves are in good agreement with those found by a Klein-Dunham analysis of measured molecular constants in terms of shape and excitation energy. The sum of the squares of the theoretical transition moments between the states at 2.44 bohr is 4.12 a.u. which agrees with the results of shock tube measurements. The variation in the sum of the squares of the theoretical moments with internuclear separation agrees with the values of Danylewych and Nicholls (1974). Based on the data for C2 and mother molecules, it is suggested that CI calculations using near Hartree-Fock quality Slater basis sets produce highly reliable transition moments.
Arnold, J. O.↗
Statistical equilibrium in cometary C2. I
Swan-band emission from the C2 molecule provides important information for a study of the physical processes occurring in comets. It is, therefore, a disturbing factor that many quantitative Swan-band observations are in clear contradiction of predictions of resonance fluorescence excitation of the Swan bands. A description is presented of an investigation involving an application of resonance fluorescence theory to C2. The investigation takes into account all important electronic transitions which determine the population distribution of the lowest energy states. It is found that the previous discrepancy for the brighter band sequences disappears.
Swamy, K. S. K.↗
On the nature of spectral features in peculiar DQ white dwarfs
Spectropolarimetric measurements are presented for the DQ white dwarfs ESO 439-162, LHS 1126, and G225-68, whose spectroscopic features in the optical have been interpreted in the past as pressure-shifted or magnetically shifted C2 Swan bands. The results convincingly demonstrate that none of these objects is strongly magnetic, with upper limits of 30, 3, and 2 MG respectively. Since Bergeron et al. (B 94) have recently ruled out the pressure-shift interpretation for LHS 1126 as well, we discuss alternative physical mechanisms for displacing the Swan bands. Although possibilities for explaining the observed shifts may exist, a comparison of the optical spectra (and that of a similar DQ star, LP 77-57) indicates that the locations and shapes of the profiles in all four objects are virtually identical. This last result suggests instead that a different molecular species could be responsible. A detailed chemical equilibrium analysis of H/He/C mixtures under the physical conditions encountered in the atmospheres of these peculiar objects reveals that C2H is a molecule preferentially formed in the photospheric regions. The nature and evolution of these objects are discussed.
Schmidt, Gary D.↗
High precision low resolution spectrophotometry of Comets Giacobini-Zinner and Halley
Optical window (300 to 1000 nm) observations were made of Comet Halley during 12 to 14 Mar. 1986 by a scanning spectrometer. The results provide accurate spectrophotometric measurements of the principal molecular bands from the 308 nm OH through the 918 nm CN emissions. The observations can be used to tie space derived ultraviolet and groundbased infrared observations to the optical observations and to one another. Additional observations were made of comet Giacobini-Zinner on 30 September 1985 of the same OH band and the 388 nm band of CN. The Swan band sequence ratios are used to test the best models of C2, with different ratios favoring different models, calling into question the assumptions of these very complete models.
Odell, C. R.↗
Origin of the c /a super 3 iig/ goes to c sub 2 /x super 3 iiu/ emission in comets.
Origin of diatomic carbon Swan bands in cometary emissions due to hydrocarbon photodissociation
CARBON↗
The spectral development of Comet P/Halley from August 1985 to June 1986
Spectra of comet Halley were obtained every month from 1985 Aug. to 1986 June, from 5200 to 10,400 A at a spectral resolution of 12 A. Spatial extent is 200" along the slit. A variety of spatially resolved spectra with the slit along the tail and perpendicular to the tail were recorded. Emission species observed are C2, CN, NH2, H2O(+), (OI) and NaI. The 2-0 C2 Phillips band is detected at 8750 A, and from its intensity ratio of 1/9 to the 0-1 Swan band a preliminary C2 singlet to triplet intercombination probability of less than 10 to the minus 7th power is derived. Sodium emission is observed stongly only in 1986 Mar. data.
Fink, Uwe↗
Spectrophotometry of Comet Kohoutek /1973f = 1973XII/
Spectrum scans have been obtained of Comet Kohoutek with a Fourier spectrometer at heliocentric distances from 0.55 to 1.05 AU. The useful spectral range is roughly 3800-8400 A and the resolution is about 10-15 A at 5000 A. Large variations occurred in the gas-to-dust ratio (pre- versus postperihelion) and in the relative strength of the NH2 bands (with heliocentric distance). There is a smaller change in the ratio of CN to C2 emission. The Swan bands of C2 show the customary anomaly in strengths implying highly non-Boltzmann distributions among vibrational levels. The red and violet CN system fluxes are in slightly better agreement with laboratory data on oscillator strengths than results on previous comets. Other species measured include Na, (O I), CH, and C3.
Ahearn, M. F.↗
Statistical equilibrium in cometary C2. II - Swan/Phillips band ratios
Statistical equilibrium calculations have been made for both the triplet and ground state singlets for C2 in comets, using the exchange rate as a free parameter. The predictions of the results are consistent with optical observations and may be tested definitively by accurate observations of the Phillips and Swan band ratios. Comparison with the one reported observation indicates compatibility with a low exchange rate and resonance fluorescence statistical equilibrium.
Swamy, K. S. K.↗
Spectrophotometry of comets 1967n, 1968b, and 1968c
Ikeya-Seki /1967n/, Thomas /1968b/ and Honda /1968c/ comet photoelectric spectrum, examining swan bands, continuum and reflected scattered light
Gebel, W. L.↗
Spectrophotometry of comet Kohoutek (1973f) during pre-perihelion period
Scans of the head of comet Kohoutek obtained during the pre-perihelion period with a photoelectric spectrum scanner are discussed. The mean relative flux distributions and the continuum energy distribution of the head of comet Kohoutek are given and normalized to 479 nm. The emission features of CN, C3, Ch, and the principal Swan band sequences of C2 and Na are identified and discussed. The adopted monochromatic values relative to 479 nm are given and plotted along with the energy distribution of the sun.
Babu, G. S. D.↗
Synthetic spectra of C2 in comets
With the key result of Krishna Swamy and O'Dell (1977), a complete fluorescence equilibrium calculation has been used to predict the detailed Swan-band spectrum in comets. A rotational Boltzmann temperature of approximately 3000 K and small changes in published molecular constants lead to a theoretical spectrum in excellent agreement with that observed. The Fox-Herzberg bands are predicted to be quite weak compared with previously observed ultraviolet features in cometary spectra. The Ballik-Ramsay bands should be observable in the near-infrared.
Ahearn, M. F.↗
The detection of the 5577.3 A forbidden line of O I in comets
The spectral synthesis of C2 Swan band sequence Delta V = -1 indicates the intensity of the forbidden green oxygen line of 5577.3 A to be about 3 to 5 percent of the 6300 A line. Therefore, it appears that the green line should be observable in high-resolution spectra of a bright comet. Festou and Feldman suggest red/green greater than or equal to 10 means a water parent origin.
Krishna Swamy, K. S.↗
C2 imagery of the inner coma of Comet IRAS-Araki-Alcock
May 10, 1983 observations of the comet IRAS-Araki-Alcock are analyzed to determine the spatial molecular abundance of C2 in the inner coma, via the Delta-v = +1 Swan band sequence near 4690 A. The observations indicate a deficiency of C2 emission across a projected diameter of about 2000 km that is centered on the peak of continuum emission. Comet imagery indicates a sunward-pointing coma that suggests an outburst of subsurface volatile ices through a nonvolatile surface crust, as predicted for periodic comets. These results are discussed in the framework of instrumental and observational constraints.
Oliversen, R. J.↗
Spectroscopic observations of cool degenerate star candidates
Spectroscopic observations are reported for 23 Luyten Half-Second degenerate star candidates and for 13 Luyten-Palomar common proper-motion pairs containing possible degenerate star components. Twenty-five degenerate stars are identified, 20 of which lack previous spectroscopy. Most of these stars are cool - Luyten color class g or later. One star, LP 77-57, shows broad continuum depressions similar to those in LHS 1126, which Liebert and Dahn attributed to pressure-shifted C2. A second degenerate star, LHS 290, exhibits apparent strong Swan bands which are blueshifted about 75 A. Further observations, including polarimetry and photometry, are required to appraise the spectroscopic peculiarities of these stars. Finally, five cool, sharp-lined DA white dwarfs have been observed to detect lines of metals and to determine line strengths. None of these DAs show signs of Mg b or the G band, and four show no evidence of Ca II K. The attempt to detect Ca MI in the fifth star, G199-71, was inconclusive.
Hintzen, P.↗