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At least 19 records

Transport–Friendly Microstructure in SSC–MEA: Unveiling the SSC Ionomer–Based Membrane Electrode Assemblies for Enhanced Fuel Cell Performance

The significant role of the cathodic binder in modulating mass transport within the catalyst layer (CL) of fuel cells is essential for optimizing cell performance. This investigation focuses on enhancing the membrane electrode assembly (MEA) through the utilization of a short-side-chain perfluoro-sulfonic acid (SSC-PFSA) ionomer as the cathode binder, referred to as SSC-MEA. This study meticulously visualizes the distinctive interpenetrating networks of ionomers and catalysts, and explicitly clarifies the triple-phase interface, unveiling the transport-friendly microstructure and transport mechanisms inherent in SSC-MEA. The SSC-MEA exhibits advantageous microstructural features, including a better-connected ionomer network and well-organized hierarchical porous structure, culminating in superior mass transfer properties. Relative to the MEA bonded by long-side-chain perfluoro-sulfonic acid (LSC-PFSA) ionomer, noted as LSC-MEA, SSC-MEA exhibits a notable peak power density (1.23 W cm –2 ), efficient O 2 transport, and remarkable proton conductivity (65% improvement) at 65 °C and 70% relativity humidity (RH). These findings establish crucial insights into the intricate morphology-transport-performance relationship in the CL, thereby providing strategic guidance for developing highly efficient MEA.

25 ENERGY STORAGE↗

Evidence that Surface-Segregated Sr Phases Can Be Removed in LSCF via Ceria Pre-Infiltration, Are Less Apt to Form in SSC

Here Ce 0.9 Gd 0.1 O 1.95−x (GDC) pre-infiltration was performed on 12 vol.% La 0.6 Sr 0.4 Co 0.8 Fe 0.2 O 3−x (LSCF) or Sm 0.5 Sr 0.5 CoO 3−x (SSC) infiltrated GDC Solid Oxide Fuel Cell cathodes. The addition of 7.5 vol.% of ∼40 nm diameter GDC nanoparticles into a ∼30 μ m thick porous scaffold of partially-sintered, sub-micron GDC particles before LSCF infiltration 1) lowered the temperature needed to produce a LSCF-GDC polarization resistance ( R P ) of 0.1 Ohm*cm 2 by ∼50 °C, and 2) reduced the amount of 500 h, 650 °C open-circuit LSCF-GDC R P degradation from ∼37% to ∼6%. In contrast, GDC pre-infiltration had no effect on the initial SSC-GDC R P or the 19% in R P degradation observed during 500 h of 650 °C open-circuit aging. X-Ray Photoelectron Spectroscopy showed that GDC pre-infiltration lowered the concentration of strontium species on the surface of the initial and 650 °C-aged LSCF-GDC, but had no effect on the initial or aged SSC-GDC Sr concentrations. Similarly, Electrochemical Impedance Spectroscopy showed that for both the initial and aged LSCF-GDC, GDC pre-infiltration improved oxygen exchange at the infiltrate-backbone and infiltrate-gas interfaces, but had no effect on the SSC-GDC. Hence, GDC pre-infiltration was concluded to improve LSCF-GDC performance and durability by scavenging exsolved Sr-rich secondary phases that form on the interfaces of LSCF, but not SSC.

36 MATERIALS SCIENCE↗

Central and Eastern United States (CEUS) Seismic Source Characterization (SSC) for Nuclear Facilities Project

This report describes a new seismic source characterization (SSC) model for the Central and Eastern United States (CEUS). It will replace the Seismic Hazard Methodology for the Central and Eastern United States, EPRI Report NP-4726 (July 1986) and the Seismic Hazard Characterization of 69 Nuclear Plant Sites East of the Rocky Mountains, Lawrence Livermore National Laboratory Model, (Bernreuter et al., 1989). The objective of the CEUS SSC Project is to develop a new seismic source model for the CEUS using a Senior Seismic Hazard Analysis Committee (SSHAC) Level 3 assessment process. The goal of the SSHAC process is to represent the center, body, and range of technically defensible interpretations of the available data, models, and methods. Input to a probabilistic seismic hazard analysis (PSHA) consists of both seismic source characterization and ground motion characterization. These two components are used to calculate probabilistic hazard results (or seismic hazard curves) at a particular site. This report provides a new seismic source model.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Supercritical/Solid Catalyst (SSC)

INL's patented, continuous-flow Supercritical/Solid Catalyst (SSC) produces the highest ASTM-quality B-100 biodiesel from waste fats, oils, and greases at the site of waste generation. SSC delivers low-cost transportation fuel, avoids significant landfill costs for municipalities, and reduces potent methane and other emissions produced in landfills from these wastes. You can learn more about INL's energy research programs at http://www.facebook.com/idahonationallaboratory.

09 BIOMASS FUELS↗

Suzaku X-ray observations of the Fermi Bubbles: Northernmost cap and southeast claw discovered with maxi-SSC

We report on Suzaku observations of large-scale X-ray structures possibly related to the Fermi Bubbles obtained in 2013 with a total duration of ≃80 ks. The observed regions were (1) the northern cap (N-cap; l ∼ 0°, 45°<b< 55°) seen in the mid-band (1.7–4.0 keV) map recently provided by Monitor of All-sky X-ray Image Solid-state Slit Camera (MAXI-SSC) and (2) the southeast claw (SE-claw; l ∼ 10°, −20{sup ∘}<b<−10{sup ∘}) seen in the ROSAT all-sky map and MAXI-SSC low-band (0.7–1.7 keV) map. In each region, we detected diffuse X-ray emission, which is represented by a three-component plasma model consisting of an unabsorbed thermal component (kT ≃ 0.1 keV) from the Local Hot Bubble, absorbed kT = 0.30 ± 0.05 keV emission representing the Galactic halo (GH), and a power-law component due to the isotropic cosmic X-ray background radiation. The emission measure of the GH component in the SE-claw shows an excess by a factor of ≃2.5 over the surrounding emission at 2° away. We also found a broad excess in the 1.7–4.0 keV count rates across the N-cap after compiling other archival data from Suzaku and Swift. The spectral stacking analysis of the N-cap data indicates the presence of another thermal component with kT = 0.70{sub −0.11}{sup +0.22}keV. The temperature kT ≃ 0.3 keV of the GH is higher than the ubiquitous value of kT ≃ 0.2 keV near the Fermi bubbles, and can be even higher (∼0.7 keV). We discuss our findings in the context of the bubble–halo interaction.

79 ASTRONOMY AND ASTROPHYSICS↗

SSC: A Tool for Constructing Libraries for Systematic Screening of Conformers

Even a relatively small molecule with 10–20 atoms might have a few local minima, which correspond to different conformers. The number of local minima quickly increases with molecular size and the most common algorithms, driven by calculated forces, frequently identify a minimum, which is closest to the initial structure, rather than the most stable conformer. Here we discuss how to perform a systematic search of the conformational space for a chain-like molecule. Our approach is fully automated and a user has control which chemical bonds will be probed and with which increments. Moreover, whole fragments of the molecule, which are adjacent to each selected rotational bond, are rotated in a properly selected cylindrical coordinate system and unchemical hybridizations and some ‘‘clashes’’ between neighboring groups, which are common when standard Z-matrices are used, are avoided. A library of potentially relevant conformers is created with a tool, which we call SSC, denoting Systematic Screening of Conformers. Each member of the library is prescreened at a predefined level of theory and the most promising conformers are identified. Finally, they are further evaluated at a higher level of theory to identify the most stable structures and their physicochemical properties. As an example, we demonstrate the results of this approach for 2'-deoxycytidine.

43 PARTICLE ACCELERATORS↗

Design and Evaluation of joint resistance in SSC Rutherford type cable splices for Torus magnet for the Jefferson Lab 12 GeV Upgrade

The Hall B 3.6-T superconducting torus magnet is being designed and built as part of the Jefferson Lab 12-GeV upgrade. The magnet consists of six trapezoidal coils connected in series, with an operating current of 3770 A. The magnet and the joints (or splices) connecting the coils are all conduction cooled by supercritical 4.6-K helium. This paper studies the design and manufacturing process of the splices made between two SSC Rutherford-type cables and discusses the tests performed to evaluate the performance of the splices under varying incident magnetic fields.

Ghoshal, Probir K.↗

X-ray plateaus in the context of the one-zone SSC model for GRB afterglows

We investigate the impact that the upper cutoff of the electron distribution has on the multiwavelength GRB afterglow spectra and on the corresponding X-ray light curves. We show under which conditions X-ray light curves with a plateau phase can be produced in this picture.

79 ASTRONOMY AND ASTROPHYSICS↗

A NUMERICAL MODEL OF PARSEC-SCALE SSC MORPHOLOGIES AND THEIR RADIO EMISSION

In current models for jets of active galactic nuclei and their emission a shortcoming in the description and understanding of the connection between the largest and smallest scales exists. In this work we present a spatially resolved synchrotron self-Compton model extended to parsec scales, which opens the possibility of probing the connections between the radio and high-energy properties. We simulate an environment that leads to Fermi-I acceleration of leptonic particles and includes the full time dependence of this process. Omitting the restriction of a finite downstream region, we find that the spectral energy distribution produced by the accelerated particles strongly depends on their radial confinement behind the shock. The requirement, for both the restriction of high-energy emission to a small region around the shock and the production of a flat radio spectrum, is an initial linear increase of the radius immediately behind the shock, which then slows down with increasing distance from the shock. A good representation of the data for the blazar Mrk 501 is achieved by a parameterized log function. The prediction for the shape of the radio blob is given by the flux distribution with respect to shock distance.

79 ASTRONOMY AND ASTROPHYSICS↗