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Results for “SPECTRAL RESPONSE”
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Hybrid quantum dot-tin disulfide field-effect transistors with improved photocurrent and spectral responsivity
We report an improved photosensitivity in few-layer tin disulfide (SnS 2 ) field-effect transistors(FETs) following doping with CdSe/ZnS core/shell quantum dots(QDs). The hybrid QD-SnS 2 FET devices achieve more than 500% increase in the photocurrent response compared with the starting SnS 2 -only FET device and a spectral responsivity reaching over 650 A/W at 400 nm wavelength. The negligible electrical conductance in a control QD-only FET device suggests that the energy transfer between QDs and SnS 2 is the main mechanism responsible for the sensitization effect, which is consistent with the strong spectral overlap between QDphotoluminescence and SnS 2 optical absorption as well as the large nominal donor-acceptor interspacing between QD core and SnS 2 . Furthermore, we also find enhanced charge carrier mobility in hybrid QD-SnS 2 FETs which we attribute to a reduced contact Schottky barrier width due to an elevated background charge carrier density.
Planck 2013 results. IX. HFI spectral response
The Planck High Frequency Instrument (HFI) spectral response was determined through a series of ground based tests conducted with the HFI focal plane in a cryogenic environment prior to launch. The main goal of the spectral transmission tests was to measure the relative spectral response (includingthe level of out-of-band signal rejection) of all HFI detectors to a known source of electromagnetic radiation individually. This was determined by measuring the interferometric output of a continuously scanned Fourier transform spectrometer with all HFI detectors. As there is no on-board spectrometer within HFI, the ground-based spectral response experiments provide the definitive data set for the relative spectral calibration of the HFI. Knowledge of the relative variations in the spectral response between HFI detectors allows for a more thorough analysis of the HFI data. The spectral response of the HFI is used in Planck data analysis and component separation, this includes extraction of CO emission observed within Planck bands, dust emission, Sunyaev-Zeldovich sources, and intensity to polarization leakage. The HFI spectral response data have also been used to provide unit conversion and colour correction analysis tools. While previous papers describe the pre-flight experiments conducted on the Planck HFI, this paper focusses on the analysis of the pre-flight spectral response measurements and the derivation of data products, e.g. band-average spectra, unit conversion coefficients, and colour correction coefficients, all with related uncertainties. Verifications of the HFI spectral response data are provided through comparisons with photometric HFI flight data. This validation includes use of HFI zodiacal emission observations to demonstrate out-of-band spectral signal rejection better than 10 8 . The accuracy of the HFI relative spectral response data is verified through comparison with complementary flight-data based unit conversion coefficients and colour correction coefficients. Furthermore, these coefficients include those based upon HFI observations of CO, dust, and Sunyaev-Zeldovich emission. General agreement is observed between the ground-based spectral characterization of HFI and corresponding in-flight observations, within the quoted uncertainty of each; explanations are provided for any discrepancies.
Broad spectral response photodetector based on individual tin-doped CdS nanowire
High purity and tin-doped 1D CdS micro/nano-structures were synthesized by a convenient thermal evaporation method. SEM, EDS, XRD and TEM were used to examine the morphology, composition, phase structure and crystallinity of as-prepared samples. Raman spectrum was used to confirm tin doped into CdS effectively. The effect of impurity on the photoresponse properties of photodetectors made from these as-prepared pure and tin-doped CdS micro/nano-structures under excitation of light with different wavelength was investigated. Various photoconductive parameters such as responsivity, external quantum efficiency, response time and stability were analyzed to evaluate the advantage of doped nanowires and the feasibility for photodetector application. Comparison with pure CdS nanobelt, the tin-doped CdS nanowires response to broader spectral range while keep the excellect photoconductive parameters. Both trapped state induced by tin impurity and optical whispering gallery mode microcavity effect in the doped CdS nanowires contribute to the broader spectral response. The micro-photoluminescence was used to confirm the whispering gallery mode effect and deep trapped state in the doped CdS nanowires.
Distribution of the Spectral Response of Cells in Silicon Modules - Mechanisms and Implications
Measurements of the spectral response of cells in a PV module can provide important insight into the physics of the device and are also needed for the accurate calibration of the performance of these devices using solar simulators. While techniques for measuring the spectral response of PV cells are well established, measurement of the spectral response of all cells in a module is not straightforward since in this case one has electrical access to a string of cells and not to cells individually. Here we present a new approach for testing the spectral response of individual cells in silicon modules that allows for the fast mapping of the response at different locations of the module. We show that in some cases the spectral response of different cells in a module can vary considerably and propose an underlying mechanism for this variation. We also discuss the implications of this observation for the uncertainty of the spectral correction and of the I SC calibration using a solar simulator.
High dynamic range measurement of spectral responsivity and linearity of a radiation thermometer using a super-continuum laser and LEDs
To realize the temperature scale above the freezing point of silver according to the definition of ITS-90, the dynamic range of the spectral responsivity is one of the most important factors which limit its uncertainty. When the residual spectral response at both side bands of a spectral band is not negligible, a significant uncertainty can be caused by a low dynamic range of the spectral responsivity measurement. In general, incandescent lamps are used to measure the spectral responsivity and the linearity. The dynamic range of the spectral responsivity measurement is often limited by a trade-off with the desired spectral resolution, which is less than 6 decades. Nonlinearity is another limiting fact of uncertainties of the temperature scale. Tungsten lamps have disadvantage in the nonlinearity measurements in terms of adjustability of radiance level and spectral selectivity. We report spectral responsivity measurements of which the measurable dynamic range is enhanced 50 times after replacing a QTH lamp with a super continuum laser. We also present a spectrally selected linearity measurement over a wide dynamic range using high-brightness light emitting diode arrays to observe a slight saturation of linearity.
Analysis of bias voltage dependent spectral response in Ga{sub 0.51}In{sub 0.49}P/Ga{sub 0.99}In{sub 0.01}As/Ge triple junction solar cell
Spectral response measurement plays great role in characterizing solar cell device because it directly reflects the efficiency by which the device converts the sunlight into an electrical current. Based on the spectral response results, the short circuit current of each subcell can be quantitatively determined. Although spectral response dependence on wavelength, i.e., the well-known external quantum efficiency (EQE), has been widely used in characterizing multijunction solar cell and has been well interpreted, detailed analysis of spectral response dependence on bias voltage (SR −V{sub bias}) has not been reported so far. In this work, we have performed experimental and numerical studies on the SR −V{sub bias} for Ga{sub 0.51}In{sub 0.49}P/Ga{sub 0.99}In{sub 0.01}As/Ge triple junction solar cell. Phenomenological description was given to clarify the mechanism of operation matching point variation in SR −V{sub bias} measurements. The profile of SR−V{sub bias} curve was explained in detail by solving the coupled two-diode current-voltage characteristic transcend formula for each subcell.
PV module spectral response measurements - Data and Resources
"This dataset includes spectral response curves for 12 commercial silicon module types that are deployed at SNL in Albuquerque. The modules chosen for evaluation were originally purchased by SNL for the PV Lifetime project (renamed to Systems Long-Term Evaluation [SLTE]). The majority of those modules are deployed outdoors for long-term evaluation, but several modules of each type were placed in storage for future comparison purposes. One stored module of each type was sent to NREL for the spectral response measurements. NREL used the recently developed Module Quantum Efficiency (QE) test bed. What makes this system unique is that it scans the entire module automatically, taking one or more measurements on each cell. Using the mean of these measurements at each wavelength leads to improvements in spectral mismatch correction and module power measurements but having the individual measurements also makes it possible to identify outlier cells, which could be useful for investigating underperforming modules. All measurements were performed nominally at 25°C"
THE IMPACT OF THE SPECTRAL RESPONSE OF AN ACHROMATIC HALF-WAVE PLATE ON THE MEASUREMENT OF THE COSMIC MICROWAVE BACKGROUND POLARIZATION
We study the impact of the spectral dependence of the linear polarization rotation induced by an achromatic half-wave plate on measurements of cosmic microwave background polarization in the presence of astrophysical foregrounds. We focus on the systematic effects induced on the measurement of inflationary gravitational waves by uncertainties in the polarization and spectral index of Galactic dust. We find that for the experimental configuration and noise levels of the balloon-borne EBEX experiment, which has three frequency bands centered at 150, 250, and 410 GHz, a crude dust subtraction process mitigates systematic effects to below detectable levels for 10% polarized dust and tensor-to-scalar ratio of as low as r = 0.01. We also study the impact of uncertainties in the spectral response of the instrument. With a top-hat model of the spectral response for each band, characterized by band center and bandwidth, and with the same crude dust subtraction process, we find that these parameters need to be determined to within 1 and 0.8 GHz at 150 GHz; 9 and 2.0 GHz at 250 GHz; and 20 and 14 GHz at 410 GHz, respectively. The approach presented in this paper is applicable to other optical elements that exhibit polarization rotation as a function of frequency.
Global horizontal spectral irradiance and module spectral response measurements: an open dataset for PV research
This report describes the creation process and final content of a spectral irradiance dataset for Albuquerque, New Mexico accompanied by a set of spectral response measurements for modules deployed at the same location. The spectral irradiance measurements were made using horizontally mounted spectroradiometers; therefore, they represent global horizontal irradiance. The dataset combines non-continuous spectroradiometer and weather measurements from a two-year period into a single calendar year. The data files are accompanied by extensive metadata as well as example calculations and graphs to demonstrate the potential uses of this database. The spectral response measurements were carried out by the National Renewable Energy Laboratory using 12 commercial silicon modules types that are undergoing long-term evaluation at Sandia National Laboratories in Albuquerque.
Enhancing mid-infrared spectral response at the LaAlO{sub 3}/SrTiO{sub 3} interface by magnetic field
Many unexpected properties have been found in the LaAlO{sub 3}/SrTiO{sub 3} heterostructure, but the interaction of the many ground states at its interface remains unclear. Here, we demonstrate an optical property of this n-type heterostructure where the mid-infrared spectral responsivity at the interface is enhanced by an external magnetic field. The field intensity ranged from 0.8 to 6 kOe at a low temperature (19 K) as measured with our spectral response measurement system. Two spectral peaks related to the spin-orbit coupling effect were also observed at wavelengths 2400 nm and 3700 nm. The intriguing phenomena relate to changes in the crystallographic structure and subband structure at the interface.
Simulation and analysis of grating-integrated quantum dot infrared detectors for spectral response control and performance enhancement
We propose and analyze a novel detector structure for pixel-level multispectral infrared imaging. More specifically, we investigate the device performance of a grating-integrated quantum dots-in-a-well photodetector under backside illumination. Our design uses 1-dimensional grating patterns fabricated directly on a semiconductor contact layer and, thus, adds a minimal amount of additional effort to conventional detector fabrication flows. We show that we can gain wide-range control of spectral response as well as large overall detection enhancement by adjusting grating parameters. For small grating periods, the spectral responsivity gradually changes with parameters. We explain this spectral tuning using the Fabry–Perot resonance and effective medium theory. For larger grating periods, the responsivity spectra get complicated due to increased diffraction into the active region, but we find that we can obtain large enhancement of the overall detector performance. In our design, the spectral tuning range can be larger than 1 μm, and, compared to the unpatterned detector, the detection enhancement can be greater than 92% and 148% for parallel and perpendicular polarizations. Our work can pave the way for practical, easy-to-fabricate detectors, which are highly useful for many infrared imaging applications.
Diagnosing x-ray power and energy of tungsten wire array z-pinch with a flat spectral response x-ray diode
Fast z-pinch is a very efficient way of converting electromagnetic energy to radiation. With an 8-10 MA current on primary test stand facility, about 1 MJ electromagnetic energy is delivered to vacuum chamber, which heats z-pinch plasma to radiate soft x-ray. To develop a pulsed high power x-ray source, we studied the applicability of diagnosing x-ray power from tungsten wire array z-pinch with a flat spectral response x-ray diode (FSR-XRD). The detector was originally developed to diagnose radiation of a hohlraum in SG-III prototype laser facility. It utilized a gold cathode XRD and a specially configured compound gold filter to yield a nearly flat spectral response in photon energy range of 0.1-4 keV. In practice, it was critical to avoid surface contamination of gold cathode. It is illustrated that an exposure of an XRD to multiple shots caused a significant change of response. Thus, in diagnosing x-ray power and energy, we used each XRD in only one shot after calibration. In a shot serial, output of FSR-XRD was compared with output of a nickel bolometer. In these shots, the outputs agreed with each other within their uncertainties which were about 12% for FSR-XRD and about 15% for bolometer. Moreover, the ratios between the FSR-XRD and the bolometer among different shots were explored. In 8 shots, the standard deviation of the ratio was 6%. It is comparable to XRD response change of 7%.
Spectral response of localized surface plasmon in resonance with mid-infrared light
We study spectral responses of localized surface plasmons (LSPs) in gold nanorods, which resonate at mid-infrared frequencies, by transmission spectroscopy and electromagnetic field analyses. The resonance linewidth is found to be linearly proportional to the resonance frequency, indicating that the dephasing due to Drude relaxation is suppressed and that the overall dephasing is dominated by radiative damping. Owing to the reduced radiative/non-radiative damping and large geometrical length of the nanorod, near-field intensity enhancement exceeds several hundred times. Nonetheless the resonance linewidth is comparable with or larger than the bandwidth of a 100-fs pulse, and therefore the enhanced near-field as short as 100-fs can be created upon pulsed excitation. The large enhancements with appropriate bandwidths make LSPs promising for enhanced nonlinear spectroscopies, coherent controls, and strong-field light-matter interactions in the mid-infrared range.
Raman spectroscopy of thermally perturbed carbon fibers: Discriminating spectral responses of modulus classes and defect types
The mechanical strength properties of carbon fibers are generally thought to be correlated with the presence of underlying atomic-level defects. These defects serve to break the underlying translational symmetry of the graphitic or graphene subunits of the fiber construction, resulting in the emergence of new Raman-active spectral features. However, historical attempts to classify the precise origin of defect contributions to the Raman spectra have been challenging because of indistinct and overlapping features in the carbon fiber Raman spectra. Further, while substantial research exists on high-temperature exposure in inert atmospheres for carbon fiber composites, comparatively less addresses microscale behaviors and Raman spectral alterations to monofilament carbon fibers exposed to high-temperature atmospheric environments. Here, we report Raman spectral responses of nine commercially available high-performance, polyacrylonitrile-based carbon fibers exposed to various atmospheric heat treatments. In this work, we introduce a model-independent characterization method, the integrated absolute difference, to quantify the spectral responses to heat treatment of different fiber modulus classes. We combine this new method with a newly reported strategy to standardize spectral fitting for carbon fibers. With this approach, we show that atomic-scale defects in the underlying fiber microstructure manifest in measurably distinct manners and have distinct responses to thermal perturbation. These combined approaches may lay the foundation for disentangling contributions from specific defects in the Raman spectra of carbon fibers.
Tunable spectral response by hydrogen irradiation of Ga(AsN) superlattice diodes
We report on the tuning of the spectral response of superlattice (SL) diodes based on dilute nitride Ga(AsN) alloys by post-growth hydrogenation. Hydrogen is incorporated into the superlattice where it neutralizes the electronic activity of nitrogen by forming N-H complexes. We exploit the controlled thermal dissociation of the complexes to tune the energy of the SL photocurrent absorption and electroluminescence emission; also, by annealing a submicron spot with a focused laser beam we create a preferential path for the injection of carriers, thus activating a nanoscale light emitting region. This method can be used for fabricating planar diode arrays with distinct optical active regions, all integrated onto a single substrate.
An Extended Study on the Uncertainty Quantification of a Photodiode's Spectral Responsivity
An extended study was done on the analysis procedure for spectral responsivity of a silicon detector from the range of 200 nm to 1100 nm for the Optical Component Calibration laboratory at Livermore Operations in Livermore California. As a result, the uncertainty of the procedure was quantified to account for variables that contribute to uncertainty; such as the reproducibility and repeatability of the working standards, quantifying Type A and B uncertainties, validating laboratory equipment and associated software, and looking at environmental variables. The findings lead to a revised analysis reporting procedure that reports uncertainties depending on three spectral ranges, 300 nm to 400 nm, 400 nm to 700 nm, and 700 nm to 1100 nm. A proficiency test was done to compare the difference between both methods and a noticeable difference was found. The results showed that the previous reporting method over estimated uncertainty as much as 3.5% for the 300 nm to 400 nm range, 4% in the >400 nm to 700 nm range, and 2% in the >700 nm to 1100 nm range. The findings lead to the use of the revised procedure when producing calibration certificates, better quantified measurement uncertainties, and will be used for the process of updating the scope of accreditation from the National Voluntary Laboratory Accreditation Program.
Spectral response to ground displacement at Hattiesburg resulting from nuclear event SALMON
Spectral response is developed from principal portions of a record of ground displacement in Hattiesburg, Mississippi, resulting from the SALMON event, Project DRIBBLE, an underground nuclear explosion near Baxterville, Mississippi in October 1964. Further, no acceleration records are available for Hattiesburg. As a part of the study it was found that peak response in the important short-period range could be reasonably estimated using as little as one second of selected motion from the entire record, and that a simple stochastic model of this key portion of the ground motion essentially duplicated the peak response.