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Evidence from coupled (Sm-147)-(Nd-143) and (Sm-146)-(Nd-142) systematics for very early (4.5-Gyr) differentiation of the earth's mantle

Evidence for early differentiation of the earth's mantle is presented based on measurements of Nd-143/Nd-144 and Nd-142/Nd-144 ratios in an approximately 3.8 Gyr-old supracrustal rock from Isua, West Greenland. Coupled (Sm-146,147)-(Nd-142,143) systematics suggest that the fractionation of Sm/Nd took place 4.44-4.54 Gyr ago, due to extraction of a light rare earth element-enriched primordial crust.

Harper, Charles L., Jr.

Soil Moisture Active Passive Mission L4_SM Data Product Assessment (Version 2 Validated Release)

During the post-launch SMAP calibration and validation (Cal/Val) phase there are two objectives for each science data product team: 1) calibrate, verify, and improve the performance of the science algorithm, and 2) validate the accuracy of the science data product as specified in the science requirements and according to the Cal/Val schedule. This report provides an assessment of the SMAP Level 4 Surface and Root Zone Soil Moisture Passive (L4_SM) product specifically for the product's public Version 2 validated release scheduled for 29 April 2016. The assessment of the Version 2 L4_SM data product includes comparisons of SMAP L4_SM soil moisture estimates with in situ soil moisture observations from core validation sites and sparse networks. The assessment further includes a global evaluation of the internal diagnostics from the ensemble-based data assimilation system that is used to generate the L4_SM product. This evaluation focuses on the statistics of the observation-minus-forecast (O-F) residuals and the analysis increments. Together, the core validation site comparisons and the statistics of the assimilation diagnostics are considered primary validation methodologies for the L4_SM product. Comparisons against in situ measurements from regional-scale sparse networks are considered a secondary validation methodology because such in situ measurements are subject to up-scaling errors from the point-scale to the grid cell scale of the data product. Based on the limited set of core validation sites, the wide geographic range of the sparse network sites, and the global assessment of the assimilation diagnostics, the assessment presented here meets the criteria established by the Committee on Earth Observing Satellites for Stage 2 validation and supports the validated release of the data. An analysis of the time average surface and root zone soil moisture shows that the global pattern of arid and humid regions are captured by the L4_SM estimates. Results from the core validation site comparisons indicate that "Version 2" of the L4_SM data product meets the self-imposed L4_SM accuracy requirement, which is formulated in terms of the ubRMSE: the RMSE (Root Mean Square Error) after removal of the long-term mean difference. The overall ubRMSE of the 3-hourly L4_SM surface soil moisture at the 9 km scale is 0.035 cubic meters per cubic meter requirement. The corresponding ubRMSE for L4_SM root zone soil moisture is 0.024 cubic meters per cubic meter requirement. Both of these metrics are comfortably below the 0.04 cubic meters per cubic meter requirement. The L4_SM estimates are an improvement over estimates from a model-only SMAP Nature Run version 4 (NRv4), which demonstrates the beneficial impact of the SMAP brightness temperature data. L4_SM surface soil moisture estimates are consistently more skillful than NRv4 estimates, although not by a statistically significant margin. The lack of statistical significance is not surprising given the limited data record available to date. Root zone soil moisture estimates from L4_SM and NRv4 have similar skill. Results from comparisons of the L4_SM product to in situ measurements from nearly 400 sparse network sites corroborate the core validation site results. The instantaneous soil moisture and soil temperature analysis increments are within a reasonable range and result in spatially smooth soil moisture analyses. The O-F residuals exhibit only small biases on the order of 1-3 degrees Kelvin between the (re-scaled) SMAP brightness temperature observations and the L4_SM model forecast, which indicates that the assimilation system is largely unbiased. The spatially averaged time series standard deviation of the O-F residuals is 5.9 degrees Kelvin, which reduces to 4.0 degrees Kelvin for the observation-minus-analysis (O-A) residuals, reflecting the impact of the SMAP observations on the L4_SM system. Averaged globally, the time series standard deviation of the normalized O-F residuals is close to unity, which would suggest that the magnitude of the modeled errors approximately reflects that of the actual errors. The assessment report also notes several limitations of the "Version 2" L4_SM data product and science algorithm calibration that will be addressed in future releases. Regionally, the time series standard deviation of the normalized O-F residuals deviates considerably from unity, which indicates that the L4_SM assimilation algorithm either over- or under-estimates the actual errors that are present in the system. Planned improvements include revised land model parameters, revised error parameters for the land model and the assimilated SMAP observations, and revised surface meteorological forcing data for the operational period and underlying climatological data. Moreover, a refined analysis of the impact of SMAP observations will be facilitated by the construction of additional variants of the model-only reference data. Nevertheless, the “Version 2” validated release of the L4_SM product is sufficiently mature and of adequate quality for distribution to and use by the larger science and application communities.

SMAP L4_SM

Soil Moisture Active Passive (SMAP) Project Assessment Report for Version 4 of the L4_SM Data Product

This report provides an assessment of Version 4 of the SMAP Level 4 Surface and Root Zone Soil Moisture (L4_SM) product, released on 14 June 2018. The assessment includes comparisons of L4_SM soil moisture and temperature estimates with in situ measurements from core validation sites and sparse networks. The assessment further includes a global evaluation of the internal diagnostics from the ensemble-based data assimilation system that is used to generate the L4_SM product, including observation-minus-forecast (O-F) brightness temperature residuals and soil moisture analysis increments.Together, the core validation site comparisons and the statistics of the assimilation diagnostics areconsidered primary validation methodologies for the L4_SM product. Comparisons against in situ measurements from regional-scale sparse networks are considered a secondary validation methodology because such in situ measurements are subject to upscaling errors from the point-scale to the grid-cell scale of the data product.The Version 4 L4_SM product benefits from an improved land surface modeling system and from retrospective surface meteorological forcing data that are as consistent as possible with the present-day datain terms of their climatology. Specifically, the model changes include revised parameters and parameterizations for (i) the surface energy balance, (ii) recharge from below of the model's surface excess reservoir, and (iii) the snow depletion curve. Updated ancillary inputs include improved datasets for landcover, topography, and vegetation height. The Version 4 algorithm further includes a revised approach to precipitation corrections that improves the precipitation climatology in Africa and the high-latitudes. Moreover, for system calibration the model is forced retrospectively with MERRA-2 reanalysis data, which are more consistent with the near-real time GEOS forward processing (FP) data used during the SMAP period than the retrospective GEOS data that were available for previous L4_SM versions. An analysis of the time-average surface and root zone soil moisture shows that the global pattern ofarid and humid regions is captured by the Version 4 L4_SM estimates. Owing to the changes in the landsurface modeling system, surface soil moisture is typically drier by several volumetric percent in Version 4 compared to Version 3, whereas root zone soil moisture is wetter in Version 4 in some regions and drierin others. Because of these climatological differences, the Version 3 and Version 4 products should not be combined into a single dataset for use in applications.Results from the core validation site comparisons indicate that Version 4 of the L4_SM data product meets the self-imposed L4_SM accuracy requirement, which is formulated in terms of the RMSE after removal of the long-term mean difference (ubRMSE). The overall ubRMSE of the 3-hourly L4_SM dataat the 9 km scale is 0.039 m3 m-3 for surface soil moisture and 0.029 m3 m-3 for root zone soil moisture,below the 0.04 m3 m-3 requirement. The L4_SM estimates are an improvement over estimates from a model-only Nature Run version 7.2 (NRv7.2), which demonstrates the beneficial impact of the SMAP brightness temperature data. Overall, L4_SM surface and root zone soil moisture estimates are more skillful than NRv7.2 estimates, with statistically significant improvements at the 5% level for surface soil moisture R and anomaly R values. Results from comparisons of the L4_SM product to i

Reichle, Rolf H.

Neutron-capture Cl-36, Ca-41, Ar-36, and Sm-150 in large chondrites: Evidence for high fluences of thermalized neutrons

We have measured significant concentrations of Cl-36, Ca-41, Ar-36 from decay of Cl-36, and Sm-150 produced from the capture of thermalized neutrons in the large Chico L6 chondrite. Activities of Cl-36 and Ca-41, corrected for a high-energy spallogenic component and a terrestrial age of approximately 50 ka, give average neutron-capture production rates of 208 atoms/min/g-Cl and 1525 atoms/min/kg-Ca, which correspond to thermal neutron (n) fluxes of 6.2 n/sq cm/s and 4.3 n/sq cm/s, respectively. If sustained for the approximately 65 Ma single-stage, cosmic ray exposure age of Chico, these values correspond to thermal neutron fluences of approximately 1.3 x 10(exp 16) and 0.8 x 10(exp 16) n/sq cm for Cl-36 and Ca-41, respectively. Stepwise temperature extraction of Ar in Chico impact melt shows Ar-36/Ar-38 ratios as large as approximately 9. The correlation of high Ar-36/Ar-38 with high Cl/Ca phases in neutron-irradiated Chico indicates that the excess Ar-36 above that expected from spallation is due to decay of neutron-produced Cl-36. Excess Ar-36 in Chico requires a thermal neutron fluence of 0.9-1.7 x 10(exp 16) n/sq cm. Decreases in Sm-149/Sm-152 due to neutron-capture by Sm-149 correlate with increases in Sm-150/Sm-152 for three samples of Chico, and one of the Torino H-chondrite. The 0.08% decrease in Sm-149 shown by Chico corresponds to a neutron fluence of 1.23 x 10(exp 16) n/sq cm. This fluence derived from Sm considers capture of epithermal neutrons and effects of chemical composition on the neutron energy distribution. Excess Ar-36 identified in the Arapahoe, Bruderheim, and Torino chondrites and the Shallowater aubrite suggest exposure to neutron fluences of approximately 0.2-0.2 x 10(exp 16) n/sq cm. Depletion of Sm-149 in Torino and the LEW86010 angrite suggest neutron fluences of 0.8 x 10(exp 16) n/sq cm and 0.25 x 10(exp 16) n/sq cm, respectively. Neutron fluences of approximately 10(exp 16) n/sq cm in Chico are almost as large as those previously observed for some lunar soils. Consideration of exposure ages suggests that the neutron flux in Chico may have been greater than that in many lunar soils.

Bogard, D. D.

Sm-Nd Isotopic Systematics of Troctolite 76335

A study of the Sm-Nd isotopic systematics of lunar Mg-suite troctolite 76335 was undertaken to further establish the early chronology of lunar magmatism. Because the Rb-Sr isotopic systematics of similar sample 76535 yielded an age of 4570 +/- 70 Ma [2, lambda = 1.402 x 10(exp -11)], 76335 was expected to yield an old age. In contrast, the Sm-Nd and K-Ar ages of 76535 indicate that the sample is approximately 4260 Ma old, one of the youngest ages obtained for a Mg-suite rock. This study establishes the age of 76335 and discusses the constraints placed on its petrogenesis by its Sm-Nd isotope systematics. The Sm-Nd isotopic system of lunar Mg-suite troctolite 76335 indicates an age of 4278 +/- 60 Ma with an initial epsilon (sup 143)(sub Nd) value of 0.06 +/- 0.39. These values are consistent with the Sm-Nd isotopic systematics of similar sample 76535. Thus, it appears that a robust Sm-Nd age can be determined from a highly brecciated lunar sample. The Sm-Nd isotopic systematics of troctolites 76335 and 76535 appear to be different from those dominating the Mg-suite norites and KREEP basalts. Further analysis of the Mg-suite must be completed to reveal the isotopic relationships of these early lunar rocks.

Edmunson, J.

Sm-Nd and Initial Sr-87/Sr-86 Isotopic Systematics of Asuka 881394 and Cumulate Eucrites Yamato 980318/433 Compared

The Asuka 881394 achondrite contains fossil Al-26 and Mn-53 and has a Pb-206/Pb-207 age of 4566.5 +/- 0.2 Ma, the oldest for an achondrite. Recent re-investigation of A881394 yielded revised initial Sm-146/Sm-144 = (9.1 +/- 1.4) x 10(exp -3), a Sm-147-Nd-143 age of 4525 +/- 58 Ma, a Rb-87-Sr-87 age of 4490 +/- 130 Ma, and initial Sr-87/Sr-86 = 0.698991 +/- 19, respectively. The relatively large uncertainties in the Sm-Nd and Rb-Sr ages are due to disturbances of the isotopic systematics of tridymite and other minor phases. A preliminary value for the Sm-147-Nd-143 age of the Yamato 980318 cumulate eucrite of 4560 +/- 150 Ma was refined in later work to 4567 +/- 24 Ma as reported orally at LPSC 35. Similarly, a preliminary value for Sm-146/Sm-144 = (7.7 +/- 1.2) x 10 (exp -3) was refined to (6.0 +/- 0.3) x 10(exp -3). For Yamato 980433, a Sm-147-Nd-143 age of 4542 +/-42 Ma and Sm-146/Sm-144 = (5.7 +/- 0.5) x 10(exp -3) has been reported. Because these two cumulate eucrites are paired, we consider them to represent one igneous rock and present their combined isotopic data here.

Nyquist, L. E.

Technical Report Series on Global Modeling and Data Assimilation: Soil Moisture Active Passive (SMAP) Project Assessment Report for the Beta-Release L4_SM Data Product - Volume 40

During the post-launch SMAP calibration and validation (Cal/Val) phase there are two objectives for each science data product team: 1) calibrate, verify, and improve the performance of the science algorithm, and 2) validate the accuracy of the science data product as specified in the science requirements and according to the Cal/Val schedule. This report provides an assessment of the SMAP Level 4 Surface and Root Zone Soil Moisture Passive (L4_SM) product specifically for the product's public beta release scheduled for 30 October 2015. The primary objective of the beta release is to allow users to familiarize themselves with the data product before the validated product becomes available. The beta release also allows users to conduct their own assessment of the data and to provide feedback to the L4_SM science data product team. The assessment of the L4_SM data product includes comparisons of SMAP L4_SM soil moisture estimates with in situ soil moisture observations from core validation sites and sparse networks. The assessment further includes a global evaluation of the internal diagnostics from the ensemble-based data assimilation system that is used to generate the L4_SM product. This evaluation focuses on the statistics of the observation-minus-forecast (O-F) residuals and the analysis increments. Together, the core validation site comparisons and the statistics of the assimilation diagnostics are considered primary validation methodologies for the L4_SM product. Comparisons against in situ measurements from regional-scale sparse networks are considered a secondary validation methodology because such in situ measurements are subject to upscaling errors from the point-scale to the grid cell scale of the data product. Based on the limited set of core validation sites, the assessment presented here meets the criteria established by the Committee on Earth Observing Satellites for Stage 1 validation and supports the beta release of the data. The validation against sparse network measurements and the evaluation of the assimilation diagnostics address Stage 2 validation criteria by expanding the assessment to regional and global scales.

ubRMSE

Sm-Nd isotopic evolution of chondrites and achondrites. II

The chondrite data obtained as a result of an investigation of Sm-147-Nd-143 and Sm-146-Nd142 isotope systematics in five chondrites and the Moama and Andra dos Reis (ADOR) achondrites are consistent with previously reported reference values for the chondritic uniform reservoir (CHUR) of 0.511847 and 0.1967. The Nd-143/Nd-144 and Sm-147/Nd-144 values of the bulk chondrites analyzed suggest that the CHUR evolution is known to within 0.5 epsilon-units and 0.15 percent of the CHUR values for the entire history of the solar system. The Sm-146-Nd-142 systematics of ADOR and Moama support the hypothesis that Sm-146 was present in the early solar system, suggesting a high Sm-146/Sm-144 ratio that cannot be explained as a late injection forma supernova, and must instead be due to galactic nucleosynthesis.

Jacobsen, S. B.

The presence of Sm-146 in the early solar system and implications for its nucleosynthesis

A correlation of Nd-142/Nd-144 with Sm-144/Nd-144 in two meteorites which have a large range in Sm-144/Nd-144 in their constituent mineral phases is presented as evidence for the presence of the p-process nucleus Sm-146 in the early solar system and its alpha-decay into Nd-142. The ratio Sm-146/Sm-144 is estimated to be about 0.015 at the time of solar system formation, 4.56 AE ago. It is suggested that the abundance of Sm-146 is compatible with p-proc ess production rate estimates, but not with the production rate for Sm-146 based on a photodisintegration model for the production of p-process nuclides.

Prinzhoffer, A.

Fuel Oxidizer Reaction Products (FORP) Contamination of Service Module (SM) and Release of N-nitrosodimethylamine(NDMA)in a Humid Environment from Crew EVA Suits Contaminated with FORP

The Service Module (SM) is an element of the Russian Segment of the International Space Station (ISS). One of the functions of the SM is to provide attitude control for the ISS using thrusters when the U.S. Control Moment Gyros (CMG's) must be desaturated. Prior to an Extravehicular Activity (EVA) on the Russian Segment, the Docking Compartment (DC1) is depressurized, as it is used as an airlock. When the DC1 is depressurized, the CMG's margin of momentum is insufficient and the SM attitude control thrusters need to fire to desaturate the CMG's. SM roll thruster firings induce contamination onto adjacent surfaces with Fuel Oxidizer Reaction Products (FORP). FORP is composed of both volatile and non-volatile components. One of the components of FORP is the potent carcinogen N-nitrosdimethylamine (NDMA). Since the EVA crewmembers often enter the area surrounding the thrusters for tasks on the aft end of the SM and when translating to other areas of the Russian Segment, the presence of FORP is a concern. This paper will discuss FORP contamination of the SM surfaces, the release of NDMA in a humid environment from crew EVA suits, if they happen to be contaminated with FORP, and the toxicological risk associated with the NDMA release.

Schmidl, William

Sm-Nd Isotopic Studies of Ureilite Novo Urei

Ureilites are ultramafic (harzburgitic) achondrites composed predominantly of olivine and pyroxenes, abundant carbon (graphites and shock-produced diamonds), some metal and sulfides. These rocks probably represent ultramafic mantles of differentiated parent asteroidal bodies. Age determinations of these rocks by Rb-Sr and Sm-Nd methods have been difficult because of their extremely low abundances of these parent-daughter elements. Nevertheless, Sm-Nd isochron ages were reported for Kenna, Goalpara, MET 78008 and PCA 82506 yielding ages of 3.74+/-0.02 Ga, approx.3.7 Ga, 4.09+/-0.08 Ga, 4.23+/-0.06 Ga, respectively [1-4]. These "young" Sm-Nd ages may represent secondary metasomatism events [1] related to impacts [5], as indicated by the similarly young Ar-39-Ar-40 degassing ages of 3.3-4.1 Ga for ureilites Kenna, Novo Urei and Havero [6]. Alternatively, it has been suggested that these rocks may have been contaminated with terrestrial crustal materials and the isochrons do not have any age significance [2,7]. Indications of old approx.4.56 Ga ages for ureilites were reported from the U-Pb and Sm-Nd model ages for MET 78008 [8]. More reliable evidences for old formation ages of ureilites were reported recently using the short-lived chronometers Hf-182-W-182, Al-26-Mg-26 and Mn-53-Cr-53. The deficits of 182W in ureilites suggest the metal-silicate segregation occurred very early, approx.1-2 Ma after CAI [9]. The Al-26-Mg-26 and Mn-53-Cr-53 studies for a feldspathic lithology [10] and the Mn-53-Cr-53 for olivine- and pyroxene-dominant lithologies [11] in ureilites revealed that they crystallized approx.5.4 Ma after CAI, i.e., at 4563.8+/-0.5 Ma relative to D.Orbigny. In this report, we present Sm-Nd isotopic data for a relatively fresh ureilite, Novo Urei, a rare ureilite fall (1886). We compare these data to Sm-Nd data for other ureilites, and discuss Novo Urei's petrogenesis

Shih, C.-Y.

Redetermination of the Sm-Nd Age and Initial (Epsilon)Nd of Lunar Troctolite 76535: Implications for Lunar Crustal Development

Lunar troctolite 76535 is an old lunar rock predating the era of the lunar cataclysmic bombardment, but its radiometrially determined ages have been discordant [1-3]. The most recent multi-chronometer study [4] gave preferred ages of 4226+/-35 Ma and 4236+/-15 Ma from a Pb-207/Pb-206 isochron and an U-Pb upper concordia intercept, resp. We derive an age of 4323+/-64 Ma from Sm-Nd data reported by [4] for the bulk rock and three mineral separates. They derived an age of approx.4.38 Ga from combined Rb-Sr data [3,4] by omitting data for olivine separates. Ar-39-Ar-40 ages of approx.4.2 Ga are summarized by [5]. New Sm-147-Nd-143 data presented here give an age of 4335+/-71 Ma in agreement with the Sm-Nd age from [4], whereas Sm-146-Nd-142 data give a model age T(sub LEW) = 4439+/-22 Ma. Further, initial (Epsilon)Nd-143 for 76535 conforms to the Nd-143 evolution expected in an urKREEP [6] reservoir, consistent with inheritance of urKREEP Sm-Nd systematics via assimilation. We show that urKREEP Sm-Nd systematics require the lunar initial (Epsilon)Nd-143 to exceed the Chondritic Uniform Reservoir (CHUR) value [7], but are consistent with evolution from initial (Epsilon)Nd-143 like that of the HED meteorite parent body as defined by a 4557+/-20 Ma internal isochron for the cumulate eucrites Y-980433 and Y- 980318 [8].

Nyquist, Laurence E.

The Sm-(146,147)-Nd-(142,143) formation interval for the lunar mantle and implications for lunar evolution

Small anomalies in the isotopic abundance of Nd-142 have been measured for two A17 high-Ti basalts, ilmenite basalt 12056, olivine-pigeonite basalt 12039, feldspathic basalt 12038, and two KREEP basalts. These anomalies correlate with Sm-147/Nd-144 for the basalt source regions as calculated from initial Nd-143/Nd-144 ratios in the basalts, and are interpreted to be from decay of Sm-146 (t sub 1/2 = 103 Ma) in distinct lunar mantle reservoirs. A three-stage model for evolution of Nd-143/Nd-144 and Nd-142/Nd-144 yields reservoir Sm-147/Nd-144 ratios which, with the Nd-142/Nd-144 ratios in the basalts, form a 'mantle isochron' giving a lunar mantle formation interval of 94+2230 Ma (2c(rho)). Calculated reservoir Sm/Nd ratios are in the range expected from some earlier models of basalt petrogenesis. The isochron value of Nd-142/Nd-144 at Sm-147/Nd-144 sub CHUR = 0.1967 is within error limits of the average Nd-142/Nd-144 measured for an L6 chondrite, an H5 chondrite, and the Orgueil carbonaceous chondrite. Evolution of Nd-143 and Nd-142 for high-Ti basalt 70135 was modeled precisely, starting from chondritic relative REE and Nd-isotopic abundances and using the initial (Sm-146/Sm-144) sub 0 ratio inferred from a previous study of angrite LEW86010 as the initial solar system value of this parameter. We infer that the initial Sm/Nd ratio in precursor lunar materials was very nearly chondritic (within approximately 8 percent) prior to lunar differentiation.

Nyquist, L. E.

Rb-Sr and Sm-Nd Study of the D'Orbigny Angrite

D'Orbigny, is a relatively a new angrite find. Angrites are achondrites that show unique mineralogy and typically ancient crystallization ages. D Orbigny has been described extensively by. We have initiated a study of D Orbigny. A Pb-Pb model age of 4559 Ga has been reported. The presence of Pu-244 fission Xe in D Orbigny has also been reported. We present Sm-Nd and Rb-Sr results and a Mn-53-Cr-53 study is in progress. We had expected to find a relatively well-behaved Sm-Nd system, and distinct evidence for the Sm-146-Nd-142 system. Emphasis in this study was placed on the precise measurement of initial Sr-87/Sr-86, since primitive initial Sr-87/Sr-86 may be characteristic of the angrite parent body. Sr isotope measurements were obtained in the recently completed laboratories at JPL, using the ThermoFinnigan Triton mass spectrometer. Due to lower amounts of Nd and Sm, Sm-Nd data were obtained on the Lunatic I spectrometer at Caltech, due to established high ionization techniques, on this instrument using light rare earth oxide ions.

Tonui, E. K.

Sm-Nd and Rb-Sr Ages for Northwest Africa 2977, A Young Lunar Gabbro from the PKT

Northwest Africa (NWA) 2977 is an olivine gabbro cumulate equivalent to one of the lithologies in lunar mare breccia NWA 773 [1,2,3]. The Ar-39-Ar-40 age is 2.77+/-0.04 Ga based on the last approx.57% of the gas release [4], similar to results for NWA 773 [5]. A Sm-Nd age (T) of 2.865+/-0.031 Ga and Epsilon(sub Nd) = -7.84+/-0.22 for the NWA 773 gabbro reported by [6] has been revised to T = 2.993+/-=0.032 Ga, Epsilon(sub Nd) -4.5+/-0.3 [7]. Sm-147-Nd-143 isochron for NWA 2977: Whole rock, pyroxene, olivine, plagioclase, whole rock leachate (approx.phosphate) and the combined leachates from the mineral separates yield a well defined Sm-Nd isochron for an age T = 3.10+/-0.05 Ga and Epsilon(sub Nd-CHUR) = -3.74+/-0.26 [8], or Epsilon(sub Nd-HEDR) = -4.61+/-0.26 [9]. Rb-87-Sr-87 isochron: NWA 2977 contains only a modest amount of Rb and/or Sr contamination. The Sr-isotopic composition of the contaminant closely resembles that of seawater. The whole rock residue after leaching combined with leach residues for plagioclase and pyroxene define an isochron age of 3.29+/-0.11 Ga for initial Sr-87/Sr-86 = 0.70287+/-18. The olivine residue, with lower Sr abundance of approx 1.5 ppm, is only slightly displaced from the isochron. The relatively small uncertainties of the Rb-Sr isochron parameters and near-concordancy with the Sm-Nd age indicate that both the Rb-Sr and the Sm-Nd ages are reliable.

Nyquist, L. E.

Prototype Interoperability Document between NASA-JSC and DLR-GSOC Describing the CCSDS SM and C Mission Operations Prototype

The purpose of the PROTOTYPE INTEROPERABILITY DOCUMENT is to document the design and interfaces for the service providers and consumers of a Mission Operations prototype between JSC-OTF and DLR-GSOC. The primary goal is to test the interoperability sections of the CCSDS Spacecraft Monitor & Control (SM&C) Mission Operations (MO) specifications between both control centers. An additional goal is to provide feedback to the Spacecraft Monitor and Control (SM&C) working group through the Review Item Disposition (RID) process. This Prototype is considered a proof of concept and should increase the knowledge base of the CCSDS SM&C Mission Operations standards. No operational capabilities will be provided. The CCSDS Mission Operations (MO) initiative was previously called Spacecraft Monitor and Control (SM&C). The specifications have been renamed to better reflect the scope and overall objectives. The working group retains the name Spacecraft Monitor and Control working group and is under the Mission Operations and Information Services Area (MOIMS) of CCSDS. This document will refer to the specifications as SM&C Mission Operations, Mission Operations or just MO.

Lucord, Steve A.

Assessing Version 4 of the SMAP L4_SM Data Product

Version 4 of the SMAP Level 4 Surface and Root Zone Soil Moisture (L4_SM) product benefits from an improved land surface modeling system. Surface soil moisture is typically drier by several volumetric percent in Version 4 compared to Version 3, whereas root zone soil moisture is wetter in Version 4 in some regions and drier in others. Results from core validation site comparisons show that Version 4 of the L4_SM data product meets the accuracy requirement, which is formulated in terms of the RMSE after removal of the long-term mean difference (ubRMSE). The overall ubRMSE of the 3-hourly L4_SM data at the 9 km scale is 0.039 m3 m-3 for surface soil moisture and 0.029 m3 m-3 for root zone soil moisture, below the 0.04 m3 m-3 requirement. L4_SM surface and root zone soil moisture estimates are more skillful than model-only simulation estimates that are not informed by SMAP brightness temperature observations, with statistically significant improvements at the 5% level for surface soil moisture R and anomaly R values. Results from comparisons of the L4_SM product to in situ measurements from more than 400 sparse network sites corroborate the core validation site results.

Reichle, R.

Neutron capture on Sm-149 in lunar samples.

High precision isotopic composition measurements of Sm have been carried out for two terrestrial and seven lunar samples from three Apollo sites. The lunar samples, selected to show a wide variation in cosmic ray exposure ages, have a wide range of enrichments in Sm-150/Sm-154 (up to 0.8%) and depletions in Sm-149/Sm-154 which are due to neutron capture. The ratio of the number of neutrons captured per atom by Sm-149 to Gd-157 is 0.9 and reflects a hardened lunar neutron spectrum. This ratio is in reasonable but not exact agreement with that obtained from the theoretical lunar neutron energy spectrum of Lingenfelter, Canfield and Hampel. The average composition for terrestrial samarium is given.

Russ, G. P., III