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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Quantitative Thermal Imaging of Single-Walled Carbon Nanotube Devices by Scanning Joule Expansion Microscopy

Electrical generation of heat in single-walled carbon nanotubes (SWNTs) and subsequent thermal transport into the surroundings can critically affect the design, operation, and reliability of electronic and optoelectronic devices based on these materials. Here we investigate such heat generation and transport characteristics in perfectly aligned, horizontal arrays of SWNTs integrated into transistor structures. We present quantitative assessments of local thermometry at individual SWNTs in these arrays, evaluated using scanning Joule expansion microscopy. Measurements at different applied voltages reveal electronic behaviors, including metallic and semiconducting responses, spatial variations in diameter or chirality, and localized defect sites. Furthermore, analytical models, validated by measurements performed on different device structures at various conditions, enable accurate, quantitative extraction of temperature distributions at the level of individual SWNTs. Using current equipment, the spatial resolution and temperature precision are as good as ~100 nm and ~0.7 K, respectively.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Note: Automated optical focusing on encapsulated devices for scanning light stimulation systems

Recently, a scanning light stimulation system with an automated, adaptive focus correction during the measurement was introduced. Here, its application on encapsulated devices is discussed. This includes the changes an encapsulating optical medium introduces to the focusing process as well as to the subsequent light stimulation measurement. Further, the focusing method is modified to compensate for the influence of refraction and to maintain a minimum beam diameter on the sample surface.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Humidity effects on tip-induced polarization switching in lithium niobate

In the last several decades, ferroelectrics have attracted much attention as perspective materials for nonlinear optics and data storage devices. Scanning probe microscopy (SPM) has emerged as a powerful tool both for studies of domain structures with nanoscale spatial resolution and for writing the isolated nanodomains by local application of the electric field. Quantitative analysis of the observed behavior requires understanding the role of environmental factors on imaging and switching process. Here, we study the influence of the relative humidity in the SPM chamber on tip-induced polarization switching. The observed effects are attributed to existence of a water meniscus between the tip and the sample surface in humid atmosphere. These results are important for a deeper understanding of complex investigations of ferroelectric materials and their applications and suggest the necessity for fundamental studies of electrocapillary phenomena at the tip-surface junction and their interplay with bias-induced materials responses.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Energy Delivery Systems with Verifiable Trustworthiness (Final Report)

Energy Delivery Systems (EDS) must be verified to be free from intrusive and malicious software. One way of verifying this software is to perform device scans to detect malicious code. Because it is possible to have “fileless” malware that exists only in device (volatile) memory, offline scanning and even many forms of online scanning is insufficient for detection. This project (“Verify”) addresses this need by performing direct sampling of memory during device operation to detect unexpected or modified software while not interfering with device operation. The Verify project provides a proof-of-concept of detection by random sampling combined with remote software- and timing-based attestation methods for robust detection of in-memory threats. An external review of Verify was performed by our partner, General Electric (GE), and a summary of their findings is provided.

97 MATHEMATICS AND COMPUTING↗

Recent Developments in X-ray Imaging Technology

A review of recent developments in the technology of x-ray imaging hardware has been completed. Based on this review, we believe that the following items merit more detailed scrutiny in regards to their applications to US Homeland Security interests: • Fujifilm’s 17” x 17” flat panel detectors which are part of the company’s FDR AcSelerate x-ray imaging systems, • GE Healthcare’s Gemstone™ scintillators for their use in CT units, • CZT baggage scanning units under development by either Endicott Interconnect Technologies or Redlen Technologies and which employ a new “XENA™” IC with NEXIS™ protocols, and • Dual Energy Line- Scanning devices from either Hamamatsu Photonics (C10800 series) or from the X-Scan Imaging Corporation (XD8800 and XDR8800 Series Line-Scan Camera). The bases for these recommendations, as well as other not highlighted above, are noted below. The footnotes document company contact information. Beyond the text highlighting the recommendations, a number of appendices have been added which document the research conducted for this review.

42 ENGINEERING↗

Nm-scale electrical resistance imaging on CdTe by scanning spreading resistance microscopy

Local resistance imaging can provide information on nm-scale carrier distribution in semiconductor devices. Scanning spreading resistance microscopy (SSRM), an atomic force microscopy-based nm-scale resistance mapping technique, has been developed for carrier delineation in Si microdevices. We report on the development and validation of SSRM on CdTe materials, by testing on molecular beam epitaxy (MBE) grown CdTe films. The probe/CdTe contact resistance was suppressed sufficiently below sample's spreading resistance by pressing the probe into the sample with ∼mN contact force and applying a large sample/probe forward bias voltage (V s ), which was understood by analyzing current-voltage (I-V) involving a serially connected insulating top layer with underlying spreading resistance. The carrier concentration as deduced from the resistance measurement, using a single mobility value, is consistent with Hall measurement with a standard deviation of 14% based on a set of MBE films with carrier concentrations in the range of 10 15 –10 16 /cm 3 . The doping polarity was readily identified by flipping V s polarity, where the resistance with reverse V s is orders of magnitude larger than forward V s . While focusing on the SSRM technique validation, we also show an example on an As-doped Cd(Se,Te) polycrystalline thin film of a high-performance CdTe solar cell, which illustrates the local resistance nonuniformity with up to two orders of magnitude differences, indicating if local mobility is roughly constant, local carrier concentration can have significant nonuniformity.

14 SOLAR ENERGY↗

The Multi Optical Transition Radiation System

The determination and monitoring of the transverse phase space in ATF2 is crucial in order to meet their performances specifications. Since the beam sizes at the Interaction Point (IP) depend strongly on the aberrations in the Final Focus System (FFS), accurate measurement upstream of the FFS is required to tune the beam sizes at the IP. The beam sizes as well as the emittance are measured in several locations in the beam diagnostic section of the Extraction Line (EXT line) of ATF2. The vertical beam sizes in the diagnostic section are of the order of 10 {mu}m this means that the devices have to image spot sizes as small as 5 {mu}m, with 10% accuracy a 2 {mu}m resolution device is necessary. The ATF2 EXT line is a beam line with low power and low repetition rate that make usable devices using solid targets. In contrast to a ring machine, where an individual bunch can be measured many times as it passes around the ring, the beam size and the emittance measurement in the LC or in the beam lines have to be performed in a single pass. This requires that the wire scan device types (laser or solid) sample across successive bunches within a train, often with an over-estimation of the beam size due to beam position and intensity jitter, and can take up to half a minute to complete the measurement. Although some of these effects could be corrected, as the jitter effect could be subtracted by using the nearby BPMs signals, this can be avoided by using Optical Transition Radiation (OTR) Monitors. These monitors are based on the transition radiation effect, a light cone emitted when the charged particle crosses a metallic interface. This light is emitted in a specular fashion so it can be focused on to a CCD and produces an image of the beam. OTRs are able to take many fast measurements and therefore to measure the emittance with high statistics, giving a low error and a good understanding of the emittance jitter. In this article, simulations of the expected beam sizes and emittance, along with a technical description of the system, its hardware and software implementation are described. Additionally first measurement of the beam size and emittance of the Multi Optical Transition Radiation System located in the Extraction Line of ATF2 are presented.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Portable positional scanning lane

A positional lane scanner and method therefor includes a positional lane cargo scanning structure having a first frame portion, a second frame portion, and a top frame portion connected to define a passage lane for a cargo vessel. The first and second frame portions are located on opposite sides and cargo vessels pass therebetween. The first and second frame portions, or both, include a first housing portion and a scanning device mounted within the first housing portion. A lifting member is provided on the top frame portion facing outward, or if the lifting means is on a transport vehicle, such as a reach spreader, a pair of lifting beams may be arranged on the transport vehicle. The lift member removably connects with a boom portion of the transport vehicle for positioning and relocating the scanning structure to be disposed adjacent a cargo vessel lane.

Stihel, Gregory C.↗

The Effect of Ring Expansion in Thienobenzo[ b ]indacenodithiophene Polymers for Organic Field-Effect Transistors

A fused donor, thienobenzo[b]indacenodithiophene (TBIDT), was designed and synthesized using a novel acid-promoted cascade ring closure strategy, and then copolymerized with a benzothiadiazole (BT) monomer. The backbone of TBIDT is an expansion of the well-known indacenodithiophene (IDT) unit and was expected to enhance the charge carrier mobility by improving backbone planarity and facilitating short contacts between polymer chains. However, the optimized field-effect transistors demonstrated an average saturation hole mobility of 0.9 cm 2 V -1 s -1 , lower than the performance of IDT-BT (~1.5 cm 2 V -1 s -1 ). Mobilities extracted from time-resolved microwave conductivity measurements were consistent with the trend in hole mobilities in organic field-effect transistor devices. Scanning tunneling microscopy measurements and computational modeling illustrated that TBIDT-BT exhibits a less ordered microstructure in comparison to IDT-BT. This reveals that a regular side-chain packing density, independent of conformational isomers, is critical to avoid local free volume due to irregular packing, which can host trapping impurities. DFT calculations indicated that TBIDT-BT, despite containing a larger, planar unit, showed less stabilization of planar backbone geometries in comparison to IDT-BT. This is due to the reduced electrostatic stabilizing interactions between the peripheral thiophene of the fused core and the BT unit, resulting in a reduction of the barrier to rotation around the single bond. Finally, these insights provide a greater understanding of the general structure-property relationships required for semiconducting polymer repeat units to ensure optimal backbone planarization, as illustrated with IDT-type units, guiding the design of novel semiconducting polymers with extended fused backbones for high-performance field-effect transistors.

36 MATERIALS SCIENCE↗

Experimental Tests of Lateral Bedload Transport Induced by a Yawed Submerged Vane Array in Open-Channel Flows

This work proposes the use of an array of yawed porous vanes to control the lateral bedload transport by locally steering bedform migration and maximize the amount of sediments redirected toward a potential sediment extraction system or bypass channel. A laboratory experiment was conducted in a quasifield-scale channel with an array of permeable vanes installed on one side, in live-bed conditions under bedload dominant regime, i.e., negligible suspended load. A baseline experiment without vanes was also performed for comparison. The evolution of migrating bedforms of different scales was tracked in space and time using a high-resolution, state-of-the-art laser scanning device. The bedload transport rate in the streamwise direction was first calculated using bedforms’ geometry and migration velocity, and then spatially distributed over the entire monitored area using a new Eulerian-averaged grid-mapping method. This allowed us to introduce a new methodology to estimate the lateral bedload transport using control volume theory and applying mass conservation. Quantitative assessments of lateral bedload transport along the channel yield consistent results, suggesting that the vanes effectively move sediments laterally as intended. Under the investigated setup, the maximum lateral sediment transport rate ranges from 9% to 18% of the whole domain-averaged streamwise transport rate. The developed methodology also allowed to identify the location where sediment capture could be maximized for the given vane spatial distribution.

42 ENGINEERING↗

Simulation of computed radiography with imaging plate detectors

Computed radiography (CR) using phosphor imaging plate detectors is taking an increasing place in Radiography Testing. CR uses similar equipment as conventional radiography except that the classical X-ray film is replaced by a numerical detector, called image plate (IP), which is made of a photostimulable layer and which is read by a scanning device through photostimulated luminescence. Such digital radiography has already demonstrated important benefits in terms of exposure time, decrease of source energies and thus reduction of radioprotection area besides being a solution without effluents. This paper presents a model for the simulation of radiography with image plate detectors in CIVA together with examples of validation of the model. The study consists in a cross comparison between experimental and simulation results obtained on a step wedge with a classical X-ray tube. Results are proposed in particular with wire Image quality Indicator (IQI) and duplex IQI.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A High-Speed Large-Range Tip-Tilt-Piston Micromirror Array

This work introduces the design of a high fill-factor (>99%) micromirror array (MMA) that consists of 1mm2 hexagonal mirrors, which are expected to each independently achieve continuous, closed-loop control of three degrees of freedom (DOFs)—tip, tilt, and piston—over large ranges (>±10o rotation and >±30μm translation) at high speeds (~45kHz for a 1o amplitude of rotational oscillation). The flexure topology of this array is designed using the Freedom, Actuation, and Constraint Topologies (FACT) synthesis approach, which utilizes geometric shapes to help designers rapidly consider every flexure topology that best achieves a desired set of DOFs driven by decoupled actuators. The geometry of this array’s comb-drive actuators are optimized in conjunction with the geometry of the system’s flexures using a novel approach. The analytical models underlying this approach are verified using finite element analysis (FEA) and validated using experimental data. The capabilities of this new mirror array will enable, or significantly improve, the performance of a variety of high-impact optical technologies such as advanced optical switches, spatial-light modulators, displays, and laser steering or scanning devices.

42 ENGINEERING↗

Monitoring Waste Tanks Using Guided Wave Technology - 18576

There are many challenges associated with the inspections of double-shell storage tanks containing radioactive waste, including limited space for accessibility and maneuverability, environments with high radiation, temperature and toxicity, and unknown physical conditions. Contents of the tank and limited space may prevent access of scanning devices that employ conventional NDE techniques such as ultrasonics, eddy current, or magnetic based methods. Resolving these challenges will become more urgent as the nuclear industry is forced to address the complications of the aging nuclear infrastructure - specifically at tank storage locations on laboratory sites across the DOE complex. A powerful, new approach to inspecting and monitoring the structural integrity of large structures, such as double-shelled tanks, is being developed using ultrasonic guided waves. Acoustic waves that propagate in a plate or other structure where the wavelength is larger than the thickness of the structure are known as ultrasonic guided waves. Ultrasonic guided waves can potentially propagate distances of tens to hundreds of feet in plate-like structures, such as those that comprise the walls and bottom of a storage tank. Guided waves enable the examination of relatively large inspection volumes from the outside surface of the structure. In double-shell tanks, the technology offers promise for examining the floor of the structure or the walls by placing guided wave sensors at accessible locations in the annulus. This guided wave technology has the capability to detect and localize areas of damage or degradation. While guided wave has recently been used in the nuclear and oil and gas industries for inspecting one-dimensional piping systems, current research is developing methods to apply this technology to the two-dimensional surfaces of double-shell storage tanks. Permanently installed sensors are being developed which would remotely collect data that would be analyzed to monitor the structural condition of the tank. Initial tests have been conducted on single plate structures to study guided wave interaction with various shapes and sizes of pertinent simulated damage mechanisms, and the experimental results were compared with hybrid finite-element numerical models. Dispersion curves were calculated to study guided wave modes and their properties in carbon steel plates and to evaluate behaviors at joints between plates. The next steps in the research process include applying the transmitters and sensors to full scale mockups, developing more mature data interpretation, and then demonstrations at an actual site. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Probing the limits of Si:P δ -doped devices patterned by a scanning tunneling microscope in a field-emission mode

Recently, a single atom transistor was deterministically fabricated using phosphorus in Si by H-desorption lithography with a scanning tunneling microscope (STM). This milestone in precision, achieved by operating the STM in the conventional tunneling mode, typically utilizes slow (∼102 nm2/s) patterning speeds. By contrast, using the STM in a high-voltage (>10 V) field-emission mode, patterning speeds can be increased by orders of magnitude to ≳104 nm2/s. We show that the rapid patterning negligibly affects the functionality of relatively large micron-sized features, which act as contacting pads for these devices. For nanoscale structures, we show that the resulting electrical transport is consistent with the donor incorporation chemistry constraining the electrical dimensions to a scale of 10 nm even though the pattering spot size is 40 nm.

Rudolph, M.↗