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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Materials Data on S3(NO)2 by Materials Project

S3(NO)2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four S3(NO)2 clusters. N5+ is bonded in a bent 120 degrees geometry to two S2- atoms. There is one shorter (1.55 Å) and one longer (1.64 Å) N–S bond length. There are two inequivalent S2- sites. In the first S2- site, S2- is bonded in a bent 120 degrees geometry to one N5+ and one O2- atom. The S–O bond length is 1.48 Å. In the second S2- site, S2- is bonded in a water-like geometry to two equivalent N5+ atoms. O2- is bonded in a single-bond geometry to one S2- atom.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on S3(NCl)2 by Materials Project

S3N2Cl2 crystallizes in the monoclinic P2_1 space group. The structure is three-dimensional. there are two inequivalent N4+ sites. In the first N4+ site, N4+ is bonded in a bent 120 degrees geometry to two S2- atoms. There is one shorter (1.57 Å) and one longer (1.64 Å) N–S bond length. In the second N4+ site, N4+ is bonded in a bent 120 degrees geometry to two S2- atoms. There is one shorter (1.56 Å) and one longer (1.62 Å) N–S bond length. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted water-like geometry to two N4+ and two equivalent Cl1- atoms. There are one shorter (2.76 Å) and one longer (3.53 Å) S–Cl bond lengths. In the second S2- site, S2- is bonded in a distorted single-bond geometry to one N4+ and two equivalent Cl1- atoms. There are one shorter (2.93 Å) and one longer (3.48 Å) S–Cl bond lengths. In the third S2- site, S2- is bonded in a distorted water-like geometry to one N4+ and three Cl1- atoms. There are a spread of S–Cl bond distances ranging from 2.22–3.55 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one S2- atom. In the second Cl1- site, Cl1- is bonded in a 2-coordinate geometry to six S2- atoms.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Materials Data on S3(NO7)2 by Materials Project

(NO2)2S3O10 crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of eight hydroxylamine, n-hydroxy- molecules and four trisulfuric acid molecules.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Selective Crystallization for Green Separations of Lanthanides Using 5-(Pyrimidyl)Tetrazolate

In an effort to develop facile, low-cost, and environmentally benign separations of lanthanides, the coordination chemistry and selective crystallization of Ln 3+ cations with the water-soluble ligand 5-(pyrimidyl)tetrazolate (pmtz) have been investigated. The wide range of coordination modes of pmtz allows for discrimination between these cations, and five distinct compound types can be prepared that are dependent on the lanthanide employed. La 3+ leads to the formation of [La(pmtz) 2 (H 2 O) 6 ]Cl (S1). [Ln(pmtz) 3 (H 2 O) 3 ]·(3+n)H 2 O is obtained with Ce 3+ and Pr 3+ (S2). Ce 3+ can also form [(Ce(pmtz) 2 (H 2 O) 3 ) 2 (μ-pmtz)](pmtz)·11H 2 O (S3). [(Ln(pmtz) 2 (H 2 O) 3 ) 2 (μ-pmtz)] 2 (pmtz) 2 ·14H 2 O (S4) is formed with Nd 3+ and Sm 3+ . Here, the smaller Ln 3+ cations, Dy 3+ to Lu 3+ , all yield [Ln(H 2 O) 8 ](pmtz) 3 ·3H 2 O (S5). This selective crystallization of Ln 3+ cations based primarily on ionic radii provides a simple method for achieving group separations.

Bai, Zhuanling↗
NASA NTRS1986

Large plasmaspheric electric fields at L approximately 2 measured by the S3-3 satellite during strong geomagnetic activity

Large plasmaspheric electric fields at L is approximately 2 measured by the S3-3 satellite during strong geomagnetic activity are reported. Since these measurements have amplitudes comparable to those of the local corotation electric field, during such events the plasmasphere is expected to get strongly altered event at such low L-values. Furthermore, those measurements could contribute to the understanding of the physics of the convection/electric field penetration to the low latitude plasmaphere as well as the disturbed dynamo, during strong geomagnetic activity. For this purpose, critical parameters related to geomagnetic activity are also presented for the reported electric field events.

Gonzalez, W. D.↗
DOE OSTI2020

Roles of Alkali Metals and Ionic Networks in Directing the Formation of Anionic Metal–Organic Frameworks

Integrating different types of fundamental chemical interactions to direct the self-assembly processes and to control the dimension of the network formed by each type of interactions is a promising strategy to develop advanced functional materials. Here, the ionic interaction of alkali metals (Na, K, Cs) towards multi-functional 2,2’-disulfo-4,4’-oxydibenzoic acid is utilized in two solvent systems, aqueous-amide and uro-amide, to synthesize six novel anionic framework materials with dramatically different features and dimensionalities: (Na 3 [Zn 4 O(L 4- ) 3 (e-murea)(H 2 O) 3 ](H 2 N(CH 3 ) 2 +) 3 (CPM-s1), [Zn 4 O(L 4- ) 3 (DMF)]((NH 2 (CH 3 ) 2 +) 6 ) (CPM-s2), Na 6 [(Zn 2 OH 2 ) 3 (L 3- ) 6 ](H 2 O) 3 (CPM-s3), K 3 [Zn 2 (L 4- ) 2 ](H 2 N(CH 3 ) 2 +)(e-murea) 2 (H 2 O) 3 (CPM-s4), K 4 [Zn(L 3- ) 2 ](H 2 O) 2 (CPM-s5), and Cs 6 [Zn(L 4- ) 2 ](H 2 O) 2 (CPM-s6), L 4- = 2,2’-disulfo-4,4’-oxydibenzoate, DMF = N,N-dimethylformamide, e-murea = 1,3-dimethyl-1-2-imidazolidinone). In CPM-s1 to CPM-s6, the alkali-sulfonate ionic bonding networks transformed from 0D clusters with Na + to 1D chains and 2D sheets with K + , and 3D network with Cs + . These vastly differing ionic domains influenced the coordination modes and spatial arrangements of the metal-carboxylate linkers, which consequently, directed the dimensionality of the coordination networks from 3D with Na + to 1D with Cs + . CPM-s1 and CPM-s2, made from tetrameric Zn 4 O clusters are rare examples of anionic MOF-5-type structures. CPM-s3 features an unprecedented hexameric Zn 6 cluster. Even though a large portion of the charge-balancing cations in these materials would hamper hydrogen bonding networks, some of them still exhibit very high ionic conductivity (e.g. 1.25 x 10 -3 S cm -1 in CPM-s3), suggesting the potential of these materials as solid-state electrolytes.

36 MATERIALS SCIENCE↗
NASA NTRS2004

[Activities of System Studies and Simulation, Inc.]

Contents include the following: 1. Launch Vehicle Interface Work Performed: a. S3 provided to KSC the new launch inclination targets needed for the April '04 launch date. 2. Prelaunch operations work performed: a. S3 updated the staffing plan for MSFC on-console personnel\during the Final Countdown prior to launch. 3. Software Assessment Work Performed: a. S3 evaluated and recommended approval for Program Control Board (PCB) proposed change 649 for ground software changes, as well as change 650 and 650A for Stored Program Commands. 4. Education and Public Outreach Work Performed: a. S3 continues to coordinate the effort for the design and fabrication of scale models of the GP-3 for use at the launch site, education forums, and management/technical briefings. S3 also prepared a Change Request for additional funds needed for fabrication of additional scale models. S3 drafted the planned uses of these models, including the possibility of participation in the Boston, MA showings of the traveling Einstein Exhibit. 5. Program Management Support Work Performed: a. S3 prepared the input for and closed three MSFC Centerwide Action Item Tracking Systems (CAITS) actions during this period.

Source record↗
NASA NTRSDate not supplied

Hydrological Data at the NASA GES DISC: Current Capabilities and New Opportunities

The NASA Goddard Earth Sciences Data and Information Services Center (GES DISC) is one of twelve NASA Earth science data centers that document, process, archive and distribute data from Earth observation missions and projects. GES DISC maintains an archive of several hydrology datasets, including the Land Data Assimilation Systems (LDAS) and the Gravity Recovery and Climate Experiment (GRACE) Data Assimilation for Drought Monitoring (GRACE-DA-DM) data products. These datasets include model output of heat fluxes, rain, snow, soil temperature, soil moisture, and runoff; and observational forcing data, including surface pressure, temperature, precipitation, downward shortwave and longwave radiation, humidity, and wind. The temporal resolution of the hydrology data at GES DISC ranges from hourly to monthly, and spatial resolutions range from 0.1° to 1.0°. The GES DISC provides services which enable users to aggregate, temporally and spatially subset, regrid, and visualize archived data including the GES DISC Subsetter, Hydrology Data Rods, and the Geospatial Interactive Online Visualization and Analysis Infrastructure (GIOVANNI). The Hydrology Data Rods service optimally reorganizes large hydrological data sets as extended time series, providing more efficient access for the hydrological community. The time series data (aka “data rods”) were integrated into hydrology community tools, such as the Data Rods Explorer on HydroShare. Furthermore, the GES DISC is in the process of migrating its data and services to the cloud. Hydrological data available at the GES DISC are now available in the Amazon Web Services (AWS) cloud (us-west-2 region) providing users Direct S3 data access and the capability for cloud computing operations. In this presentation, the hydrology data products and services currently available at the GES DISC will be summarized. Also discussed are the migration to the cloud, user support through this transition, and the status of migrating the data rods service to the cloud.

Ashley Heath↗
DOE OSTI2020

Materials Data on Ba(SO2)2 by Materials Project

Ba(SO2)2 crystallizes in the orthorhombic Pbcn space group. The structure is two-dimensional and consists of two Ba(SO2)2 sheets oriented in the (0, 0, 1) direction. Ba2+ is bonded in a 5-coordinate geometry to eight O2- atoms. There are a spread of Ba–O bond distances ranging from 2.59–3.37 Å. There are two inequivalent S3+ sites. In the first S3+ site, S3+ is bonded in a single-bond geometry to one O2- atom. The S–O bond length is 1.55 Å. In the second S3+ site, S3+ is bonded in a trigonal non-coplanar geometry to three O2- atoms. There is two shorter (1.49 Å) and one longer (1.50 Å) S–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Ba2+ and one S3+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Ba2+ and one S3+ atom. In the third O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Ba2+ and one S3+ atom. In the fourth O2- site, O2- is bonded in a distorted single-bond geometry to three equivalent Ba2+ and one S3+ atom.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Exploring the environmental drivers of vegetation seasonality changes in the northern extratropical latitudes: a quantitative analysis *

Abstract Vegetation seasonality in the northern extratropical latitudes (NEL) has changed dramatically, but our understanding of how it responds to climate change (e.g. temperature, soil moisture, shortwave radiation) and human activities (e.g. elevated CO 2 concentration) remains insufficient. In this study, we used two remote-sensing-based leaf area index and factorial simulations from the TRENDY models to attribute the changes in the integrated vegetation seasonality index ( S ), which captures both the concentration and magnitude of vegetation growth throughout the year, to climate, CO 2 , and land use and land cover change (LULCC). We found that from 2003 to 2020, the enhanced average S in the NEL (MODIS: 0.0022 yr −1 , p < 0.05; GLOBMAP: 0.0018 yr −1 , p < 0.05; TRENDY S3 [i.e. the scenario considering both time-varying climate, CO 2 , and LULCC]: 0.0011 ± 7.5174 × 10 −4 yr −1 , p < 0.05) was primarily determined by the elevated CO 2 concentration (5.3 × 10 −4 ± 3.8 × 10 −4 yr −1 , p < 0.05) and secondly controlled by the combined climate change (4.6 × 10 −4 ± 6.6 × 10 −4 yr −1 , p > 0.1). Geographically, negative trends in the vegetation growth concentration were dominated by climate change (31.4%), while both climate change (47.9%) and CO 2 (31.9%) contributed to the enhanced magnitude of vegetation growth. Furthermore, around 60% of the study areas showed that simulated major climatic drivers of S variability exhibited the same dominant factor as observed in either the MODIS or GLOBMAP data. Our research emphasizes the crucial connection between environmental factors and vegetation seasonality, providing valuable insights for policymakers and land managers in developing sustainable ecosystem management strategies amidst a changing climate.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1981

Rocket study of auroral processes

Abstracts are presented of previously published reports analyzing data from three Echo 3 rocket flights. Particle experiments designed for the Terrier-Malmute flight, the Echo 5 flight, and the Norwegian Corbier Ferdinand 50 flight are described and their flight performance evaluated. Theoretical studies on auroral particle precipitation are reviewed according to observations made in three regions of space: (1) the region accessible to rockets and low altitude satellites (few hundred to a few thousand kilometers); (2) the region extending from 4000 to 8000 km (S3-3 satellite range); and (3) near the equatorial plane (geosynchronous satellite measurements). Questions raised about auroral arc formation are considered.

Arnoldy, R. L.↗
NASA NTRS2003

Compositional Grading in an Impact-produced Spherule Bed, Barberton Greenstone Belt, South Africa: A Key to Condensation History of Rock Vapor Clouds

The chemical and physical processes by which spherules form during the condensation of impact-produced rock vapor clouds are poorly understood. Although efforts have been made to model the processes of spherule formation, there is presently a paucity of field data to constrain the resulting theoretical models. The present study examines the vertical compositional variability in a single early Archean spherule bed in the Barberton Greenstone Belt (BGB), South Africa, in order to better identify the process by which impact vapor clouds condense and spherules form and accumulate. The BGB spherule beds are suitable for this type of study because of their great thickness, often exceeding 25cm of pure spherules, due to the massive sizes of the impactors. Two main problems complicate analysis of vertical compositional variability of graded spherule beds: (1) differential settling of particles in both the vapor and water column due to density and size differences and (2) turbulence within the vapor cloud. The present study compares sections of spherule bed S3 from four different depositional environments in the Barberton Greenstone Belt: (1) The Sheba Mine section (SAF-381) was deposited under fairly low energy conditions in deep water, providing a nice fallout sequence, and also has abundant Ni-rich spinels; (2) Jay's Chert section (SAF-380) was deposited in subaerial to shallow-water conditions with extensive post-depositional reworking by currents. The spherules also have preserved spinels; (3) the Loop Road section (loc. SAF-295; samp. KSA-7) was moderately reworked and has only rare preservation of spinels; and (4) the shallow-water Barite Syncline section (loc. SAF-206; samp KSA-1) has few to no spinels preserved and is not reworked. Although all of the spherule beds have been altered by silica diagenesis and K-metasomatism, most of the compositional differences between these sections appear to reflect their diagenetic histories, possibly related to their differing depositional environments. Sulfate diagenesis in the Barite Syncline and Loop road sections may account for the loss of spinels.

Krull, A. E.↗
NASA NTRS1984

Electrostatic ion (hydrogen) cyclotron and ion acoustic wave instabilities in regions of upward field-aligned current and upward ion beams

An investigation is made into the stability of electrostatic hydrogen ion cyclotron and ion acoustic waves in a model plasma where an ion beam, population 2, and oppositely directed drifting electrons pass through a stationary ion background, population 1. The excited wave properties are then compared with the characteristics of the unstable modes observed on the S3-3 satellite. Three temperature regimes are studied: (1) Te greater than Ti2 much greater than Ti1, (2) Ti2 greater than Te not less than Ti1, and (3) Te approximately equal to Ti1 greater than Ti2. It is found that the ion beam acts as a free energy source only in regime 1. This regime is also highly unstable to the electrons as a free energy source. Unstable modes in regimes 2 and 3 seem to best satisfy the electrostatic hydrogen cyclotron wave (EHC) properties at 1 earth radius. For these cases the electrons are the free energy source, the beam supplies damping.

Bergmann, R.↗
DOE OSTI2026

Data for "Genetics of flooding tolerance in an F2 Miscanthus sacchariflorus ssp. lutarioriparius × M. sinensis population"

This dataset contains all data and supplementary materials from "Genetics of flooding tolerance in an F2 Miscanthus sacchariflorus ssp. lutarioriparius × M. sinensis population". 1. The dataset S1 table contains the raw phenotypic data collected during the experiment. 2. The dataset S2 table contains the LSmean values for the 24 traits studied. 3. The dataset S3 table contains the TASSEL GBSv2 map, marker information, and genotype data used for mapping. 4. The dataset S4 table contains information on candidate genes found in each of the QTL intervals. 5. The dataset S5 table contains the GO annotations and KEGG enrichment analyses for those candidate genes. 6. The dataset S6 table contains information on the sequences used to classify AP2 ERF transcription factors. 7. The dataset S7 table contains information on AP2 ERF orthologs between Miscanthus and rice based on synteny. 8. Supplementary file 1 contains the ANOVA results using the raw phenotypic data collected from protocol "A". 9. Supplementary file 2 contains the ANOVA results using the raw phenotypic data collected from protocol "B". 10. Supplementary file 3 contains notes on the comparison of SNP calling methods. 11. Supplementary file 4 is a script for analyzing candidate genes found in QTL intervals.

Miscanthus, flood, partial submergence, complete s↗
NASA NTRS1997

Archiving of Wideband Plasma Wave Data

Beginning with the third year of funding, we began a more ambitious archiving production effort, minimizing work on new software and concentrating on building representative archives of the missions mentioned above, recognizing that only a small percentage of the data from any one mission can be archived with reasonable effort. We concentrated on data from Dynamics Explorer and ISEE 1, archiving orbits or significant fractions of orbits which attempt to capture the essence of the mission and provide data which will hopefully be sufficient for ongoing and new research as well as to provide a reference to upcoming and current ISTP missions which will not fly in the same regions of space as the older missions and which will not have continuous wideband data. We archived approximately 181 Gigabytes of data, accounting for some 1582 hours of data. Included in these data are all of the AMPTE chemical releases, all of the Spacelab 2/PDP data obtained during the free-flight portion of its mission, as well as significant portions of the S3, DE-1, Imp-6, Hawkeye, Injun 5, and ISEE 1 and 2 data sets. Table 1 summarizes these data. All of the data archived are summarized in gif-formatted images of frequency-time spectrograms which are directly accessible via the internet. Each of the gif files are identified by year, day, and time as described in the Web page. This provides a user with a specific date/time in mind a way of determining very quickly if there is data for the interval in question and, by clicking on the file name, browsing the data. Alternately, a user can browse the data for interesting features and events simply by viewing each of the gif files. When a user finds data of interest, he/she can notify us by email of the time period involved. Based on the user's needs, we can provide data on a convenient medium or by ftp, or we can mount the appropriate data and provide access to our analysis tools via the network. We can even produce products such as plots or spectrograms in hardcopy form based on the specific request of the user.

Kurth, William S.↗
NASA NTRS1993

The large-scale morphology of IRAS galaxies

At present, visual inspection is the only method for comparing the large-scale morphologies in the distribution of galaxies to those in model universes generated by N-body simulations. To remedy the situation, we have developed a set of three structure functions (S1, S2, S3) that quantify the degree of large-scale prolateness, oblateness, and sphericity/uniformity of a 3-D particle distribution and have applied them to a volume-limited (less than = 4000 km/s) sample of 699 IRAS galaxies with f sub 60 greater than 1.2 Jy. To determine the structure functions, we randomly select 500 galaxies as origins of spherical windows of radius R sub w, locate the centroid of the galaxies in the window (assuming all galaxies have equal mass) and then, compute the principal moments of inertia (I sub 1, I sub 2, I sub 3) about the centroid. Each S sub i is a function of (I sub 2)/(I sub 1) and (I sub 3)/I sub 1). S1, S2, and S3 tend to unity for highly prolate, oblate, and uniform distributions, respectively and tend to zero otherwise. The resulting 500 values of S sub i at each scale R sub w are used to construct a histogram.

Babul, Arif↗
NASA NTRS1982

Findings on rings and inner satellites of Saturn of Pioneer 11

The introductory part of this paper gives a short account of the theory of absorption by planetary rings and satellites of energetic charged particles that are trapped in a planet's magnetic field and describes the observable consequences of such absorption processes. The previously published University of Iowa observations of absorption features during Pioneer 11's passage through Saturn's inner radiation belt on 1 September 1979 are critically reanalyzed and related to other evidence on rings and satellites inside 2.9 Saturn radii, especially that from the imaging system on Voyagers 1 and 2. It is found (a) that satellites 1979 S1, 1979 S2, and 1980 S3 are almost certainly identical; (b) that the evidence for 1979 S4 is weak to nonexistent; (c) that 1979 S5 and two other nearby absorption features and 1979 S6 and one other nearby absorption feature are probably caused by longitudinal and radial structure of Ring F and not by satellites; and (d) that absorption feature 1979 S3 at 169,200 + or - 600 km is identified with the optically observed Ring G.

Van Allen, J. A.↗