Materials Data on ReSbOF9 by Materials Project
ReSbOF9 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two ReSbOF9 clusters. Re6+ is bonded in a 6-coordinate geometry to one O2- and five F1- atoms. The Re–O bond length is 1.67 Å. There are a spread of Re–F bond distances ranging from 1.86–2.36 Å. Sb5+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.88–2.13 Å. O2- is bonded in a single-bond geometry to one Re6+ atom. There are nine inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Re6+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the fourth F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Re6+ and one Sb5+ atom. In the fifth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the sixth F1- site, F1- is bonded in a single-bond geometry to one Re6+ atom. In the seventh F1- site, F1- is bonded in a distorted bent 150 degrees geometry to one Re6+ and one Sb5+ atom. In the eighth F1- site, F1- is bonded in a single-bond geometry to one Re6+ atom. In the ninth F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.