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Ta2VRe crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two Ta2VRe ribbons oriented in the (1, 0, 0) direction. Ta is bonded in a linear geometry to one V and one Re atom. The Ta–V bond length is 2.35 Å. The Ta–Re bond length is 2.28 Å. V is bonded in a linear geometry to two equivalent Ta atoms. Re is bonded in a linear geometry to two equivalent Ta atoms.
TaV2Re crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TaV2Re ribbons oriented in the (1, 0, 0) direction. Ta is bonded in a linear geometry to two equivalent V atoms. Both Ta–V bond lengths are 2.26 Å. V is bonded in a linear geometry to one Ta and one Re atom. The V–Re bond length is 2.21 Å. Re is bonded in a linear geometry to two equivalent V atoms.
TaVRe2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two TaVRe2 ribbons oriented in the (1, 0, 0) direction. Ta is bonded in a linear geometry to two equivalent Re atoms. Both Ta–Re bond lengths are 2.35 Å. V is bonded in a linear geometry to two equivalent Re atoms. Both V–Re bond lengths are 2.31 Å. Re is bonded in a linear geometry to one Ta and one V atom.
Ta2VRe is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Ta is bonded in a body-centered cubic geometry to four equivalent V and four equivalent Re atoms. All Ta–V bond lengths are 2.76 Å. All Ta–Re bond lengths are 2.76 Å. V is bonded in a distorted body-centered cubic geometry to eight equivalent Ta atoms. Re is bonded in a body-centered cubic geometry to eight equivalent Ta atoms.