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Materials Data on RbGe by Materials Project

RbGe crystallizes in the cubic P-43n space group. The structure is three-dimensional. there are two inequivalent Rb sites. In the first Rb site, Rb is bonded in a 6-coordinate geometry to six Ge atoms. There are three shorter (3.67 Å) and three longer (3.81 Å) Rb–Ge bond lengths. In the second Rb site, Rb is bonded in a 6-coordinate geometry to six Ge atoms. There are a spread of Rb–Ge bond distances ranging from 3.52–3.79 Å. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded in a 9-coordinate geometry to six Rb and three equivalent Ge atoms. All Ge–Ge bond lengths are 2.60 Å. In the second Ge site, Ge is bonded in a 9-coordinate geometry to six Rb and three equivalent Ge atoms. There are two shorter (2.60 Å) and one longer (2.63 Å) Ge–Ge bond lengths.

36 MATERIALS SCIENCE↗

Materials Data on RbGe by Materials Project

RbGe crystallizes in the tetragonal I4_1/acd space group. The structure is three-dimensional. there are two inequivalent Rb sites. In the first Rb site, Rb is bonded in a 12-coordinate geometry to eight equivalent Ge atoms. There are a spread of Rb–Ge bond distances ranging from 3.70–3.84 Å. In the second Rb site, Rb is bonded in a 6-coordinate geometry to six equivalent Ge atoms. There are a spread of Rb–Ge bond distances ranging from 3.70–3.82 Å. Ge is bonded in a distorted q6 geometry to seven Rb and three equivalent Ge atoms. There are two shorter (2.61 Å) and one longer (2.62 Å) Ge–Ge bond lengths.

36 MATERIALS SCIENCE↗

Materials Data on RbGe by Materials Project

RbGe is Halite, Rock Salt structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rb is bonded to six equivalent Ge atoms to form a mixture of corner and edge-sharing RbGe6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Rb–Ge bond lengths are 3.59 Å. Ge is bonded to six equivalent Rb atoms to form a mixture of corner and edge-sharing GeRb6 octahedra. The corner-sharing octahedral tilt angles are 0°.

36 MATERIALS SCIENCE↗