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DOE OSTI2020

Materials Data on RbClO4 by Materials Project

RbClO4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rb is bonded in a 10-coordinate geometry to ten O atoms. There are a spread of Rb–O bond distances ranging from 3.06–3.33 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted single-bond geometry to three equivalent Rb and one Cl atom. The O–Cl bond length is 1.47 Å. In the second O site, O is bonded in a distorted single-bond geometry to one Rb and one Cl atom. The O–Cl bond length is 1.45 Å. In the third O site, O is bonded in a distorted single-bond geometry to three equivalent Rb and one Cl atom. The O–Cl bond length is 1.46 Å. Cl is bonded in a tetrahedral geometry to four O atoms.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Materials Data on RbClO4 by Materials Project

RbClO4 crystallizes in the cubic F-43m space group. The structure is three-dimensional. Rb is bonded in a 12-coordinate geometry to twelve equivalent O atoms. All Rb–O bond lengths are 3.27 Å. O is bonded in a single-bond geometry to three equivalent Rb and one Cl atom. The O–Cl bond length is 1.47 Å. Cl is bonded in a tetrahedral geometry to four equivalent O atoms.

36 MATERIALS SCIENCE↗