Materials Data on Rb2BaPt2(CN)8 by Materials Project
Rb2BaPt2(CN)8 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. Rb1+ is bonded in a body-centered cubic geometry to eight equivalent N3- atoms. All Rb–N bond lengths are 3.36 Å. Ba2+ is bonded in a body-centered cubic geometry to eight equivalent N3- atoms. All Ba–N bond lengths are 2.92 Å. Pt2- is bonded in a rectangular see-saw-like geometry to four equivalent C3+ atoms. All Pt–C bond lengths are 1.99 Å. C3+ is bonded in a linear geometry to one Pt2- and one N3- atom. The C–N bond length is 1.18 Å. N3- is bonded in a distorted single-bond geometry to two equivalent Rb1+, one Ba2+, and one C3+ atom.
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